• 한국자기공명학회논문지
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• 제17권2호
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• pp.86-91
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• 2013

Detailed information about the structural nature of three-coordinate borons in ${\beta}-BaB_2O_4$ is obtained through $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR. The three-coordinate $BO_3$ of the two borons B(1) and B(2) in ${\beta}-BaB_2O_4$ were distinguished. The spin-lattice relaxation time in the laboratory frame $T_1$ for B(1) and B(2) slowly decreases with increasing temperature, whereas the spin-lattice relaxation time in the rotating frame $T_{1{\rho}}$ for B(1) and B(2), which differs from $T_1$, is nearly constant. The B(1) and B(2) of the two types were distinguished by $^{11}B$ MAS NMR and $^{11}B$ single-crystal NMR.

• 한국자기공명학회논문지
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• 제10권2호
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• pp.197-202
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• 2006

[ $^{11}B$ ] nuclear magnetic resonance (NMR) measurements were performed on the single crystals of $TbB_4$ to investigate local electronic structure and 4f spin dynamics. $^{11}B$ NMR spectrum, Knight shift, spin-lattice and spin-spin relaxation rates were measured down to 4K at 8T. $^{11}B$ NMR shift and linewidth are huge and strongly temperature dependent due to the 4f moments. In addition, both are proportional to magnetic susceptibility, indicating that the hyperfine field at the boron site originates from the 4f spins of Tb. Below $T_N$, the single broad resonance peak of $^{11}B$ NMR splits into several peaks reflecting the local magnetic fields due to antiferromagnetic spin arrangements. The longitudinal and the transverse relaxation rates, $1/T_1\;and\;1/T_2$, independent of temperature above $T_N$, decreases tremendously confirming huge suppression of spin fluctuation below $T_N$.

• 한국자기공명학회논문지
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• 제17권1호
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• pp.24-29
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• 2013

The structural characteristics of 4-coordinate $BO_4$ [B(1)] and 3-coordinate $BO_3$ [B(2)] groups in $BiB_3O_6$ were studied by $^{11}B$ magic angle spinning (MAS) and single-crystal nuclear magnetic resonance (NMR) spectroscopy. The spin-lattice relaxation time in the laboratory frame, $T_1$, for $^{11}B$ decreased slowly with increasing temperature, whereas the spin-lattice relaxation times in the rotating frame, $T_{1{\rho}}$, for B(1) and B(2), which differed from $T_1$, were nearly constant. Further, $T_{1{\rho}}$ for B(1) and B(2) showed very similar trends, although the $T_{1{\rho}}$ value of B(2) was shorter than that of B(1). The 3-coordinate $BO_3$ and 4-coordinate $BO_4$ were distinguished by $^{11}B$ MAS NMR spectrum and $T_{1{\rho}}$.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2000년도 High Temperature Superconductivity Vol.X
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• pp.61-64
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• 2000

$^{11}$B NMR measurements have been performed to investigate local electronic structure and 4f spin dynamics for TbNi$_2$B$_2$C single crystal. $^{11}$B NMR spectra show three resonance peaks due to the quadrupolar interaction. Shift and linewidth are huge and strongly temperature-dependent. In addition, both are proportional to magnetic susceptibility, indicating that the hyperfine field at the boron site originates from the 4f spins of Tb. $^{11}$B NMR shift and relaxation rates show high anisotropy for field parallel and perpendicular to the c-axis. Anisotropy of the shift and the relaxation rates suggests that the hyperfine field perpendicular to the c-axis is larger.

• Bulletin of the Korean Chemical Society
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• 제19권5호
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• pp.519-524
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• 1998

In this work, we applied the 1D 11B nutation NMR method for the analysis of the local structural environments in powdered borosilicates (SiO2-B2O3). Spin dynamics during a rf irradiation for spin I=3/2 was analytically calculated with a density matrix formalism. Spectral simulation programs were written in MATLAB on a PC. Two borosilicates prepared by the sol-gel process at different stabilization temperature were used for the 1D 11B nutation NMR experiment. The 11B NMR parameters, quadrupole coupling constants (e2qQ/h) and asymmetry parameters (η), for each borosilicate were extracted from the nonlinear least-squares fitting. The effects of heat treatments on the local structures of boron sites in borosilicates were discussed.

• 한국자기공명학회논문지
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• 제7권2호
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• pp.80-88
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• 2003

We have performed $^{11}$ B nuclear magnetic resonance (NMR) measurements to microscopically investigate an electronic structure of the ferromagnetic state in three different compositions of calcium-hexaboride single crystals. Although the crystal structure of Ca $B_{6}$ is cubic and three NMR lines may be expected for the nuclear spin 3/2 of $_{11}$ B, a larger number of NMR resonance peaks have been observed. The frequency and intensity of those peaks distinctively changes depending on the angle between crystalline axis and magnetic field. Analyzing this behavior, we find that the electric field gradient(EFG) tensor at the boron has its principal axis perpendicular to the six cubic faces with a quadrupole resonance frequency $v_{Q}$ 600 kHz. Even though the magnetization data highlight the ferromagnetic hysteresis, $^{11}$ B NMR linewidth data show no clear microscopic evidence of the ferromagnetic state in three different compositions of Ca $B_{6}$ single crystals.s.

• 한국자기공명학회논문지
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• 제9권1호
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• pp.21-28
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• 2005

$^{11}B$ nuclear magnetic resonance (NMR) measurements have been performed to investigate electronic structures and vortex states of $M_gB_2$ superconductor. The central transition shows a narrow peak down to 25 K at 3.15 T. Below 25 K, an extra line starts to show up and dominates. The extra line is broad and asymmetric with a long tail in the high frequency side, which confirms that this originates from vortex pinning below the irreversibility temperature. From temperature evolution of the fraction and linewidth of the broad portion, temperature dependence of coherence length and penetration depth are extracted.

• 한국광물학회지
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• 제29권3호
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• pp.155-165
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• 2016

붕소가 포함된 다성분계 규산염 용융체의 원자 구조를 규명하는 것은 화산의 분화 양상을 포함한 다양한 지구화학적 과정의 원자 단위 기작을 밝히는데 중요하다. 붕소를 포함한 소듐 알루미노규산염 용융체의 붕소 및 알루미늄 주위의 원자 환경에 관한 자세한 정보는 수용액과 핵폐기물 유리(nuclear waste glasses)의 반응도(reactivity)에 대한 미시적인 설명을 제공한다. 본 연구에서는 붕소가 포함된 비정질 물질의 원자 구조 규명에 가장 적합한 고상 핵자기 공명 분광분석(solid-state nuclear magnetic resonance, solid-state NMR)을 이용하여 붕소의 함량이 비정질 소듐 보레이트($Na_2O-B_2O_3$)와 붕소를 포함한 다성분계 규산염 용융체[말린코아이트(malinkoite, $NaBSiO_4$)와 네펠린(nepheline, $NaAlSiO_4$)의 유사 이원계]의 원자 구조에 미치는 영향을 규명하였다. 비정질 소듐 보레이트의 $^{11}B$ MAS NMR 스펙트럼을 통해 붕소의 함량이 증가함에 따라 배위수가 3인 붕소($^{[3]}B$)가 증가한다는 것이 확인되었다. 비정질 말린코아이트와 네펠린의 유사 이원계의 $^{11}B$ MAS NMR 스펙트럼을 통해 $X_{Ma}$ [$=NaBSiO_4/(NaBSiO_4+NaAlSiO_4)$]가 증가함에 따라 배위수가 4인 붕소($^{[4]}B$)는 증가하는 반면 $^{[3]}B$는 감소하는 것이 관찰되었다. 다성분계 용융체의 $^{27}Al$ MAS NMR 실험 결과, 모든 조성의 용융체에서 배위수가 4인 알루미늄($^{[4]}Al$) 피크가 지배적으로 나타났다. 또한 네펠린 용융체에 붕소가 첨가되었을때 $^{[4]}Al$ 피크의 폭이 크게 감소하였고, 이는 붕소의 첨가가 네펠린 용융체 내의 알루미늄 주위의 구조적 위상학적 무질서도를 감소시킨다는 것을 지시한다. 붕소를 포함한 이원계 및 다성분계 비정질 물질의 $^{11}B$ MAS NMR 스펙트럼으로부터 시뮬레이션을 하여 붕소의 함량에 따른 붕소 원자 환경의 상대적인 존재비를 정량적으로 분석하였고, 이 결과는 붕소가 포함된 비정질 물질의 거시적 성질 변화에 대한 미시적 기작의 근원을 제시할 가능성을 보여준다.

• Bulletin of the Korean Chemical Society
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• 제19권5호
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• pp.501-503
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• 1998

In this work, we applied the 1D $11^B$ nutation NMR method for the analysis of the local structural environments in powdered borosilicates $(SiO_2-B_2O_3)$. Spin dynamics during a rf irradiation for spin I=3/2 was analytically calculated with a density ma trix formalism. Spectral simulation programs were written in MATLAB on a PC. Two borosilicates prepared by the sol-gel process at different stabilization temperature were used for the 1D $11^B$ nutation NMR experiment. The $11^B$ NMR parameters, quadrupole coupling constants $(e^2qQ/h)$ and asymmetry parameters (η), for each borosilicate were extracted from the nonlinear least-squares fitting. The effects of heat treatments on the local structures of boron sites in borosilicates were discussed.

• 한국초전도ㆍ저온공학회논문지
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• 제11권4호
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• pp.1-7
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• 2009

The unique features of HTS offer Opportunities and challenges to a number of applications. In this paper we focus on NMR and MRI magnets, illustrating them with the NMR/MRI magnets that we are currently and will shortly be engaged: a 1.3GHz NMR magnet, an "annulus" magnet, and an $MgB_2$ whole-body MRI magnet. The opportunities with HTS include: 1) high fields (e.g., 1.3GHz magnet); 2) compactness (annulus magnet); and 3) enhanced stability despite liquid-helium-free operation ($MgB_2$ whole-body MRI magnet). The challenges include: 1) a large screening current Beld detrimental to spatial field homogeneity (e.g., 1.3 GHz magnet); 2) uniformity of critical current density (annulus magnet); and 3) superconducting joints ($MgB_2$ magnet).