• Bulletin of the Korean Chemical Society
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• v.15 no.10
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• pp.857-860
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• 1994

We have calculated the ${\pi}$-electron density, atom self-polarizability, and free valence on each atom of N-(2-chlorobenzyl)-pyridinium, N-(benzyl)-2-chloropyridinium, and N-(2-chlorobenzyl)-2-chloropyridinium salts using a simple Huckel method in order to discuss their intramolecular photocyclization reaction in a qualitative method. Our calculation qualitatively predicts that photocyclization occurs through forming radicals as a reaction intermediate by breaking a C-Cl bond after photoexcitation into a triplet state via intersystem crossing from an initially excited singlet state. We noticed that this C-Cl bond breaking is aided by ${\pi}$-complex formation between a chlorine atom and the ${\pi}$ -electrons of the neighboring ring in the triplet state and a stronger ${\pi}$-complex bond makes C-Cl bond breaking, i.e., radical formation, much easier. A chlorine atom will form a stronger ${\pi}$ -complex bond to a benzyl ring of N-(benzyl)-2-chloropyridinium than a pyridinium ring of N-(2-chlorobenzyl)-pyridinium because the former can donate its ${\pi}$-electron more easily than the latter. The chlorine at position 15 of N-(2-chlorobenzyl)-2-chloropyridinium salt in the excited state also provides its ${\pi}$-electron to the benzyl ring. So this ${\pi}$-electron can increase the bond strength of the $\pi-complex.$ Therefore, the strength of ${\pi}$-complex follows the order of N-(2-chlorobenzyl)-2-chloropyridinium, N-(benzyl)-2-chloropyridinium, and N-(2-chlorobenzyl)-pyridinium salts and thus the radical formation rate. This provides us with an intramolecular photocyclization reaction rate of the same order as given above.

• The Transactions of the Korean Institute of Power Electronics
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• v.11 no.5
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• pp.404-408
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• 2006

This paper presents an anti-windup gain selection method for a complex vector synchronous frame PI current controller. The complex vector PI current controller is more robust to the parameter variation than the state feedback decoupling PI current controller. The complex vector PI current controller also includes an integral term, which can results in windup problem when the controller is saturated due to physical limitation of the system. Furthermore, even an anti-windup is utilized, inappropriate gain can deteriorate the performance of the current controller. Therefore, appropriate anti-windup gain selection method for a complex vector current controller has been proposed based on the mathematical description of the current control system. The superior performance of the current control system with the proposed anti-windup gain has been verified by the experimental results.

• BMB Reports
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• v.49 no.7
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• pp.355-356
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• 2016

The THO/TREX complex consists of several conserved subunits and is required for mRNA export. In metazoans, THO/TREX binds a subset of mRNAs during RNA splicing, and facilitates their nuclear export. How THO/TREX selects RNA targets is, however, incompletely understood. In our recent study, we reported that THO is loaded onto Piwi-interacting RNA (piRNA) precursor transcripts independent of splicing, and facilitates convergent transcription in Drosophila ovary. The precursors are later processed into mature piRNAs, small noncoding RNAs that silence transposable elements (TEs). We observed that piRNAs originating from dual-strand clusters, where precursors are transcribed from both strands, were specifically affected by THO mutation. Analysis of THO-bound RNAs showed enrichment of dual-strand cluster transcripts. Interestingly, THO loading onto piRNA precursors was dependent on Cutoff (Cuff), which comprises the Rhino-Deadlock-Cutoff (RDC) complex that is recruited to dual-strand clusters by recognizing H3K9me3 and licenses convergent transcription from he cluster. We also found that THO mutation affected transcription from dual-strand clusters. Therefore, we concluded that THO/TREX is recruited to dual-strand piRNA clusters, independent of splicing events, via multi-protein interactions with chromatin structure. Then, it facilitates transcription likely by suppressing premature termination to ensure adequate expression of piRNA precursors.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.22 no.6
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• pp.1231-1243
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• 1997

Digital satellite communication channels have nonlinearities with memory due to saturation characteristics of traveling wave tube amplifier in the satellite and transmitter/receiver linear filters. In this paper, we propose a network structure and a learning algorithm for complex pi-sigma network (CPSK) and exploit CPSN in the problem of equalization of nonlinear satellite channels. The proposed CPSN is a complex-valued extension of real-valued pi-sigma network that is a higher-order feedforward network with fast learning while greatly reducing network complexity by utilizing efficient form of polynomials for many input variables. The performance of the proposed CPSN is demonstrated by computer simulations on the equalization of complex-valued QPSK input symbols distorted by a nonlinear channel modeled as a Volterra series and additive noise. The results indicate that the CPSN shows good equalization performance, fast convergence, and less computations as compared to conventional higher-order models such as Volterra filters.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 1999.05a
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• pp.437-441
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• 1999

In this paper, a fault diagnosis method using unknown-input proportional integral (PI) observers including the magnitude of actuator failures is proposed. It is shown that actuator failures are detected and isolated perfectly by monitoring the integrated error between the actual output and the estimated output using an unknown-input PI observer. Also in presence of complex actuator and sensor failures, these failures are detected and isolated by multiple unknown-input PI observers perfectly.

• Journal of the Chungcheong Mathematical Society
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• v.21 no.2
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• pp.269-278
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• 2008

Let ${\partial}D$ be the boundary of the open unit disk D in the complex plane and $L^p({\partial}D)$ the class of all complex, Lebesgue measurable function f for which $\{\frac{1}{2\pi}{\int}_{-\pi}^{\pi}{\mid}f(\theta){\mid}^pd\theta\}^{1/p}<{\infty}$. Let P be the orthogonal projection from $L^p({\partial}D)$ onto ${\cap}_{n<0}$ ker $a_n$. For $f{\in}L^1({\partial}D)$, ${\hat{f}}(z)=\frac{1}{2\pi}{\int}_{-\pi}^{\pi}P_r(t-\theta)f(\theta)d{\theta}$ is the harmonic extension of f. Let ${\hat{P}}$ be the composition of P with the harmonic extension. In this paper, we will show that if $1, then ${\hat{P}}:L^p({\partial}D){\rightarrow}H^p(D)$ is bounded. In particular, we will show that ${\hat{P}}$ is unbounded on $L^{\infty}({\partial}D)$.

• Korean Journal of Microbiology
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• v.28 no.2
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• pp.134-144
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• 1990

In order to examine that what kind of system correlated with cadmium detoxification mechanism in Klebsiella aerogenes ATCC 10031, we tried to investigate the effect of phosphate upon the detoxification and also elucidate whether the cadmium phosphate and/or polymeric Cd-Pi complex is formed actually in cell or not. As the results, it was shown that growing pattern had long lag adaptive phase of 12 hr to 24 hr, at the concentrations of 0.02 mM and 0.08 mM cadmium, respectively. Cadmium was accumulated more highly in the fraction of cell wall and membrane than in those of cytoplasm. In case of phosphate starving cells added cadmium, inorganic polyphosphate system was primarily correlated with Cd-detoxification during the lag phase for the accommodation to cadmium, on the other hand, Cd:Sulfide complex system secondarily correlated it during the stationary phase. These results implied that polyphosphate system and Cd:sulfide complex system, these two systems were operated compensatively each other. Considering the results obsdrved with EM and examined tha changes of sulfide and polyphosphate amount, it was reflected that Cd:S complex was located at the cell surface. In the results of $in-vivo^{31}$P NMR spectra in the cells with cadmium pressure, several phosphate signals arose newly from the polyphosphate region with moving chemical shift of it. This phinomenon strongly implied the actual existence of Dd:Pi comples and /or Cd:poly-P complex in the cell and also the cellular compartmentalization of cadmium detoxifying mechanism.

• Macromolecular Research
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• v.14 no.2
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• pp.199-204
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• 2006

Remarkably high and stable separation performance for olefin/paraffin mixtures was previously reported by facilitated olefin transport through ${\pi}$-complex membranes consisting of silver ions dissolved in poly(hexamethylenevinylene) (PHMV). In this study, the ${\pi}$-complex formation of $AgBF_4,\;AgClO_4\;and\;AgCF_{3}SO_3$ with PHMV and their ionic interactions were investigated. FT-Raman spectroscopy showed that the C=C stretching bands of PHMV shifted to a lower frequency upon incorporation of silver salt, but the degree of peak shift depended on the counter-anions of salt due to different complexation strengths. The symmetric stretching modes of anions indicated the presence of only free ions up to [C=C]:[Ag]=1:1, demonstrating the unusually high solubility of silver salt in PHMV. Above the solubility limit, the ion pairs and higher-order ionic aggregates started to form. The coordination number of silver ion for C=C of PHMV was in the order $AgBF_4$ > $AgClO_4$ > $AgCF_{3}SO_3$, but became similar at [C=C]:[Ag]=1:1. The different coordination number was interpreted in terms of the different transient crosslinks of silver cations in the complex, which may be related to both the interaction strength of the polymer/silver ion and the bulkiness of the counteranion.

• Kyungpook Mathematical Journal
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• v.59 no.3
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• pp.391-401
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• 2019

A module is said to be ${\pi}$-extending provided that every projection invariant submodule is essential in a direct summand of the module. In this article, we focus on the class of modules having the ${\pi}$-extending property by looking at the singularity of quotient submodules. By doing so, we provide counterexamples, using hypersurfaces in projective spaces over complex numbers, to show that being generalized ${\pi}$-extending is not inherited by direct summands. Moreover, it is shown that the direct sums of generalized ${\pi}$-extending modules are generalized ${\pi}$-extending.

• The Transactions of the Korean Institute of Electrical Engineers A
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• v.48 no.6
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• pp.671-677
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• 1999

In this paper, we have designed power system stabilizer (PSS) using object-oriented method. There are several types of power system stabilizer. A proportional-integral(PI) controller is very simple for practical implementation. Therefore it has been widely employed by the industry. The methods of obtaining the gains(Ki,Kp) of PI controller are root-locus method and sub-optimal regulator approach. But these methods are cannot be applicable to nonlinear system and faulted power system. So we proposed a new method which can be applied to nonlinear system by numerical analysis method. The method of dynamic system simulation by numerical method is very difficult and complex. We proposed flexible simultaion method for complex power system analysis using object-oriented programming(OOP) and applied to PI controller design.