• Title/Summary/Keyword: $\alpha$-quartz

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Dielectric Characteristics of Carbon Nitride Films on Quartz Substrate (석영기판에 증착된 질화탄소막의 유전특성)

  • Ha, Se-Geun;Lee, Ji-Gong;Lee, Sung-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.872-875
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    • 2003
  • Carbon nitride($CN_x$) thin films were deposited on quartz substrates using reactive RF magnetron sputtering system at uarious deposition conditions and investigated dielectric characteristics. Samples for capacitance measurements were of the MIM(Metal-Insulator-Metal) type devices. Aluminum film electrodes were prepared by a vacuum thermal evaporation method before and after the deposition of carbon nitride films. Capacitances were measured by a FLUKE PM6306 RCL Meter at room temperature. Current-voltage(I-V) characteristics and resistivity were measured by a CATS CA-EDA semiconductor test and analyzer. The carbon nitride films showed ${\alpha}-C_3N_4$ and ${\beta}-C_3N_4$ etc. peaks through Raman and FTIR. Observed surface of film and side structure using SEM(Scanning Electron Microscope), and measured thickness of film by ${\alpha}-step$. We can find that the dielectric constant was the lowest value in 50% nitrogen ratio and the resistivity was the highest value in 70% nitrogen ratio.

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Image Cut Raman Microscope Study of the Geryong Mountain Chulwha Buncheong Ware (Image Cut Raman Microscope을 사용한 계룡산 철화 분청사기 연구)

  • Lim, Seong-Ho;Kim, Young-Bum;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.47 no.4
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    • pp.312-318
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    • 2010
  • Chulwha pieces collected from Hakbong-ri site in Keryong mountain were studied whether there is reactions or not in each layer to investigate firing condition of glaze, body, Chulwha, engobe of Buncheong ware in the early Chosun Dynasty, 15th~16th Century. As a result of XRD analysis of a Chulwha piece, a main crystal phase was $\alpha$-Quartz and a second was Mullite. It was assumed the firing temperature would be around $1200^{\circ}C$ because a little amount of Mullite was formed in the body and there was no phase transition $\alpha$-Quartz to cristobalite. As a result of ICRM analysis, Chulwha and glaze didn't react and the melted glazes were sunk into the Chunwha particles. The thin layer of glaze was found on the Chulwha layer. As a result, the color of Chulwha layer always came to vivid black. Moreover, Chulwha painting didn't spread over the Buncheong ware, because Chulwha and engobe didn't react. The boundary interface of engobe and body was not clear because they had similar compositions. This shows engobe was composed of more $Al_2O_3$ than body.

The Scientific Analysis of Floor Tile Excavated from the Beobgwangsa Temple Site in the Pohang (포항 법광사지 출토 녹유전의 자연 과학적 조사)

  • Moon Whan-Suk;Han Min-Su;Hwang Jin-Ju;Kim Ho-Sang
    • KOMUNHWA
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    • no.60
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    • pp.101-120
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    • 2002
  • The floor tile on a coated green-glass was excavated from the Beobgwangsa Temple Site in the Pohang City. We analyzed using the MXRD, ICP-AES, EDXRF, TG/DTA and TIMS. As a result of microscope analysis, it was composed of quartz, feldspar and clay particl

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Comparison of light transmittance in different thicknesses of zirconia under various light curing units

  • Cekic-Nagas, Isil;Egilmez, Ferhan;Ergun, Gulfem
    • The Journal of Advanced Prosthodontics
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    • v.4 no.2
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    • pp.93-96
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    • 2012
  • PURPOSE. The objective of this study was to compare the light transmittance of zirconia in different thicknesses using various light curing units. MATERIALS AND METHODS. A total of 21 disc-shaped zirconia specimens (5 mm in diameter) in different thicknesses (0.3, 0.5 and 0.8 mm) were prepared. The light transmittance of the specimens under three different light-curing units (quartz tungsten halogen, light-emitting diodes and plasma arc) was compared by using a hand-held radiometer. Statistical significance was determined using two-way ANOVA (${\alpha}$=.05). RESULTS. ANOVA revealed that thickness of zirconia and light curing unit had significant effects on light transmittance ($P$ <.001). CONCLUSION. Greater thickness of zirconia results in lower light transmittance. Light-emitting diodes light-curing units might be considered as effective as Plasma arc light-curing units or more effective than Quartz-tungsten-halogen light-curing units for polymerization of the resin-based materials.

Cordierite Powder Preparation from Alkoxides without Using Organic Solvents (유기용매의 사용없이 알콕사이드로부터 코디어라이트 분말제조)

  • Ryu, S.C.;Kim, H.R.;Kim, K.;Park, H.C.
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.291-297
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    • 1994
  • Cordierite powders were prepared by controlled hydrolysis of metal alkoxides with catalysts in water medium without using organic solvents. Water was adjusted to a certain pH by HC1 and NH4OH. $\alpha$-Cordierite powder was prepared from aluminum isopropoxide, tetraethyl orthosilicate and magnesium ethoxide mixed with water adjusted to pH of 3. At water pH of 11, $\alpha$-cordierite, mullite and $\beta$-quartz phases were coexisted. The powders were freeze dried, calcined and then fired at different temperatures. The characteristics of powders were examined by means of DTA, X-ray diffraction, FT-IR, and electron microscopy. It was found that $\alpha$-cordierite could be synthesized at temperature of 120$0^{\circ}C$ from the powders prepared by alkoxides with water medium without organic solvents.

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Growth of Low Defect Piezo-quartz and Defect Analysis (저결함 압전수정의 성장과 결함분석)

  • Lee Young Kuk;Bak Ro Hak
    • Korean Journal of Crystallography
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    • v.8 no.1
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    • pp.26-32
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    • 1997
  • Quartz single crystals were grown hydrothermally and growth defects such as dislocations, etch channels and impurities were examined. Growth rates were 0.25-0.65 mm/day under the growth conditions of following. 1. Mineralizer: $4wt.\%$ NaOH. 2. Growth temperature: $340-360^{\circ}C$. 3. Temperature gradient: $20-40^{\circ}C$. 4. Seed: ZY plate. 5. Nutrient: synthetic quartz. Defects of the quartz which was grown with optical grade synthetic nutrient, low dislocation density seed and horizontal seed setting technique were as follows. 1. Dislocation density: 20.0 each/$cm^2$. 2. Etch channel density: 5.0 each/$cm^2$ (1st grade by IEC 758 standard). 3. Impurity (larger than 10$\mu$) concentration: 2.4 each/$cm^3$ (Ia grade by IEC 758 standard). 4. Alpha value: 0.019 (A grade by IEC 758 standard).

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Effect of Quartz Porphyry on Growth of Creeping Bentgrass (Agrostis stolonifera) and Soil Bacterial Community Structures (맥반석처리가 골프장 잔디의 생육과 토양미생물의 군집구조에 미치는 영향)

  • Koh, Sung-Cheol;Choi, Jung-Hye;Kim, Byung-Hyuk;Kim, Sang-Eun
    • Korean Journal of Microbiology
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    • v.44 no.4
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    • pp.317-325
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    • 2008
  • Recently there are difficulties in management of golf courses because of an ever increasing demand for golf as a leisure sports. Hence natural minerals as an amendment could be applied to improve and manage the physicochemical properties of the golf course soils in an environment-friendly way. In this study, quartz porphyry, which has been shown to be a good soil amendment for crop production, was tested for its effect on physicochemical properties of the golf course soil, growth of creeping bentgrass (Agrostis stolonifera) and changes of soil microbial communities in the soil. In general, amendment of 20% quartz porphyry into the soil turned out to be most effective in enhancing a proper growth of the grass leaves and roots. DGGE profile data showed that eubacterial species richness was also the highest at this level of the mineral treatment in which Actinobacteria and ${\alpha}$-Proteobacteria were the dominant phyla. This appeared to be attributed to a low level of soluble organic matter content and decreased concentration of cations such as $Ca^{2+}$, $Mg^{2+}$, and $K^+$.

Local Electronic Structures of $SiO_2$ Polymorph Crystals: Insights from O K-edge Energy-Loss Near-Edge Spectroscopy (산소 K-전자껍질 에너지-손실 흡수끝-부근 구조 양자계산을 이용한 $SiO_2$ 동질이상 광물의 전자구조 연구)

  • Yi, Yoo-Soo;Lee, Sung-Keun
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.403-411
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    • 2010
  • Essentials of understanding the geochemical evolution and geophysical processes in Earth's system are macroscopic properties and atomistic (and electronic) structures of Earth materials. Recent advances in quantum calculations based on the density functional theory allow us to unveil the previously unknown details of local atomic structures in diverse silicates in Earth's interior. Here, we report the O K-edge ELNES (energy-loss near-edge structure; ELNES) spectra and PLDOS (partial local density of states) for oxygen atoms in ${\alpha}$-quartz and stishovite using the quantum calculations based on FP-LAPW (full potential linearized augmented plane wave). The calculated O K-edge ELNES spectrum of ${\alpha}$-quartz shows a strong peak at ~538 eV due to comer-sharing oxygen linking two $SiO_4$ tetrahedra and that for stishovite shows two distinct peaks at ~537 and ~543 eV corresponding to edge-sharing oxygen linking $SiO_6$ octahedra. The significant differences in spectral features of O K-edge ELNES spectra suggest that the O K-edge features can be useful indicator to distinguish various oxygen sites in diverse crystal and amorphous silicates in the Earth's interior.

Secondary Compression Characteristics Caused by Particles Crushing of Sabkha Soil (입자파쇄 특성에 따른 Sabkha층의 이차압축 특성)

  • Kim, Seok-Ju;Bae, Kyung-Tae;Yi, Chang-Tok;Han, Heui-Soo
    • Journal of the Korean Geotechnical Society
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    • v.29 no.11
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    • pp.61-72
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    • 2013
  • The consolidation tests are conducted to investigate the soil particle crushing stress for understanding the secondary compression characteristics of carbonate sandy sabkha soil caused by particle crushing under a high confining stress. The rate of secondary crushing compression ($C_{{\alpha}{\epsilon}}{^*}$) is introduced instead of the rate of secondary compression to define the characteristic of the particle crushing compression settlement ($S_s{^*}$). Void ratio ($e_p{^*}$) and settlement ($H_p{^*}$) in particle crushing are used as a reference point of secondary behavior, and the ratio of primary compression index ($C_c$) to secondary crushing compression ($C_{{\alpha}{\epsilon}}{^*}$), $C_{{\alpha}{\epsilon}}{^*}/C_c$ value was changed from 0.0105 to 0.0187. When comparing with quartz sands, secondary compression settlement of sabkha is very large due to particle crushing which is not usually observed in quartz sand. It is observed that as the depth of sabkha layer becomes deep, the $S_s{^*}$ and $C_{{\alpha}{\epsilon}}{^*}$ increase under the same stress level.

Firing Condition, Source Area and Quantitative Analysis of Plain Coarse Pottery from the Unjeonri Bronze Age Relic Site, Cheonan, Korea (천안 운전리 청동기 유적지에서 출토된 무문토기의 정량분석, 산지 및 소성조건)

  • Choi, Seok-Won;Lee, Chan-Hee;Oh, Kuy-Jin;Lee, Hyo-Min;Lee, Myeong-Seong
    • Korean Journal of Heritage: History & Science
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    • v.36
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    • pp.267-297
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    • 2003
  • The plain coarse pottery from the Unjeonri Bronze Age relic sites in the Cheonan, Korea were studied on the basis of clay mineralogy, geochemistry and archaegeological interpretations. For the research, the potteries are utilized at the analysis for 6 pieces of plain coarse potteries. Color of the these potteries are mainly light brown, partly shows the yellowish brown to reddish brown. The interior, surface and inside of the pottery appear as different colors in any cases. Original source materials making the Unjeonri potteries are used of mainly sandy clay soil with extreme coarse grained irregularly quartz and feldspar. The magnetic susceptibility of the Unjeonri pottery range from 0.20 to 1.20. And the Unjeonri soil's magnetic susceptibility agree almost with 0.20 to 1.30. In the same magnetization of soil and pottery, the results revealed that the Unjeonri soil and low material of pottery are same produced by identical source materials. The Unjeonri potteries and soil are very similar patterns with all characteristics of soil mineralogy, geochemical evolution trend. The result seems to be same relationships between the behavior and enrichment patterns on the basis of a compatible and a incompatible elements. Consequently, the Unjeonri potteries suggest that made the soil to be distributed in the circumstance of the relic sites as the raw material are high in a greater part. In the Unjeonri soil, the kaolinite is common occurred minerals. However, in the Unjeonri pottery, the kaolinite was not detected in all broken pieces. The kaolinite was presumed to destroy crystal structure during the firing processes of over $550^{\circ}C$. The quartz is phase transition from ${\alpha}$-quartz to ${\beta}$-quartz at $573^{\circ}C$, but the Unjeonri pottery did not investigated any phase transition evidences of quartz. The chorite was detected within the mostly potteries and soils. As the results, the Unjeonri potteries can be interpreted by not experiencing a firing temperature over $800^{\circ}C$. The colloidal and cementing materials between the quartz and low materials during the heating did not exist in the internal part of the potteries. An any secondary compounds by heating does not appear within the crack to happen during the dry of the pottery. The hyphae group are kept as it is with the root tissue of an organic matters to live in the swampy land. In the syntheses of all results, the general firing condition to bake and make the Unjeonri pottery is presumed from $550^{\circ}C$ to $800^{\circ}C$. However, the firing condition making the Unjeonri pottery can be different firing temperature partially in one pottery. Even, the some part of the pottery does not take a direct influence on the fire.