• Title/Summary/Keyword: $({\alpha}-phase$

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Two New Correlations for Predicting Detonating Power of CHNO Explosives

  • Keshavarz, M.H.;Oftadeh, M.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.19-22
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    • 2003
  • For CHNO explosives, two new correlations of the form $P_{CJ}\;=\;8.7({\alpha}T_c')^{1/2}{\rho}_0^2-5\;and\;P_{CJ}\'=\'9.5({\alpha}T_c')^1/2{\rho}_0^2-9$ have been demonstrated, which relate detonation pressure, $P_{CJ}$; combustion temperature of the explosive in gas phase, $T_c$; combustion temperature of the explosive in crystalline state, $T_c'$; and the number of moles of gaseous products per unit weight of explosive, α; at initial density of the explosive, ${\rho}_0$. Experimental and semi-empirical PM3 procedures were used for the computation of $T_c$. Detonation pressures derived in this manner have a simple form without need to use computer code.

Fabrication and Mechanical Properties of Porous Silicon Carbide Ceramics from Silicon and Carbon Mixture (실리콘과 카본을 이용한 다공질 탄화규소의 제조와 기계적 특성)

  • Kim, Jong-Chan;Lee, Eun Ju;Kim, Deug-Joong
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.429-433
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    • 2013
  • Silicon, carbon, and B4C powders were used as raw materials for the fabrication of porous SiC. ${\beta}$-SiC was synthesized at $1500^{\circ}C$ in an Ar atmosphere from a silicon and carbon mixture. The synthesized powders were pressed into disk shapes and then heated at $2100^{\circ}C$. ${\beta}$-SiC particles transformed to ${\alpha}$-SiC at over $1900^{\circ}C$, and rapid grain growth of ${\alpha}$-SiC subsequently occurred and a porous structure with elongated plate-type grains was formed. The mechanism of this rapid grain growth is thought to be an evaporation-condensation reaction. The mechanical properties of the fabricated porous SiC were investigated and discussed.

Properties of $SiC/MoSi_2$ Composites Prepared by Reaction Sintering Method (반응소결에 의한 $SiC/MoSi_2$ 복합체의 특성)

  • 한인섭;양준환;서동수
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.399-406
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    • 1994
  • The SiC/MoSi2 composite material was prepared by infiltration with the mixture of metal Si and MoSi2 into the preform of $\alpha$-SiC and graphite under the vacuum atmosphere of 10-1 torr. The mechanical properties, phases and microstructural characteristics have been investigated by employing an universal testing machine, scanning electron microscope and X-ray diffractometer. With the increase of MoSi2/Si mixing content, the quantity of the residual silicon phase was decreased and the hardness and fracture toughness of composite materials were increased. Also, as the infiltration temperature increased, a lot of fine-grained $\beta$-SiC phases, which were produced from the reaction of graphite and liquid silicon melt, were transformed to $\alpha$-SiC phases.

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Mechanical Properties of Silicon Carbide-Silicon Nitride Composites Sintered with Yttrium Aluminum Garnet (YAG상 첨가 탄화규소-질화규소 복합재료의 기계적 특성)

  • 이영일;김영욱;최헌진;이준근
    • Journal of the Korean Ceramic Society
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    • v.36 no.8
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    • pp.799-804
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    • 1999
  • Composites of SiC-Si3N4 consisted of uniformly distributed elongated $\beta$-Si3N4 grains and equiaxed $\beta$-SiC grains were fabricated with $\beta$-SiC,. $\alpha$-Si3N4 Al2O3 and Y2O3 powders. By hot-pressing and subsequent annelaing elongated $\beta$-Si3N4 grains were grown via$\alpha$longrightarrow$\beta$ phase transformation and equiaxed $\beta$-Si3N4 composites increased with increasing the Si3N4 content owing to the reduced defect size and enhanced crack deflection by elongated $\beta$-Si3N4 grains and the grain boundary strengthening by nitrogen incorporation. Typical flexural strength and fracture toughness of SiC-40 wt% Si3N4 composites were 783 MPa and 4.2 MPa.m1/2 respectively.

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Dielectric Relaxation Time of Long Chain Fatty Acid Langmuir films (장쇄지방산 L막의 완화 시간)

  • Cho, Dong-Kyu;Chang, Hun;Oh, Jae-Han;Gang, Yong-Chul;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.279-282
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    • 2000
  • The displacement current measurement has been employed to study the dielectric properties of Langmuir films. A method for determining the dielectric relaxation time $\tau$ of floating monolayers on water surface is presented. The displacement current flowing across monolayers is analyzed using a rod-like molecular model. It's revealed that the dielectric relaxation time $\tau$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayers compression speed $\alpha$ and the molecular maximum area $A_{m}$. The compression speed $\alpha$ was about 30, 40, 50mm/minmm/min

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Dielectric Relaxation Phenomena of Arac.acid (Arac.acid의 유전완화현상)

  • Song, Jin-Won;Cho, Su-Young;Lee, Young-Gil;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2003.07c
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    • pp.1583-1585
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    • 2003
  • Maxwell displacement current(MDC) measuring technique has been employed to study the dielectric property of Langmuir-films. A method for determining the dielectric relaxation time ${\tau}$ of floating monolayers on the water surface is presented. MDC flowing across monolayers is analyzed using a rod-like molecular model. It is revealed that the dielectric relaxation time ${\tau}$ of monolayers in the isotropic polar orientational phase is determined using a liner relationship between the monolayer compression speed ${\alpha}$ and the molecular area Am. Compression speed ${\alpha}$ was about 30, 40, 50mm/min.

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Fabrication of Deep-Sub-Millimeter-Thick Compacts Using Spark Plasma Sintering

  • Ohashi, T.;Tanaka, T.;Oshiro, K.;Fujimori, H.;Kurisu, H.;Matsuura, M.;Yamamoto, S.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.270-271
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    • 2006
  • Nd-Fe-B type powder was sintered using spark plasma sintering method. Fabricated compact sintered at the temperature of $700\;^{\circ}C$, is found to be a composite magnet with Nd-Fe-Co-B and ${\alpha}-Fe$. The compact sintered at $700\;^{\circ}C$ shows slightly low coercivity and large remanent magnetization comparing to the compact sintered at $600^{\circ}C$ due to the formation of ${\alpha}-Fe$ phase, resulting in the large maximum energy product. Maximum energy product tends to decrease with decreasing thickness of sintered compacts below 0.5 mm in thickness.

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Synthesis of ($\pm$)-Methyl-(1-aryl-4-pyridin-3-yl-but-3-enyl)-amines

  • Jang, Jin-Hee;Sin, Kwan-Seog;Park, Hae-Il
    • Archives of Pharmacal Research
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    • v.24 no.6
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    • pp.503-507
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    • 2001
  • trans-Metanicotine, a subtype (${\alpha}_4{\beta}_2$)-selective ligand for neuronal nicotinic acetylcholine receptor, is under clinical phase for Alzheimer's disease. An efficient synthetic route for ($\pm$)-methyl-(1-aryl-4-pyridin-3-yl-but-3-enyl)-am ices, derivatives of tracts-metanicotine, was explored. Allylation reaction of aryl aldimines with allylmagnesium bromide in THF gave ($\pm$)-methyl-(1-aryl-but-3-enyl)-amines. Protection of the amines with the Boc group and following Heck reaction of the N-Boc amines with 3-bromopyridine gave ($\pm$)-methyl-(1-aryl-4-pyridin-3-yl-but-3-enyl)-carbamic acid tert-butyl esters. Deprotection of the N-Boc group in aqueous 1 N-HCI solution gave the titled amines in good yields. Thus, trans-metanicotine analogues modified at the ${\alpha}-position$ of the methylamino group with amyl groups were obtained in 5 steps.

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C/EBP$\beta$ and Nrf2-Mediated GSTA2 Induction by $\alpha$-Lipoic acid, an Insulin-Sensitizing Agent that has Antioxidant and Prooxidant Activities

  • Ki, Sung-Hwan;Cho, Il-Je;Kim, Sang-Geon
    • Proceedings of the PSK Conference
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    • 2003.10b
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    • pp.82.1-82.1
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    • 2003
  • The protective adaptive response to electrophiles and reactive oxygen species is mediated by enhanced expression of phase II detoxifying genes including glutathione S-transferases. ${\alpha}$-Lipoic acid, which exerts prooxidant or antioxidant activities, has been shown to activate the insulin signaling pathway and thus to induce insulin-like actions via PI3-kinase and Akt. Our previous studies have shown that PI3-kinase plays an essential role in Nrf2-or C/EBP${\beta}$-mediated glutathione S-transferase A2 (GSTA2) induction. (omitted)

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Aging Behavior and Effect of Heat Treatment on High Temperature Mechanical Properties in Ti-15V-3AI-3Cr-3Sn (Ti-15V-3Al합금의 시효거동과 열처리에 따른 고온 기계적 특성)

  • Lee Jae Won;Lee Back-Hee;Lee Kyu Hwan;Kim Young Do
    • Korean Journal of Materials Research
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    • v.14 no.1
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    • pp.13-18
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    • 2004
  • Titanium alloys are the one of promising candidate materials for medium high temperature parts in the aircraft, automobile, petrochemistry and electrochemistry because of their high strength with low density in medium high temperature. In this study, the effects of aging and heat treatments on the mechanical properties of Ti-15-3 alloy in medium high temperature, which was $400^{\circ}C$, were studied. Solid solution treatment was performed at $8000^{\circ}C$ of $\beta$ phase region for 1 h and the alloy was quenched in water. The alloy was aged at $5000^{\circ}C$ of $\alpha$ and $\beta$ two-phase region for 1, 2, 4, 8, ... and 100 h to increase the mechanical property. The $\beta$ single phase was observed at all parts of specimens in Ti-15-3 alloy after ST. As the aging at $500^{\circ}C$, fine precipitates of a phase was generated from matrix of $\beta$ phase and the microstructure was consisted of weaving structure such as Widmanstiitten a phase. The most suitable aging time is 24h in$ 400^{\circ}C$. At this time, strength is 1164 MPa and elongation is about 12%. In room temperature, elongation of Ti-15-3 alloy aged at $500^{\circ}C$ for 16 h is poor (=3%) in spite of high tensile strength (1458 MPa).