In this study, the effects of Zn-based colorants on plastic degradation and the corrosion of metals in contact with degraded plastics were investigated. Poly (butylene terephthalate) (PBT) and Polyamide6,6 (PA66) were used as base resins and compounded with ZnO, ZnS, and TiO2 as white colorants. It was confirmed that the flexural strength dramatically decreased under accelerated conditions of 130℃ and 85% RH only when ZnS or ZnO was added to the ester-based PBT compounds. Under high temperature and humidity conditions, the added Zn-based colorants acted as strong Lewis acids in the form of Zn2+ ions, thereby accelerating the hydrolysis of PBT. FT-IR spectroscopy and end-group analysis of the degraded PBT confirmed that the ester linkages were depolymerized to generate carboxylic acids. Carboxylic acids derived from PBT degradation attacked contacting aluminum, causing surface corrosion and the release of Al3+ ions. This process eventually resulted in the formation of white aluminum oxides and aluminum hydroxides, such as Al2O3 and Al(OH)3. Furthermore, the Al3+ ions released during corrosion acted as Lewis acid catalysts, similar to Zn2+ ions, thereby accelerating the degradation of PBT. In conclusion, the catalytic degradation of PBT by Zn-based colorants and the corrosion mechanism of aluminum induced by the carboxylic acids from degraded PBT were chemically elucidated. Based on these findings, material specifications were updated to prohibit the use of Zn-based colorants in ester-based plastics.