DOI QR코드

DOI QR Code

Characteristics of Wood Plastic Composites from Four Blend Ratios of Alkali-Treated Ulin (Eusideroxylon zwageri) and Sengon (Falcataria moluccana) Wood Flour

  • Isna Yuniar WARDHANI (Study Program of Forestry, Faculty of Forestry and Tropical Environment, Mulawarman University) ;
  • Nopriyanto PAI'PIN (Study Program of Forestry, Faculty of Forestry and Tropical Environment, Mulawarman University) ;
  • Sri Asih HANDAYANI (Study Program of Forestry, Faculty of Forestry and Tropical Environment, Mulawarman University) ;
  • Fitria Cita DIRNA (Study Program of Forestry, Faculty of Forestry and Tropical Environment, Mulawarman University)
  • Received : 2025.05.14
  • Accepted : 2025.08.12
  • Published : 2025.09.25

Abstract

In this study, we investigated the effects of wood flour composition (ulin and sengon) and 5% NaOH alkali treatment on the physical and mechanical properties of wood-plastic composites bonded with unsaturated polyester resin. Four formulations were developed using different blend ratios of ulin and sengon, with alkali treatment applied only to ulin-wood flour. The physical tests evaluated density, moisture content, water absorption, and swelling thickness. The mechanical evaluations included the modulus of elasticity (MOE), modulus of rupture (MOR), tensile strength, impact strength, and internal bond strength (IBS). Analysis of variance results (α = 0.05) showed that treatment variations significantly affected all physical properties except density, and significantly influenced mechanical properties such as MOE, MOR, tensile strength, and IBS. No significant differences were observed in impact strength. The best mechanical performance was achieved by P4, which recorded the highest MOE (1,001.4 N/mm2), MOR (12.04 N/mm2), tensile strength (8.12 N/mm2), and impact strength (0.0084 J/mm2). P1 exhibited the highest IBS value (1.52 MPa). Although none of the treatments met the structural strength thresholds of SNI 8514:2015, the composites exhibited adequate dimensional stability and mechanical consistency. When benchmarked against the ASTM D7031 and JIS A 5908 performance guidelines, these results support their potential use in nonstructural applications, such as indoor cladding, ceiling panels, partition walls, and furniture components, especially in applications where dimensional stability and moisture resistance are more critical than high mechanical strength.

Keywords

Acknowledgement

The author would like to express sincere gratitude to the Dean of the Faculty of Forestry and Tropical Environment, Mulawarman University, Prof. Dr. Irawan Wijaya Kusuma, S. Hut., and M.P. for their valuable support and opportunity to carry out this research. Special appreciation is also extended to Vice Dean I for Academic Affairs and Prof. Dr. Harlinda Kuspradini, S. Hut., M.P., for the research funding assistance that made this study possible. Their support was instrumental in the successful completion of this research project.

References

  1. Ayrilmis, N., Jarusombuti, S., Fueangvivat, V., Bauchongkol, P., White, R.H. 2011. Coir fiber reinforced polypropylene composite panel for automotive interior applications. Fibers and Polymers 12(7): 919-926. https://doi.org/10.1007/s12221-011-0919-1
  2. Bafti, H., Habibolahzadeh, A. 2013. Compressive properties of aluminum foam produced by powder-carbamide spacer route. Materials & Design 52: 404- 411. https://doi.org/10.1016/j.matdes.2013.05.043
  3. Bhat, P., Merotte, J., Simacek, P., Advani, S.G. 2009. Process analysis of compression resin transfer molding. Composites Part A: Applied Science and Manufacturing 40(4): 431-441. https://doi.org/10.1016/j.compositesa.2009.01.006
  4. Chang, C., Dan, H., Zhang, L.P., Chang, M.X., Sheng, Y.F., Zheng, G.H., Zhang, X.Z. 2014. Fabrication of thermoresponsive, core-crosslinked micelles based on poly[N-isopropyl acrylamide-co-3-(trimethoxysilyl)propylmethacrylate]-b-poly{N-[3-(dimethylamino)propyl]methacrylamide} for the codelivery of doxorubicin and nucleic acid. Journal of Applied Polymer Science 132(15): 41752. https://doi.org/10.1002/app.v132.15
  5. Cheah, C.B., Part, W.K., Ramli, M. 2017. The long term engineering properties of cementless building block work containing large volume of wood ash and coal fly ash. Construction and Building Materials 143: 522-536. https://doi.org/10.1016/j.conbuildmat.2017.03.162
  6. Chotikhun, A., Arsyad, W.O.M., Salca, E.A., Hadi, Y.S., Hiziroglu, S. 2024. Resistance of wood plastic composites having silica filler to subterranean termite. Journal of the Korean Wood Science and Technology 52(4): 331-342. https://doi.org/10.5658/WOOD.2024.52.4.331
  7. Das, S.N., Pradhan, S.K. Bhuyan, S. 2021. Structural, morphological and magnetoelectric properties of (Bi0.6Ni0.2Ba0.2)(Fe0.6Ti0.4)O3 electronic material. Materials Today: Proceedings 35(Part 2): 102-105. https://doi.org/10.1016/j.matpr.2020.03.172
  8. Davallo, M., Pasdar, H., Mohseni, M. 2010. Mechanical properties of unsaturated polyester resin. International Journal of ChemTech Research 2(4): 2113-2117.
  9. Deka, B.K., Maji, T.K. 2011. Study on the properties of nanocomposite based on high density polyethylene, polypropylene, polyvinyl chloride and wood. Composites Part A: Applied Science and Manufacturing 42(6): 686-693. https://doi.org/10.1016/j.compositesa.2011.02.009
  10. Dirna, F.C. 2024. The effect of impregnation treatment with MEG and PEG on the color of Solomon teak wood. Perennial 20(2): 67-72. https://doi.org/10.24259/perennial.v20i2.37287
  11. Dirna, F.C., Wahyuningtyas, I. 2025. Ketahanan kayu jabon dan sengon terhadap serangan rayap kayu kering Cryptotermes cynocephalus light. Terra: Journal of Forest Management 1(1): 52-62.
  12. Franke, T., Volkmer, T. 2021. Mineralization treatment of European oak heartwood with calcium oxalate for improved fire retardancy. Holzforschung 76(1): 77-88. https://doi.org/10.1515/hf-2021-0055
  13. Gapsari, F., Setyarini, P.H. 2010. Pengaruh fraksi volume terhadap kekuatan tarik dan lentur komposit resin berpenguat serbuk kayu. Jurnal Rekayasa Mesin 1(2): 59-64.
  14. Gassan, J., Bledzki, A.K. 1997. The influence of fiber-surface treatment on the mechanical properties of jute-polypropylene composites. Composites Part A: Applied Science and Manufacturing 28(12): 1001-1005. https://doi.org/10.1016/S1359-835X(97)00042-0
  15. Gurau, L., Ayrilmis, N. 2018. Effect of raw material composition of wood plastic composites on surface roughness parameters evaluated with a robust filtering method. Journal of Thermoplastic Composite Materials 32(4): 427-441. https://doi.org/10.1177/0892705718759391
  16. Gurunathan, T., Mohanty, S., Nayak, S.K. 2015. A review of the recent developments in biocomposites based on natural fibres and their application perspectives. Composites Part A: Applied Science and Manufacturing 77: 1-25. https://doi.org/10.1016/j.compositesa.2015.06.007
  17. Hadi, Y.S., Herliyana, E.N., Pari, G., Pari, R., Abdillah, I.B. 2022. Furfurylation effects on discoloration and physical-mechanical properties of wood from tropical plantation forests. Journal of the Korean Wood Science and Technology 50(1): 46-58. https://doi.org/10.5658/WOOD.2022.50.1.46
  18. Keya, K.N., Kona, N.A., Hossain, M.S., Razzak, M., Islam, M.N., Khan, R.A. 2019. Preparation and characterization of polypropylene and unsaturated polyester resin filled with jute fiber. Advanced Materials Research 1156: 60-68. https://doi.org/10.4028/www.scientific.net/AMR.1156
  19. Khalil, H.P.S.A., Bhat, I.U.H., Jawaid, M., Zaidon, A., Hermawan, D., Hadi, Y.S. 2012. Bamboo fibre reinforced biocomposites: A review. Materials & Design 42: 353-368. https://doi.org/10.1016/j.matdes.2012.06.015
  20. Khan, M.M.H., Deviatkin, I., Havukainen, J., Horttanainen, M. 2021. Environmental impacts of wooden, plastic, and wood-polymer composite pallet: A life cycle assessment approach. The International Journal of Life Cycle Assessment 26(8): 1607-1622. https://doi.org/10.1007/s11367-021-01953-7
  21. Laksono, G.D., Rahayu, I.S., Karlinasari, L., Darmawan, W., Prihatini, E. 2023. Characteristics of magnetic sengon wood impregnated with nano Fe3O4 and fufuryl alcohol. Journal of the Korean Wood Science and Technology 51(1): 1-13. https://doi.org/10.5658/WOOD.2023.51.1.1
  22. Lee, I., Oh, W. 2022. Flexural modulus of larch boards laminated by adhesives with reinforcing material. Journal of the Korean Wood Science and Technology 51(1): 14-22. https://doi.org/10.5658/WOOD.2023.51.1.14
  23. Lestary, C.A., Azwar, A., Asri, A. 2022. Sifat fisis dan mekanis wood plastic composite berbahan serbuk kayu lamtoro dan limbah plastik. Wahana Fisika 2(2): 104-115. https://doi.org/10.17509/wafi.v7i2
  24. Marketsandmarkets. 2024. Wood plastic composites market. https://www.marketsandmarkets.com/Market-Reports/wood-plastic-composite-market-170450806.html?utm_source=chatgpt.com
  25. Nawawi, D.S., Maria, A., Firdaus, R.D., Rahayu, I.S., Fatrawana, A., Pramatana, F., Sinaga, P.S., Fatriasari, W. 2023. Improvement of dimensional stability of tropical light-wood Ceiba pentandra (L) by combined alkali treatment and densification. Journal of the Korean Wood Science and Technology 51(2): 133-144. https://doi.org/10.5658/WOOD.2023.51.2.133
  26. Nurwendi, H., Simpen, I.N., Negara, I.M.S. 2016. Sintesis komposit selulosa serbuk gergaji kayu kamper-limbah plastik LDPE (low density poliethylene) dengan reagen fenton sebagai agen pengkopling. Jurnal Kimia 10(1): 89-95. https://doi.org/10.24843/JCHEM.2016.v10.i01
  27. Rahayu, I., Dirna, F.C., Maddu, A., Darmawan, W., Nandika, D., Prihatini, E. 2021. Dimensional stability of treated sengon wood by nano-silica of betung bamboo leaves. Forests 12(11): 1581. https://doi.org/10.3390/f12111581
  28. Rahman, M.B.N., Sudarisman, S., Nugroho, E. 2018. Pengaruh ukuran butir, fraksi volume dan penambahan aseton terhadap kekuatan flexural komposit papan partikel serbuk gergaji kayu sengon-matrik polyester. JMPM: Jurnal Material dan Proses Manufaktur 2(2): 110-118.
  29. Rimdusit, S., Damrongsakkul, S., Wongmanit, P., Saramas, D., Tiptipakorn, S. 2011. Characterization of coconut fiber-filled polyvinyl chloride/acrylonitrile styrene acrylate blends. Journal of Reinforced Plastics and Composites 30(20): 1691-1702. https://doi.org/10.1177/0731684411427484
  30. Rowell, R.M. 2012. Handbook of Wood Chemistry and Wood Composites. CRC Press, Boca Raton, FL, USA.
  31. Sari, A.L.R., Winarti, Ulva, S.M., Sulaiman, D. 2023. Pemanfaatan limbah potongan kayu ulin menjadi cuka kayu melalui proses kondensasi menggunakan reaktor drum bekas. Jurnal Sains Benuanta 2(2): 9-17.
  32. Setiawan, D., Hidayat, A., Supriyadi, S., Lestari, W. 2023. Environmental ethics policy in Jepara: Optimization of handicraft designs from wood waste in the furniture industry. Journal of the Korean Wood Science and Technology 51(5): 392-409. https://doi.org/10.5658/WOOD.2023.51.5.392
  33. Spigarelli, S., Paoletti, C. 2018. A new model for the description of creep behaviour of aluminium-based composites reinforced with nanosized particles. Composites Part A: Applied Science and Manufacturing 113: 346-355. https://doi.org/10.1016/j.compositesa.2018.06.021
  34. Vedat, C. 2020. Selected properties of mahogany wood flour filled polypropylene composites: The effect of maleic. Bio Resources 15(2): 2227-2236.
  35. Wanishdilokratn, T., Wanishdilokratn, J. 2024. Influence of adding silicon dioxide in particleboard from teak sawdust to reduce water absorption and thickness swelling. Journal of the Korean Wood Science and Technology 52(5): 438-449. https://doi.org/10.5658/WOOD.2024.52.5.438
  36. Widiastuti, I., Panuntun, A.B., Seno, E.B., Towip, Sutrisno, V.L.P., Pramesti, G. 2025. Mechanical properties and water absorption behaviour of virgin/recycled polypropylene wood waste composites: A comparative analysis of injection and compression moulding. Journal of the Korean Wood Science and Technology 53(2): 164-176. https://doi.org/10.5658/WOOD.2025.53.2.164
  37. Wu, J., Yixiu, Z., Zhong, T., Zhang, W., Chen, H. 2023. Bamboo slivers with high strength and toughness prepared by alkali treatment at a proper temperature. Journal of Wood Science 69(1): 13. https://doi.org/10.1186/s10086-023-02084-3
  38. Wulan, T.C., Sari, D.P., Hartini, S., Azzahra, F. 2025. Leveraging integrated quality function deployment (QFD) and theory of solving problems inventively, eco-efficiency (TRIZEE) methodologies for sustainable innovation in chair design through wood waste to enhance eco-efficiency. Journal of the Korean Wood Science and Technology 53(3): 324-342. https://doi.org/10.5658/WOOD.2025.53.3.324
  39. Zhao, N., Wang, S., Quan, X., Liu, K., Xu, J., Xu, F. 2022. Behavior of fiber reinforced cementitious composites under the coupled attack of sulfate and dry/wet in a tidal environment. Construction and Building Materials 314(Part A): 125673. https://doi.org/10.1016/j.conbuildmat.2021.125673
  40. Zhou, W., Wang, C., Ai, T., Wu, K., Zhao, F., Gu, H. 2009. A novel fiber-reinforced polyethylene composite with added silicon nitride particles for enhanced thermal conductivity. Composites Part A: Applied Science and Manufacturing 40(6–7): 830- 836. https://doi.org/10.1016/j.compositesa.2009.04.005
  41. Zou, J., Duan, H., Chen, Y., Ji, S., Cao, J., Ma, H. 2020. A P/N/S-containing high-efficiency flame retardant endowing epoxy resin with excellent flame retardance, mechanical properties and heat resistance. Composites Part B: Engineering 199: 108228.
  42. Zyryanov, M., Medvedev, S., Mokhirev, A. 2024. Investigation of the fiberboard production process with the addition of coniferous wood greenery. Journal of the Korean Wood Science and Technology 52(6): 525-538. https://doi.org/10.5658/WOOD.2024.52.6.525