한국환경과학회지 (Journal of Environmental Science International)

  • 제33권9호
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  • Pages.645-665
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  • 2024
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  • 1225-4517(pISSN)
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  • 2287-3503(eISSN)
한국환경과학회 (The Korean Environmental Sciences Society)
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녹산국가산단의 대기질 개선 및 관리방안: 휘발성유기화합물질 위주로

Improving and Managing Air Quality in Noksan National Industrial Complex: Focus on Volatile Organic Compounds

  • 강종민 (부산광역시 보건환경연구원)
  • Jong-min Kang (Busan Metropolitan City Institute of Health & Environment)
  • 투고 : 2024.07.22
  • 심사 : 2024.09.05
  • 발행 : 2024.09.30
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초록

For volatile organic compounds (VOCs) emanating from workplaces within the Noksan national industrial complex, the emission characteristics of pollutants were identified through zone-based measurements using vehicles equipped with selective ion flow tube mass spectrometry(SIFT-MS). The average concentration of total VOCs was higher in zones 2, 4, and 5 than in zones 1, 3, and 6, and was 2.1 to 4.2 times higher than background concentrations. The average concentrations of pollutants investigated were (from highest to lowest) methyl ethyl ketone, formaldehyde, methanol, and n-hexane. However, the pollutants that should be prioritized for reduction to decrease ozone generation were (from highest to lowest) methyl ethyl ketone, n-hexane, for maldehyde, and ethylbenzene+xylene. Benzene, a substance governed by atmospheric environmental standards, exhibited a frequency distribution exceeding the stipulated limits, and concentrations exceeding 100 ppb were identified for methyl ethyl ketone, methanol, toluene, and n-hexane. In certain class 4 and 5 workplace facilities, VOC emissions and emission prevention installations were inadequately managed, necessitating the formulation of management measures for small enterprises. Also, workplaces that emit large amounts of VOCs need to upgrade to VOC-prevention installations with higher processing efficiencies. To efficiently monitor VOCs in a wide range of areas, such as the Noksan national industrial complex, it is considered appropriate to monitor workplaces that emit high concentrations of VOCs using mobile SIFT-MS in real time rather than relying on fixed monitoring methods. A specialized method targeting approximately 10 VOCs is necessary to quickly track emission sources.Furthermore, it is essential to phase in a system for the intensive management of suspected workplaces based on accumulated data from SIFT-MS in areas where high VOC concentrations are measured and to establish a cooperative system for sharing data between relevant institutions.

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과제정보

본 논문은 환경부의 재원으로 국립환경과학원의 지원(과제번호 2024-01-03-001)을 받아 수행하였습니다.

참고문헌

  1. Kim, J. B., Park, D. S., Park, S. H., Versoza M., Lee, Y. G., Lee, S. S., Park, J. S., Kim, J. H., 2019, Concentration characteristics of particulate matter and volatile organic compounds in petrochemical industrial complex using real-time monitoring devices, J. Korean Soc. Atmos. Environ., 35(6), 683-700.
  2. Youn, S. J., Jo, K. H., Kim, H. Y., Song, G. B., Lee, S. B., Jeong, J. Y., 2020, Measurement of hazardous air pollutants in industrial complex using mobile measurement system with SIFT-MS, J. Korean Soc. Atmos. Environ., 36(4), 507-521.
  3. Choi, S. W., Park, S. W., Cha, Y. W., Lee, S. I., Yoo, E. C., 2021, The characteristics of air pollutants distribution around industrial complexes using real-time mobile atmospheric measurement system, J. Korean Soc. Environ. Eng., 43(6), 476-489.
  4. Yu, B. G., Tak, K. H., Lee, D. W., 2022, Characteristics of concentration distribution of volatile organic compounds in Ulsan using SIFT-MS, J. Korean Soc. Environ. Eng., 44(11), 406-417.
  5. Syft technologies. Co. Ltd., 2019, SYFT voice 200 ULTRA advanced SIFT mass spectrometer operation manual.
  6. DAUM encyclopedia, 2023, https://100.daum.net/encyclopedia/view/b04n0271a.
  7. Son, H. D., An, J. G., Ha, S. Y., Kim, G. B., Yim, U. H., 2018, Development of real-time and simultaneous quantification of volatile organic compounds in ambient with SIFT-MS (Selected ion flow tube-mass spectrometry), J. Korean Soc. Atmos. Environ., 34(3), 393-405.
  8. National Institute of Environmental Research, 2021, Selective ion flow tube mass spectrometry operating guidelines.
  9. National Institute of Chemical Safety, 2023, Pollutant release and transfer registers, https://icis.me.go.kr/prtr/main.do.
  10. Ministry of Environment and National Institute of Chemical Safety, 2023, Chemical emissions survey guidelines.
  11. Ministry of Employment and Labor, 2023, Occupational safety and health act.
  12. Choi, I. J., Lee, D. W., Tak, K. H., Jo, J. H., 2023, A Study on the characteristics of HAPs in residential areas affected by industrial complex using SIFT-MS, J. Korean Soc. Environ. Eng., 45(1), 21-33.
  13. U.S.EPA (United States Environmental Protection Agency), 2023, Acute exposure guideline levels, https://www.epa.gov/aegl.
  14. Youn, S. J., 2021, Monitoring of hazardous air pollutants and emission sources tacking with real time mass spectrometer (SIFT-MS), Ph.D. Dissertation, Pukyong National University, Busan, Korea.
  15. Lee, J. H., Han, J. S., Yun, H. K., Cho, S. Y., 2007, Evaluation of incremental reactivity and ozone production contribution of VOCs using the PAMS data in Seoul Metropolitan area, J. Korean Soc. Atmos. Environ., 23(3), 286-296.
  16. Carter, W. P. L., 1994, Development ozone reactivity scales for volatile organic compounds, Journal of the Air and Waste Management Association, 44(7), 881-899.
  17. Cheng, H. R., Guo, H., Saunders, S. M., Lam, S. H. M., Jiang, F., Wang, X. M., Simpson, I. J., Blake, D. R., Louie, P. K. K., Wang, T. J., 2010, Assessing photochemical ozone formation in the Pearl River Delta with a photochemical trajectory model, Atmospheric Environment, 44(34), 4199-4208.