Journal of Food Hygiene and Safety (한국식품위생안전성학회지)

The Korean Society of Food Hygiene and Safety (한국식품위생안전성학회)
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Monitoring Pesticide Residues in Commercial Dried Red Peppers and Pepper Powders

유통 건고추와 고춧가루의 잔류농약 안전성 조사

  • Yoo-Li Han (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Hyun-Ju Kim (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Sang-Tae Kim (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Nan-Joo Park (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Yu-Na Song (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Yu-Mi Choi (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Hye-Yeoun Lee (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Bo-Min Son (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Youn-Ho Kim (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Jeong-Hwa Seo (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Jong-Sung Son (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Myoung-Ki Park (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment) ;
  • Yong-Bae Park (Guri Agricultural and Fishery Products Inspection Center, Gyeonggi province Institute of Health and Environment)
  • 한유리 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 김현주 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 김상태 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 박난주 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 송유나 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 최유미 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 이혜연 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 손보민 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 김윤호 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 서정화 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 손종성 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 박명기 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소) ;
  • 박용배 (경기도보건환경연구원 농수산물검사부 구리농수산물검사소)
  • Received : 2024.06.07
  • Accepted : 2024.06.14
  • Published : 2024.06.30
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Abstract

Pesticide residues were monitored in dried red pepper and pepper powder samples purchased in Northern Gyeonggi-do and from domestic online markets. The QuEChERS method was used to prepare 88 samples. GC-MS/MS and LC-MS/MS were used to analyze 338 pesticide residues. In the study, pesticide residues were detected in 70 samples (79.5%), with residues exceeding the maximum residue limits (MRL) in 4 samples (4.5%). Pesticide levels exceeded the MRL in imported samples, with two samples of dried red pepper and two samples of pepper powder showing elevated levels. Among the 61 pesticides detected, tebuconazole, a fungicide was most frequently detected (52 times). Tricyclazole, which is used to control the main disease affecting rice, exceeding the MRL in 3 of 12 Vietnam-origin samples. Ethion exceeded the MRL in one Indian-origin sample. Both tricyclazole and ethion are banned for use in pepper products in Korea and are regulated under the positive list system (PLS). Conversely, pesticides detected in domestic samples were within the MRLs. Therefore, authorities should monitor pesticide residues in imported red pepper products.

본 연구에서는 경기 북부지역 및 온라인에서 유통되는 건고추 및 고춧가루 88건을 대상으로 잔류농약을 분석했다. 시료는 QuEChERS법으로 전처리한 후 GC-MS/MS, LC-MS/MS를 이용하여 분석했다. 88건 중 70건(79.5%)에서 잔류농약이 검출되었고 그 중 4건(4.5%)인 수입산 건고추 2건, 수입산 고춧가루 2건이 농약 잔류허용기준을 초과하였다. 총 61종의 농약이 검출되었고 검출 빈도가 가장 높은 농약은 살균제 tebuconazole로 52회 검출되었다. 쌀에 사용하는 진균제 tricyclazole은 베트남산 시료 12개 중 3개 시료에서, ethion은 인도산 시료 1개에서 농약 잔류허용기준을 초과하여 검출되었다. tricyclazole과 ethion은 고추 품목에서의 사용이 금지되어 positive list system 제도에 의해 규제되고 있다. 본 연구를 통해 국내산 건고추 및 고춧가루의 잔류농약 수준이 비교적 잘 관리되고 있으며 수입산 건고추 및 고춧가루에 대한 지속적인 관리가 필요한 것으로 확인하였다.

Keywords

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