DOI QR코드

DOI QR Code

Comparison of chemical resistance properties of anodized film according to anodized sealing treatment method of Al6061 alloy

Al6061 합금의 양극산화 봉공 처리 방법에 따른 양극산화 피막의 내화학 특성 비교

  • Young Uk Han (R&D center, YKMC Inc.) ;
  • Sang Sub Lee (R&D center, YKMC Inc.) ;
  • Jun Seok Lee (R&D center, YKMC Inc.) ;
  • Gibum Jang (YKMC Inc.) ;
  • Sung Youl Cho (R&D center, YKMC Inc.)
  • 한영욱 ((주)영광와이케이엠씨 연구개발센터) ;
  • 이상섭 ((주)영광와이케이엠씨 연구개발센터) ;
  • 이준석 ((주)영광와이케이엠씨 연구개발센터) ;
  • 장기범 ((주)영광와이케이엠씨) ;
  • 조성열 ((주)영광와이케이엠씨 연구개발센터)
  • Received : 2024.04.16
  • Accepted : 2024.05.16
  • Published : 2024.06.30

Abstract

This study compared the chemical resistance properties according to various sealing treatment methods for the anode film formed during the anodization process of Al6061 alloy. Al6061 aluminum was used in four different sealing treatment methods: boiling water sealing, lithium sealing, nickel sealing, and pressurized sealing, and each sample was evaluated for corrosion resistance through a 5% HCl bubble test and the microstructure was observed through a scanning electron microscope(SEM). According to the results, corrosion resistance increased as time and temperature increased in all sealing treatment methods. Relatively, corrosion resistance was high in the order of boiling water sealing, lithium sealing, nickel sealing, and pressure sealing, and the best corrosion resistance was found in pressure sealing. These research results can be helpful in selecting a process necessary to improve the efficiency and performance of anodizing process in the industrial field using aluminum alloys.

Keywords

References

  1. R. Sadeler, S. Atasoy, A. Arici, Y. Totik, The fretting fatigue of commercial hard anodized aluminum alloy, Journal of Materials Engineering and Performance, 18 (2009) 1280-1284. 
  2. T. Aerts, Th. Dimogerontakis, I. De Graeve, J. Fransaer, H. Terryn, Influence of the anodizing temperature on the porosity and the mechanical properties of the porous anodic oxide film, Surface and Coatings Technology, 201 (2007) 7310-7317. 
  3. V. Lopez, J.A. Gonzalez, E. Otero, E. Escudero, M. Morcillo, Atmospheric corrosion of bare and anodised aluminium in a wide range of environmental conditions. part II: electrochemical responses, Surface and Coatings Technology, 153 (2002) 235-244. 
  4. N. Jeong, J. Choi, Properties of double-layered anodizing films on Al alloys formed by two consecutive anodizings, Journal of the Korean Institute of Surface Engineering, 54 (2021) 30-36. 
  5. J. Zhang, Y. Yu, P. Fang, L. Liu, H. Yue, J. Ou, A. Han, Anodization of aluminum in a sealed container, Electrochemistry Communications, 129 (2021) 107086. 
  6. S.Y. Kang, D.W. Lee, Study on improvement of corrosion resistance and wear resistance by anodizing and sealing treatment with nano-diamond powder on aluminum, Journal of the Korean Institute of Surface Engineering, 47 (2014) 121-127. 
  7. M.Y. Lin, P.S. Hsiao, H.H. Sheu, C.C. Cang, M.S. Tsai, D.S. Wuu, H.B. Lee, Improving the corrosion resistance of 6061 aluminum alloy using anodization and nickel-cobalt based sealing treatment, International Journal of Electrochemical Science, 16 (2021) 211053. 
  8. M. Ardelean, S. Lascau, E. Ardelean, A. Josan, Surface treatments for aluminium alloys, IOP Conference Series: Materials Science and Engineering, 294 (2018) 012042. 
  9. N. Hu, X. Dong, X. He, J.F. Browning, D.W. Schaefer, Effect of sealing on the morphology of anodized aluminum oxide, Corrosion Science, 97 (2015) 17-24. 
  10. L. Hao, B.R. Cheng, Sealing processes of anodic coatings-past, present, and future, Metal Finishing, 98 (2000) 8-18. 
  11. H. Jo, S. Lee, D. Kim, J. Lee, Low temperature sealing of anodized aluminum alloy for enhancing corrosion resistance, Materials, 13 (2020) 4904. 
  12. S. Ono, H. Asoh, Mechanism of hot water sealing of anodic films formed on aluminum, Corrosion Science, 181 (2021) 109221. 
  13. Y. Wan, H. Wang, Y. Zhang, Y. Li, Study on anodic oxidation and sealing of aluminum alloy, International Journal of Electrochemical Science, 13 (2018) 2175-2185. 
  14. S.U. Ofoegbu, F.A.O. Fernandes, A.B. Pereira, The sealing step in aluminum anodizing: a focus on sustainable strategies for enhancing both energy efficiency and corrosion resistance, Coatings, 10 (2020) 226. 
  15. H. Zhao, X. Chem, X. Yuan, L. Zhou, X. Wang, Effect of different sealing treatments of oxide films on corrosion resistance
  16. E. Rocca, D. Vantelon, S. Reguer, F. Mirambet, Structural evolution in nanoporous anodic aluminium oxide, Materials Chemistry and Physics, 134 (2012) 905-911. 
  17. J. Lee, U. Jung, W. Kim, W. Chung, Effects of residual water in the pores of aluminum anodic oxide layers, Applied Surface Science, 283 (2013) 941-946. 
  18. Y. Suzuki, K. Kawahara, T. Kikuchi, R.O. Suzuki, S. Natsui, Corrosion-resistant porous alumina formed via anodizing aluminum in etidronic acid and its pore-sealing behavior in boiling water, Journal of The Electrochemical Society, 166 (2019) C261. 
  19. H. Zhao, X. Chem, X. Yuan, L. Zhou, X. Wang, Effect of different sealing treatments of oxide films on corrosion resistance of anodized ZL101A aluminum alloy in simulated marine atmospheric environment, International Journal of Electrochemical Science, 17 (2022) 220851. 
  20. A. Hakimizad, K. Raeissi, F. Ashrafizadeh, A comparative study of corrosion performance of sealed anodized layers of conventionally colored and interference-colored aluminium, Surface and Coatings Technology, 206 (2012) 4628-4633.