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Microstructural and corrosion behavior of D3 tools steel and 440C SS for blade application

  • Nur Maizatul Shima Adzali (Frontier Materials Research, Centre of Excellence (FrontMate), Universiti Malaysia Perlis (UniMAP)) ;
  • Nurul Abidah Mohamad Khapeli (Department of Materials, Faculty of Chemical Engineering & Technology, University Malaysia Perlis) ;
  • Alina Rahayu Mohamed (Department of Chemistry, Faculty of Chemical Engineering & Technology, University Malaysia Perlis)
  • Received : 2023.08.02
  • Accepted : 2024.01.05
  • Published : 2024.06.25

Abstract

D3 tools steel and 440C stainless steel (SS) are normally being employed for application such as knife blade and cutting tools. These steels are iron alloys which have high carbon and high chromium content. In this study, lab work focused on the microstructural and corrosion behavior of D3 tools steel and 440C SS after went through heat treatment processes. Heat treatments for both steels were started with normalizing at 1020 ℃, continue with hardening at 1000 ℃followed by oil quenching. Cryogenic treatment was carried out in liquid nitrogen for 24 hours. The addition of cryogenic heat treatment is believed to increase the hardness and corrosion resistance for steels. Both samples were then tempered at two different tempering temperatures, 160 ℃ and 426 ℃. For corrosion test, the samples were immersed in NaCl solution for 30 days to study the corrosion behavior of D3 tool steel and 440C SS after heat treatment. The mechanical properties of these steels have been investigated using Rockwell hardness machine before heat treatment, after heat treatment (before corrosion) and after corrosion test. Microstructure observation of samples was carried out by scanning electron microscopy. The corrosion rate of these steels was calculated after the corrosion test completed. From the results, the highest hardness is observed for D3 tool steel which tempered at 160 ℃(54.1 HRC). In terms of microstructural analysis, primary carbide and pearlite in the as-received samples transform to tempered martensite and cementite after heat treatment process. From this research, for corrosion test, heat treated 440C SS sample tempered with 426 ℃possessed the excellent corrosion resistance with corrosion rate 0.2808 mm/year.

Keywords

Acknowledgement

The authors acknowledge the Centre of Excellence Frontier Materials Research from University Malaysia Perlis (UniMAP) Malaysia, Steel Technica Sdn Bhd., and SIG (Special Interest Group) Metal Processing & Metallurgy Research Group (MetaPrime) research group for the generous collaboration in the acquisition of data and results. Author self-funding involved in this project.

References

  1. Ajay, A., Ramesh, A., Amal, V.H. and Menon, G.R. (2018), "Effect of quenching medium on hardness of D3 tool steel", J. Eng. Res. Appl., 8, 20-26. https://doi.org/10.9790/9622-0805052026.
  2. Alza, V.A. (2020), "Effect of multiple tempering on mechanical properties and microstructure of ledeburitic tool steel AISI D3", Int. J. Rec. Tech. Eng. 8(5), 2514-2521. https://doi.org/10.35940/ijrte.E6278.018520.
  3. Al-Qawabah, S., Mostafa, A., Al-Rawajfeh, A. and Al-Qawabeha, U. (2020), "Effect of heat treatment on the grain size, microhardness and corrosion behavior of the cold-working tool steels AISI D2 and AISI O1", Mater. Tehnol., 54(6), 785-790. https://doi.org.10.17222/mit.2020.035.
  4. Atapek, S.H., Polat, S. and Zor, S. (2013), "Effect of tempering temperature and microstructure on the corrosion behavior of a tempered steel", Prot. Met. Phys. Chem. Surf., 49(2), 240-246. https://doi.org.10.1134/S2070205113020111.
  5. Singh, R.B. and Kumar, D. (2019), "Heat treatment of tool steel D3 and effects on mechanical properties", Int. J. Rec. Sci. Res., 10(5), 32540-32545. http://doi.org/10.24327/ijrsr.2019.1005.3493.
  6. Barlow, L.D. and Du Toit, M. (2012), "Effect of austenitizing heat treatment on the microstructure and hardness of martensitic stainless steel AISI 420", J. Mater. Eng. Perform., 21(7), 1327-1336. https://doi.org/10.1007/s11665-011-0043-9.
  7. Bhateja, A., Varma, A., Kashyap, A. and Singh, B. (2012), "Study the effect on the hardness of three sample grades of tool steel i.e. EN-31, EN-8, and D3 after heat treatment processes such as annealing, normalizing, and hardening & tempering", Int. J. Eng. Sci., 1(2), 253-259.
  8. Chandra, K., Gupta, B., Kumar, D.K., Kumar Jaisal, A., Umar Ranjan, A., Rivastava, A. and Haudhary, P. (2021), "Effect of heat treatment on properties and microstructure of steels", Mater. Today: Proc., 44, 199-205. https://doi.org/10.1016/j.matpr.2020.08.556.
  9. Ghasemi, N.H. and Jahazi, M. (2014), "Simultaneous enhancement of strength and ductility in cryogenically treated AISI D2 tool steel", Mater. Sci. Eng. A, 598, 413-419. https://doi.org/10.1016/j.msea.2014.01.065.
  10. Ghazi, S.S. and Mashloosh, K.M. (2015), "Influence of heat treatment on resistance of wear and mechanical properties of die steel kind D3", Am. J. Sci. Indust. Res., 5(2), 33-40. https://doi.org/10.5251/ajsir.2015.6.2.33.40.
  11. Ibrahim, M.A.M., Abd El Rehim, S.S. and Hamza, M.M. (2009), "Corrosion behavior of some austenitic stainless steels in chloride environments", Mater. Chem. Phys., 115(1), 80-85. https://doi.org.10.1016/j.matchemphys.2008.11.016.
  12. Katiyar, P.K., Misra, S. and Mondal, K. (2018), "Effect of different cooling rates on the corrosion behavior of high-carbon pearlitic steel", J. Mater. Eng. Perform., 27(4), 1753-1762. https://doi.org.10.1007/s11665-018-3256-3.
  13. Kumar, S., Mohan, N.S.R. and Khedkar, N. (2017), "Effect of cryogenic treatment on tool steels", Int. J. Adv. Res., 5(3), 1035-1045. https://doi.org/10.21474/ijar01/3602.
  14. Kwok, C.T., Lo, K.H., Cheng, F.T. and Man, H.C. (2003), "Effect of processing conditions on the corrosion performance of laser surface-melted AISI 440C martensic stainless steel", Surf. Coat. Technol., 166(2-3), 221-230. https://doi.org/10.1016/S0257-8972(02)00782-X.
  15. Lajis, M.A., Nurul Amin, A.K.M., Mustafizul Karim, A.N. and Hafiz, A.M.K. (2010), "Preheating in end milling of AISI D2 hardened steel with coated carbide inserts", Adv. Mater. Res., 83, 56-66. https://doi.org/10.4028/www.scientific.net/AMR.83-86.56.
  16. Mahmoud, A.E., Ahmed, Y.S., Mohamed, K.E., Emad, E. and Hassan, M. (2023), "Effect of deep cryogenic treatment on wear behavior of cold work tool steel", Metals, 13(2), 382. https://doi.org/10.3390/met13020382.
  17. Nandakumar, P., Karthikeyan, R. and Paulo, J.D. (2017), "A review on effects of cryogenic treatment of AISI 'D' series cold working tool steels", Rev. Adv. Mater. Sci., 51, 149-159.
  18. Naravade, R.H., Belkar, S.B. and Kharde, R.R. (2013), "Effects of cryogenic treatment, hardening and multiple tempering on wear behaviour of D6 tool steel", Int. J. Eng. Sci., 2(5), 1-15.
  19. Nykiel, T. and Hryniewicz, T. (2014), "Transformations of carbides during tempering of D3 tool steel", J. Mater. Eng. Perform., 23(6), 2050-2054. https://doi.org/10.1007/s11665-014-0979-7.
  20. Okafor, U.C. (2012), "Mechanical Characterization of A2 and D2 Tool Steels by Nanoindentation", Doctoral Dissertation, University of North Texas, Denton, TX, USA.
  21. Peral, L.B., Ebrahimzadeh, P., Gutierrez, A. and Fernandez-Pariente, I. (2023), "Effect of tempering temperature and grain refinement induced by severe shot peening on the corrosion behavior of a low alloy steel", J. Electr. Chem., 932, 117207. https://doi.org.10.1016/j.jelechem.2023.117207.
  22. Saefuloh, I., Kanani, N. and Yazid, R. (2020), "The study of corrosion behaviour API 5l steel in sea water using immersion test method", IOP Conf. Ser. Mater. Sci. Eng., 909(1), 012030. https://doi.org.10.1088/1757-899X/909/1/012030.
  23. Saha, S.K., Prasad, L. and Kumar, V. (2012), "Experimental investigations on heat treatment of cold work tool steels: Part 1, air-hardening grade (D2)", Int. J. Eng. Res. Appl., 2(2), 510-519. https://doi.org/10.1016/S0257-8972(02)00782-X.
  24. Salih, A.A., Omar, M.Z., Junaidi, S. and Sajuri, Z. (2011), "Effect of different heat treatment on the SS440C martensitic stainless steel", Aus. J. Basic Appl. Sci., 5(12), 867-871.
  25. Salleh, S.H., Omar, M.Z., Syarif, J., Ghazali, M.J., Abdullah, S. and Sajuri, Z. (2009), "Investigation of microstructures and properties of 440C martensitic stainless steel", Int. J. Mech. Mater. Eng., 4(2), 123-126.
  26. Samuel, A. and Narayan Prabhu, K. (2022), "Residual stress and distortion during quench hardening of steels: A review", J. Mater. Eng. Perform., 31, 5161-5188. https://doi.org/10.1007/s11665-022-06667-x.
  27. Sundjono, S., Priyotomo, G., Nuraini, L. and Prifiharni, S. (2017), "Corrosion behavior of mild steel in seawater from northern coast of java and southern coast of Bali, Indonesia", J. Eng. Technol. Sci., 49(6), 770-784. https://doi.org.10.5614/j.eng.technol.sci.2017.49.6.5.
  28. Uygur, I., Gerengi, H., Arslan, Y. and Kurtay, M. (2015), "The effects of cryogenic treatment on the corrosion of AISI D3 steel", Mater. Res., 18(3), 569-574. http://doi.org/10.1590/1516-1439.349914.
  29. Xu, M.L. (2012), "Secondary carbide dissolution and coarsening in 13% Cr martensitic stainless steel during austenitizing", Doctoral Dissertation, Northeastern University Boston, Boston, MA, USA.
  30. Yuhua, L., Yongli, C. and Xuejiao, Z. (2020), "Effects of cryogenic treatment and tempering on mechanical properties and microstructure of 0.25C-0.80Si-1.6Mn steel", Adv. Mater. Sci. Eng., 2020, 1-8. https://doi.org/10.1155/2020/1501474.
  31. Zhang, H., Yan, X., Chen, Z., Zhao, M., Tang, L., Gao, Y., Li, F., Huang, Y. and Li, J. (2022), "Effect of cryogenic treatment on wear resistance and microstructure of 42CrMo steel", Arch. Metall. Mater., 67(1), 127-135. https://doi.org/10.24425/amm.2022.137481.