한국표면공학회지 (Journal of Surface Science and Engineering)

  • 제57권2호
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  • Pages.115-124
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  • 2024
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  • 1225-8024(pISSN)
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  • 2288-8403(eISSN)
한국표면공학회 (The Korean Institute of Surface Engineering)
권호 표지
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리튬 이온 배터리 음극에서 비닐렌 카보네이트가 매개하는 고체 전해질 계면 형성 메커니즘 연구

Understanding the Mechanism of Solid Electrolyte Interface Formation Mediated by Vinylene Carbonate on Lithium-Ion Battery Anodes

  • 이진희 (인하대학교 화학.화학공학융합학과) ;
  • 정지윤 (인하대학교 화학.화학공학융합학과) ;
  • 하재윤 (인하대학교 화학.화학공학융합학과) ;
  • 김용태 (전남대학교 화공생명공학과) ;
  • 최진섭 (인하대학교 화학.화학공학융합학과)
  • Jinhee Lee (Department of Chemistry and Chemical Engineering, Inha University) ;
  • Ji-Yoon Jeong (Department of Chemistry and Chemical Engineering, Inha University) ;
  • Jaeyun Ha (Department of Chemistry and Chemical Engineering, Inha University) ;
  • Yong-Tae Kim (Department of Chemical and Biomolecular Engineering, Chonnam National University) ;
  • Jinsub Choi (Department of Chemistry and Chemical Engineering, Inha University)
  • 투고 : 2024.04.20
  • 심사 : 2024.04.25
  • 발행 : 2024.04.30
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초록

In advancing Li-ion battery (LIB) technology, the solid electrolyte interface (SEI) layer is critical for enhancing battery longevity and performance. Formed during the charging process, the SEI layer is essential for controlling ion transport and maintaining electrode stability. This research provides a detailed analysis of how vinylene carbonate (VC) influences SEI layer formation. The integration of VC into the electrolyte markedly improved SEI properties. Moreover, correlation analysis revealed a connection between electrolyte decomposition and battery degradation, linked to the EMC esterification and dicarboxylate formation processes. VC facilitated the formation of a more uniform and chemically stable SEI layer enriched with poly(VC), thereby enhancing mechanical resilience and electrochemical stability. These findings deepen our understanding of the role of electrolyte additives in SEI formation, offering a promising strategy to improve the efficiency and lifespan of LIBs.

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