Advances in nano research

  • 제16권1호
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  • Pages.41-52
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  • 2024
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  • 2287-237X(pISSN)
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  • 2287-2388(eISSN)
테크노프레스 (Techno-Press)
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Rational design of rare-earth orthoferrite LnFeO3 via Ln variation towards high photo-Fenton degradation of organics

  • Thi T. N. Phan (College of Science, Technology, Engineering & Mathematics, Murdoch University) ;
  • Aleksandar N. Nikoloski (College of Science, Technology, Engineering & Mathematics, Murdoch University) ;
  • Parisa A. Bahri (College of Science, Technology, Engineering & Mathematics, Murdoch University) ;
  • Dan Li (College of Science, Technology, Engineering & Mathematics, Murdoch University)
  • 투고 : 2023.03.13
  • 심사 : 2024.01.04
  • 발행 : 2024.01.25
⟨ 이전 논문 다음 논문 ⟩

초록

In this study, rare-earth orthoferrites LnFeO3 were synthesized using a facile hydrothermal reaction and their visible-light-induced photo-Fenton degradation of organics was optimized through Ln variation (Ln = La, Pr, or Gd). The morphological, structural, and chemical characteristics of as-prepared samples were examined in detail by using different methods, including XRD, SEM, TEM, XPS, etc. On the other side, under visible light illumination, the photo-Fenton-like catalytic activities of LnFeO3 were assessed in terms of the removal of selected organic models, i.e., pharmaceuticals (ketoprofen and tetracycline) and dyes (rhodamine B and methyl orange). As compared with PrFeO3 or GdFeO3, the sample of LaFeO3 displayed more structural distortion, larger specific surface area, and narrower band gap, resulting in its higher photo-Fenton-like catalytic activity toward the degradation of organics. In organic-containing solution, in which the initial solution pH = 5, catalyst dosage = 1 g/L and H2O2 concentration = 10 mM, 98.2% of rhodamine B, 31.1% of methyl orange, 67.7% of ketoprofen, or 96.4% of tetracycline was removed after 90-min exposure to simulated visible light. Our findings revealed that variation of Ln site on rare-earth orthoferrites was an effective strategy for optimizing their organic removal via visible-light-induced photo-Fenton reaction.

키워드

과제정보

This research was funded by Vietnam National Foundation for Science and Technology Development (NAFOSTED) under grant number 104.05-2020.06. The authors acknowledge the support received from Murdoch SEIT Small Grant Scheme (2016). T. Phan's PhD study was supported by Australia Awards Scholarship. The authors acknowledge the facilities, and the scientific and technical assistance of the Australian Microscopy & Microanalysis Research Facility at the Centre for Microscopy, Characterisation & Analysis, The University of Western Australia, a facility funded by the University, State and Commonwealth Governments. The authors thank Ms Caitlin Sweeney for band gap measurement and analysis.

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