한국표면공학회지 (Journal of the Korean institute of surface engineering)

  • 제56권5호
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  • Pages.299-308
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  • 2023
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  • 1225-8024(pISSN)
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  • 2288-8403(eISSN)
한국표면공학회 (The Korean Institute of Surface Engineering)
권호 표지
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인이 도핑된 NiCo2O4 전극 제조 공정의 간소화를 통한 전극 특성의 변화

Variations in electrode characteristics through simplification of phosphorus-doped NiCo2O4 electrode manufacturing process

  • 이석희 (부산대학교 재료공학과) ;
  • 차현진 (부산대학교 재료공학과) ;
  • 박정환 (부산대학교 재료공학과) ;
  • 손영국 (부산대학교 재료공학과) ;
  • 황동현 (신라대학교 배터리학과)
  • Seokhee-Lee (School of Materials Science and Engineering, Pusan National University) ;
  • Hyunjin Cha (School of Materials Science and Engineering, Pusan National University) ;
  • Jeonghwan Park (School of Materials Science and Engineering, Pusan National University) ;
  • Young Guk Son (School of Materials Science and Engineering, Pusan National University) ;
  • Donghyun Hwang (Department of Batteries Science and Engineering, Silla University)
  • 투고 : 2023.08.17
  • 심사 : 2023.08.30
  • 발행 : 2023.10.31
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초록

In this study, phosphorus (P)-doped nickel cobaltite (P-NiCo2O4) and nickel-cobalt layered double hydroxide (P-NiCo-LDH) were synthesized on nickel (Ni) foam as a conductive support using hydrothermal synthesis. The thermal properties, crystal structure, microscopic surface morphology, chemical distribution, electronic state of the constituent elements on the sample surface, and electrical properties of the synthesized P-NiCo2O4 and P-NiCo-LDH samples were analyzed using thermogravimetric analysis-differential scanning calorimetry (TGA-DSC), X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy (EIS). The P-NiCo2O4 electrode exhibited a specific capacitance of 1,129 Fg-1 at a current density of 1 Ag-1, while the P-NiCo-LDH electrode displayed a specific capacitance of 1,012 Fg-1 at a current density of 1 Ag-1. When assessing capacity changes for 3,000 cycles, the P-NiCo2O4 electrode exhibited a capacity retention rate of 54%, whereas the P-NiCo-LDH electrode showed a capacity retention rate of 57%.

키워드

과제정보

이 과제는 부산대학교 기본연구지원사업(2년)에 의하여 연구되었음.

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