DOI QR코드

DOI QR Code

Preparation and Tactile Performance of Soluble Eggshell Membrane (S-ESM) Embedded Waterborne Polyurethane (WPU) Composite

  • Soohyun Joo (Department of Materials Engineering and Convergence Technology, RIGET, Gyeongsang National University) ;
  • Tridib Kumar Sinha (Department of Chemistry, Applied Science Cluster, School of Engineering, University of Petroleum and Energy Studies) ;
  • Junho Moon (Department of Materials Engineering and Convergence Technology, RIGET, Gyeongsang National University) ;
  • Jeong Seok Oh (Department of Materials Engineering and Convergence Technology, RIGET, Gyeongsang National University)
  • Received : 2023.09.04
  • Accepted : 2023.09.20
  • Published : 2023.09.30

Abstract

Herein, we propose a facile water-processible method to develop an eggshell membrane (ESM)-embedded waterborne polyurethane (WPU)-based bio-degradable and bio-compatible coating material that exhibits attractive tactile properties. Virgin ESM is not dispersible in water. Hence, to develop the ESM-based WPU composite, soluble ESM (S-ESM) was first extracted by de-crosslinking the ESM. The extracted S-ESM at different concentrations (0, 0.5, 1.0, 1.5 wt %) was mixed with WPU. Compared to virgin WPU, the viscosity of S-ESM/WPU dispersion and the in-plane coefficient of friction (COF) of the composite film surfaces decreased with an increase in the S-ESM content. In addition, an increase in the S-ESM content improved the tribo-positive characteristics of the film. Different good touch-feeling biomaterials, such as fur, feather, and human skin exhibit tribo-positivity. Thus, the enhanced tribo-positive characteristics of the S-ESM/WPU and the decrease in their COF owing to an increase in the S-ESM content imply the enhancement of its touch-feeling performance. The S-ESM embedded WPU composites have potential applications as coating materials in various fields, including automobile interiors and artificial leather.

Keywords

Acknowledgement

This work was supported by the Development Fund Foundation of Gyeongsang National University, 2021.

References

  1. R. Mulhaupt, "Green polymer chemistry and bio-based plastics: Dreams and reality", Macromol. Chem. Phys., 214, 159 (2013). 
  2. S. Singh, S. Ramakrishna, and M. K. Gupta, "Towards zero waste manufacturing: A multidisciplinary review", J. Clean. Prod., 168, 1230 (2017). 
  3. G. Kaur, K. Uisan, K. L. Ong, and C. S. Ki Lin, "Recent Trends in Green and Sustainable Chemistry & Waste Valorisation: Rethinking Plastics in a circular economy", Curr. Opin. Green Sustain. Chem., 9, 30 (2018). 
  4. H. S. Katz and J. V. Mileski, "Handbook of fillers for plastics", p. 3, Springer, New York, 1988. 
  5. J.-B. Donnet, "Carbon black: science and technology", p. 2, Marcel Dekker, Inc., New York Basel, 1993. 
  6. I. T. Kim, T. K. Sinha, J. Lee, Y. Lee, and J. S. Oh, "Ultrasonic treatment: An acid-free green approach toward preparing high-performance activated carbon from lignin", Ind. Eng. Chem. Res., 60, 2439 (2021). 
  7. I. T. Kim, K. H. Lee, T. K. Sinha, and J. S. Oh, "Comparison of ultrasonic-treated rice husk carbon with the conventional carbon black towards improved mechanical properties of their EPDM composites", Carbon Lett., 31, 1071 (2021). 
  8. A. Mittal, M. Teotia, R. K. Soni, and J. Mittal, "Applications of egg shell and eggshell membrane as adsorbents: a review", J. Mol. Liq., 223, 376 (2016). 
  9. M. Waheed, M. Yousaf, A. Shehzad, M. Inam-Ur-Raheem, M. K. I. Khan, M. R. Khan, N. Ahmad, and R. M. Aadil, "Channelling eggshell waste to valuable and utilizable products: a comprehensive review", Trends Food Sci. Technol,. 106, 78 (2020). 
  10. X. Meng amd D. Deng, "Trash to treasure: waste eggshells used as reactor and template for synthesis of Co9S8 nanorod arrays on carbon fibers for energy storage", Chem. Mater., 28, 3897 (2016). 
  11. X. Liu, Z. Yue, Z. Cai, D. G. Chetwynd, and S. T. Smith, "Quantifying touch-feel perception: tribological aspects", Meas. Sci. Technol., 19, 84007 (2008). 
  12. L. Tangeland, K. O. Schulte, and C. Boks, "Tactile Qualities of Materials in Consumer Product Packaging", Nord Design Conference. Tallinn, Estonia, 89 (2008). 
  13. M. S. Balaji, S. Raghavan, and S. Jha, "Role of tactile and visual inputs in product evaluation: a multisensory perspective", Asia Pacific J. Mark. Logist., 23, 513 (2011). 
  14. W. S. Na, T. K. Sinha, J. Lee, and J. S. Oh, "Eggshell membrane reinforced polypropylene biocomposite and its tactile assessment", J. Appl. Polym. Sci., 137, 49508 (2020). 
  15. T. J. Mahara, H. Wanga, and R. Postle, "A review of fabric tactile properties and their subjective assessment for next-to-skin knitted fabrics", J. Text. Inst., 104, 572 (2013). 
  16. J. Dargahi and S. Najarian, "Human tactile perception as a standard for artificial tactile sensing-a review", Int. J. Med. Robot. Comput. Assist. Surg., 1, 23 (2004). 
  17. R. Ackerley, I. Carlsson, H. Wester, H. Olausson, and H. B. Wasling, "Touch perceptions across skin sites: differences between sensitivity, direction discrimination and pleasantness", Front. Behav. Neurosci., 8, 54 (2014). 
  18. P. Dario, "Tactile sensing: Technology and applications", Sensors Actuators A Phys., 26, 251 (1991). 
  19. H. Li, T. K. Sinha, J. Lee, J. S. Oh, Y. Ahn, and J. K. Kim, "Melt-Compounded Keratin-TPU Self-Assembled Composite Film as Bioinspired e-Skin", Adv. Mater. Interfaces, 5, 1800635 (2018). 
  20. P. E. Shaw, "Experiments on tribo-electricity. I.-The tribo-electric series", Proc. R. Soc. London. Ser. A, Contain. Pap. a Math. Phys. Character, 94, 16 (1917). 
  21. H. Zou, Y. Zhang, L. Guo, P. Wang, X. He, G. Dai, H. Zheng, C. Chen, A. C. Wang, and C. Xu, "Quantifying the triboelectric series", Nat. Commun., 10, 1 (2019). 
  22. A. F. Diaz and R. M. Felix-Navarro, "A semi-quantitative tribo-electric series for polymeric materials: the influence of chemical structure and properties", J. Electrostat., 62, 277 (2004). 
  23. P. Pakdeechote, "Preparation of high density polyethylene composites from eggshell powder and heat-treated eggshell powder", PhD diss., School of Polymer Engineering Institute of Engineering, Suranaree University of Technology, 2010. 
  24. C. M. M. Cordeiro and M. T. Hincke, "Recent patents on eggshell: shell and membrane applications", Recent Pat. Food. Nutr. Agric., 3, 1 (2011). 
  25. D. Cree and A. Rutter, "Sustainable bio-inspired limestone eggshell powder for potential industrialized applications", ACS Sustain. Chem. Eng., 3, 941 (2015). 
  26. M. Balaz, "Eggshell membrane biomaterial as a platform for applications in materials science", Acta Biomater., 10, 3827 (2014). 
  27. A. Tsopmo, F. Tsige, and C. C. Udenigwe, "Byproducts from Agriculture and Fisheries on Animal Byproducts", Utilization of egg byproducts for food and biomaterial applications", p. 147, John Wiley & Sons, Ltd. (2019). 
  28. M. K. Sah and S. N. Rath, "Soluble eggshell membrane: a natural protein to improve the properties of biomaterials used for tissue engineering applications", Mater. Sci. Eng. C., 67, 807 (2016). 
  29. F. Yi, Z.-X. Guo, L.-X. Zhang, J. Yu, and Q. Li, "Soluble eggshell membrane protein: preparation, characterization and biocompatibility", Biomaterials, 25, 4591 (2004). 
  30. S. Park, K. S. Choi, D. Lee, D. Kim, K. T. Lim, K.-H. Lee, H. Seonwoo, and J. Kim, "Eggshell membrane: Review and impact on engineering", Biosyst. Eng., 151, 446 (2016). 
  31. D.-H. Lee, S.-Y. Baek, and Y. H. Kim, "Recycling different eggshell membranes for lithium-ion battery", Mater. Lett., 228, 504 (2018). 
  32. L. Ma, R. Chen, Y. Hu, W. Zhang, G. Zhu, P. Zhao, T. Chen, C. Wang, W. Yan, and Y. Wang, "Nanoporous and lyophilic battery separator from regenerated eggshell membrane with effective suppression of dendritic lithium growth", Energy Storage Mater., 14, 258 (2018). 
  33. F. Yi, J. Yu, Z. Guo, L. Zhang, and Q. Li, "Natural bioactive material: a preparation of soluble eggshell membrane protein", Macromol. Biosci., 3, 234 (2003). 
  34. M.-C. Lee and Y.-C. Huang, "Soluble eggshell membrane protein-loaded chitosan/fucoidan nanoparticles for treatment of defective intestinal epithelial cells", Int. J. Biol. Macromol., 131, 949 (2019). 
  35. K. Takahashi, K. Shirai, M. Kitamura, and M. Hattori, "Soluble egg shell membrane protein as a regulating material for collagen matrix reconstruction", Biosci. Biotechnol. Biochem., 60, 1299 (1996). 
  36. L. Mohammadzadeh, R. Rahbarghazi, R. Salehi, and M. Mahkam, "A novel eggshell membrane based hybrid nanofibrous scaffold for cutaneous tissue engineering", J. Biol. Eng., 13, 1 (2019).