DOI QR코드

DOI QR Code

양식업 종사자 포르말린 살포 작업에 대한 포름알데히드 노출평가

Evaluation of Formaldehyde Exposure for Formalin Spraying Work of Fish Farm Workers

  • 김은영 (근로복지공단 직업환경연구원) ;
  • 최성원 (근로복지공단 직업환경연구원) ;
  • 이성숙 (근로복지공단 직업환경연구원) ;
  • 손혜림 (근로복지공단 직업환경연구원) ;
  • 백진이 (근로복지공단 직업환경연구원) ;
  • 신재훈 (근로복지공단 직업환경연구원) ;
  • 김대호 (근로복지공단 직업환경연구원)
  • Eun Young Kim (Institute of Occupation and Environment, COMWEL) ;
  • Sungwon Choi (Institute of Occupation and Environment, COMWEL) ;
  • Sungsook Lee (Institute of Occupation and Environment, COMWEL) ;
  • Hyerim Son (Institute of Occupation and Environment, COMWEL) ;
  • Jin Ee Baek (Institute of Occupation and Environment, COMWEL) ;
  • Jae Hoon Shin (Institute of Occupation and Environment, COMWEL) ;
  • Deaho Kim (Institute of Occupation and Environment, COMWEL)
  • 투고 : 2023.11.01
  • 심사 : 2023.12.12
  • 발행 : 2023.12.31

초록

Objectives: Formalin is used as an anthelmintic in farms where flounder are raised. In this study, we aim to identify formaldehyde exposure levels for aquaculture industry workers and provide basic data for managing formaldehyde exposure. Methods: Exposure levels of formaldehyde in the air, including formalin spraying operations, were assessed separately for personal and area samples. In addition, considering the formalin administration method, dermal exposure to the hands was estimated when administering the chemical, and dermal exposure to the legs during water tank work was estimated by collecting water in the water tank and evaluating the amount of formaldehyde remaining. Finally, the respiratory exposure level and the estimated dermal exposure level were added to derive the total exposure level and compared with the maximum allowable human dose. Results: As a result of the airborne evaluation, the formaldehyde concentration of the worker (1 person) who performed the formalin spraying and flounder sorting was 33.61 ppb, and the arithmetic mean of formaldehyde concentrations of the workers (3 people) who only performed the flounder sorting was 3.28 ppb (range: 2.25-4.89 ppb). In the case of dermal exposure, when spraying formalin once, the amount was estimated to be 0.33-2.62 mg when wearing protective gear and 3.27-26.12 mg when not wearing it. Conclusions: There was a difference in the formaldehyde exposure level of workers depending on their operation of handling formalin and whether or not protective gear was worn. In particular, because the level of formaldehyde exposure due to dermal exposure can be significant, there is a need to improve formalin administration methods in a way that avoids skin contact as much as possible.

키워드

참고문헌

  1. Andreoli R, Manini P, Corradi M, Mutti A, Niessen WM. Determination of patterns of biologically relevant aldehydes in exhaled breath condensate of healthy subjects by liquid chromatography/ atmospheric chemical ionization tandem mass spectrometry. Rapid Commun Mass Spectrom 2003;17(7):637-645. https://doi.org/10.1002/rcm.960 
  2. Kim HA, Jang JW, Kim DH, Lee HJ, Lee SM et al. Analysis of formaldehyde in fisheries products. Korean Journal of Food Science and Technology 2010;43(1):17-22  https://doi.org/10.9721/KJFST.2011.43.1.017
  3. Kim KY, Lee KS, Kim MS. Work improvement of aquaculture workers by investigation to exposure level of harmful factors. Korea Occupational Safety and Health Agency(KOSHA). 2022. p. 27-59 
  4. Ministry of Food and Drug Safety(MFDS). Skin body surface area survey of risk assessment. 2010. p. 13-14
  5. Ministry of Oceans and Fisheries(MoF). Aquaculture Industry Development Act. 2021 
  6. National Fishery Products Quality Management Service (NFPQMS). 2022 Aquatic medicine catalog. 2022. p. 128-141 
  7. Occupational Safety and Health Administration(OSHA). OHSA techical manual(OTM): surface contaminats, skin exposure, biological monitoring and other analyses [Accessed 2023 Oct 31]. Available from: URL https://www.osha.gov/otm/section-2-healthhazards/chapter-2 
  8. Statistics Korea. 2022 Survey on the status of fish culture. 2023. p. 11-15 
  9. Wahed P, Razzaq MA, Dharmapuri S, Corrales M. Determination of formaldehyde in food and feed by an in-house validated HPLC method. Food Chem 2016;202:476-483. https://doi.org/ 10.1016/j.foodchem.2016.01.136