DOI QR코드

DOI QR Code

Wear Behavior of Silica filled Styrene-Butadiene Rubber: A Comparative Study Between the Blade-Type and Akron-Type Abrader

  • Gi-Bbeum Lee (Department of Polymer-Nano Science and Technology, Jeonbuk National University ) ;
  • Dongwon Kim (Department of Bionanotechnology and Bioconversence Engineering, Jeonbuk National University) ;
  • Seowon Lee (Department of Bionanotechnology and Bioconversence Engineering, Jeonbuk National University) ;
  • Seonhong Kim (Department of Bionanotechnology and Bioconversence Engineering, Jeonbuk National University) ;
  • Myung-Su Ahn (Department of Bionanotechnology and Bioconversence Engineering, Jeonbuk National University) ;
  • Bismark Mensah (Department of Materials Science and Engineering, University of Ghana) ;
  • Changwoon Nah (Department of Polymer-Nano Science and Technology, Jeonbuk National University )
  • Received : 2023.11.15
  • Accepted : 2023.11.20
  • Published : 2023.12.31

Abstract

The effect of the particle size and silica structure on the wear behavior of Silica/Styrene-Butadiene Rubber (SBR) compounds was investigated using a blade-type abrader and the findings were compared with those obtained with an Akron abrader. The compensated characteristic parameter (Ψc), which was the contributory factor of the combined effect of the particle size and filler structure, was introduced. This parameter was found to exhibit a linear relationship with the Young's modulus. The Young's modulus correlated more with Ψc than the uncompensated characteristic parameter (Ψ) modeled for carbon black. The wear rate and volume loss measured using a blade-type abrader and Akron abrader were respectively observed to be inversely proportional to Ψc, that is, the wear resistance of Silica/SBR compound improved as the particle size became smaller and the silica structure became intricate. The coefficient of determination (R2) obtained from the linear relationship between Ψc and wear rate was higher than those between Ψc and volume loss for the Silica/SBR compound. Thus, the blade-type abrader exhibited high potential to be used for accurately evaluating the effect of particle size and structural properties of silica on the wear behavior of SBR compounds.

Keywords

Acknowledgement

This work was supported by the Technology Innovation Program (20010851, An advanced butadiene rubber and a functional complex development for super abrasion tire) funded By the Ministry of Trade, Industry & Energy (MOTIE, Korea).

References

  1. T. Kurian and N. M. Mathew, "Natural Rubber: Production, Properties and Applications", In S. Kalia and L. Averous (Eds.), Biopolymers: Biomedical and Environmental Applications, Beverly, Scrivener Publishing LLC, 2011; pp. 403-436. 
  2. C. M. Bhuvaneswari, S. S. Kale, G. Gouda, P. Jayapal, and K. Tamilmani, "Elastomers and Adhesives for Aerospace Applications", In N. Prasad and R. Wanhill (Eds.), Aerospace Materials and Material Technologies, Indian Institute of Metals Series, Singapore, Springer, 2017; pp. 563-586. 
  3. E. M. Dannenberg, "The Effects of Surface Chemical Interactions on The Properties of Filler-Reinforced Rubbers", Rubber Chemistry and Technology, 48, 410 (1975). 
  4. A. Voet, J. C. Morawski, and J. B. Donnet, "Reinforcement of Elastomers by Silica", Rubber Chemistry and Technology, 50, 342 (1977). 
  5. Y. Li, M. J. Wang, T. Zhang, F. Zhang, and X. Fu, "Study on Dispersion Morphology of Silica in Rubber", Rubber Chemistry and Technology, 67, 693 (1994). 
  6. H. H. Hassan, E. Ateia, N. A. Darwish, S. F. Halim, and A. K. Abd El-Aziz, "Effect of Filler Concentration on The PhysicoMechanical Properties of Super Abrasion Furnace Black and Silica Loaded Styrene Butadiene Rubber", Materials and Design, 34, 533 (2012). 
  7. P. Sae-oui, C. Sirisinha, U. Thepsuwan, and K. Hatthapanit, "Dependence of Mechanical and Aging Properties of Chloroprene Rubber on Silica and Ethylene Thiourea Loadings", European Polymer Journal, 43, 185 (2007). 
  8. S. Chuayjuljit, S. Eiumnoh, and P. Potiyaraj, "Using Silica from Rice Husk as a Reinforcing Filler in Natural Rubber", Journal of Scientific Research, Chulalongkorn University, 26, 127 (2001). 
  9. R. Rauline, U.S. Patent No. 5,227,425. Washington DC: U.S. Patent and Trademark Office, (1993). 
  10. S. S. Sarkawi, "Silica-Reinforced Deproteinized Natural Rubber, In B. Zaidi and S. Belghit (Eds.), Silicon Materials, London, IntechOpen, 2017; pp. 1-24. 
  11. X. Zhai, Y. Chen, D. Han, J. Zheng, X. Wu, Z. Wang, X. Li, X. Ye, and L. Zhang, "New Designed Coupling Agents for Silica used in Green Tires with Low VOCs and Low Rolling Resistance", Applied Surface Science, 558, 149819 (2021). 
  12. D. Lee and S. H. Song, "A Study of Silica Reinforced Rubber Composites with Eco-Friendly Processing Aids for Pneumatic Tires", Macromolecular Research, 27, 850 (2019). 
  13. M. J. Wang, P. Zhang, and K. Mahmud, "Carbon-Silica Dual Phase Filler, A New Generation Reinforcing Agent for Rubber: Part IX. Application to Truck Tire Tread Compound", Rubber Chemistry and Technology, 74, 124 (2001). 
  14. K. Cho and D. H. Lee, "Wear of Rubber", Elast. and Compos., 30, 247 (1995). 
  15. B. Briscoe, "Wear of Polymers: An Essay on Fundamental Aspects", Tribology International, 14, 231 (1981). 
  16. W. Arayapranee, "Rubber Abrasion Resistance", In M. Adamiak (Ed.), Abrasion Resistance of Materials, London, IntechOpen, 2012; pp. 147-166. 
  17. C. K. Hong, H. Kim, C. Ryu, C. Nah, Y. Huh, and S. Kaang, "Effects of Particle Size and Structure of Carbon Blacks on The Abrasion of Filled Elastomer Compounds", Journal of Materials Science, 42, 8391 (2007). 
  18. A. Schallamach, "Abrasion Pattern on Rubber", Rubber Chemistry and Technology, 26, 230 (1953). 
  19. K. A. Grosch and A. Schallamach, "Relation between Abrasion and Strength of Rubber", Rubber Chemistry and Technology, 39, 287 (1966). 
  20. A. N. Gent and C. T. R. Pulford, "Mechanisms of Rubber Abrasion", Journal of Applied Polymer Science, 28, 943 (1983). 
  21. A. G. Thomas and E. Southern, "Studies of Rubber Abrasion", Rubber Chemistry and Technology, 52, 1008 (1979). 
  22. D. H. Champ, E. Southern, and A. G. Thomas, "Fracture Mechanics Applied to Rubber Abrasion", In L.-H. Lee (Ed.), Advances in Polymer Friction and Wear, New York, Plenum Press, 1974; pp. 133-144. 
  23. H. Lee, W. Wang, B. Shin, S. L. Kang, K. C. Gupta, and C. Nah, "A Correlation between Crack Growth and Abrasion for Selected Rubber Compounds", Elastomers and Composites, 54, 313 (2019). 
  24. Y. S. Kim, S. D. Yoon, and J. S. Kim, "Abrasion by A Blade Scraper Compared with Abrasion by A Rough Surface", Polymer Testing, 37, 123 (2014). 
  25. H. Kim and I. Jeon, "Wear and Frictional Behavior of Tire Rubber", Polymer Science and Technology, 11, 592 (2000). 
  26. A. N. Gent and C. Nah, "Abrasion of Rubber by A Blade Abrader: Effect of Blade Sharpness and Test Temperature for Selected Compounds", Rubber Chemistry and Technology, 69, 819 (1996). 
  27. S.-S. Hwang and P. P. Hsu, "Effects of Silica Particle Size on the Structure and Properties of Polypropylene/Silica Composites Foams", Journal of Industrial and Engineering Chemistry, 19, 1377 (2013). 
  28. W. A. Kyei-Manu, L. B. Tunnicliffe, J. Plagge, C. R. Herd, K. Akutagawa, N. M. Pugno, and J. J. C. Busfield, "Thermomechanical Characterization of Carbon Black Reinforced Rubbers During Rapid Adiabatic Straining", Frontiers in Materials, 8, 743146 (2021).