The Growth of Extended Melem Units on g-C₃N₄ by Hydrothermal Treatment and Its Effect on Photocatalytic Activity of g-C₃N₄ for Photodegradation of Tetracycline Hydrochloride under Visible Light Irradiation

In this work, the growth of extended tri-s-triazine units (melem units) on g-C₃N₄ (CN) by hydrothermal treatment and its effect on the photodegradation efficiency of tetracycline hydrochloride (TC) is investigated. The CN-180-x and CN-200-6 samples were prepared using different hydrolysis times and temperatures, and they were characterized by multiple physicochemical techniques. In addition, their photodegradation performance was evaluated under visible light irradiation. Compared to the CN, CN-180-6 possesses remarkable photocatalytic degradation efficiency at 97.17% towards TC removal in an aqueous solution. The high visible-light-induced photo-reactivity of CN-180-6 directly correlates to charge transfer efficiency, numerous structural defects with a high specific surface area (75.0 m² g^-1), and sufficient O-functional groups over g-C₃N₄. However, hydrothermal treatment at a higher temperature or during a longer time additionally induces the growth of extended melem units on the surface of g-C₃N₄, resulting in the inhibition of the charge transfer. In addition, the superoxide radical is proven to be generated from photoexcited reaction and plays a key role in the TC degradation.