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Synthesis and Electrochemical Performance of Microporous Hollow Carbon from Milkweed Pappus as Cathode Material of Lithium-Sulfur Batteries

  • Jun-Ki Kim (Busan Center, Korea Basic Science Institute (KBSI)) ;
  • Yunju Choi (Busan Center, Korea Basic Science Institute (KBSI)) ;
  • Euh Duck Jeong (Busan Center, Korea Basic Science Institute (KBSI)) ;
  • Sei-Jin Lee (Jeonju Center, Korea Basic Science Institute (KBSI)) ;
  • Hyun Gyu Kim (Busan Center, Korea Basic Science Institute (KBSI)) ;
  • Jae Min Chung (Division of Plant Resources, Korea National Arboretum) ;
  • Jeom-Soo Kim (Department of Chemical Engineering, Dong-A University) ;
  • Sun-Young Lee (Secondary Batteries Technology Center, Chungnam Techno Park) ;
  • Jong-Seong Bae (Busan Center, Korea Basic Science Institute (KBSI))
  • Received : 2022.09.20
  • Accepted : 2022.10.12
  • Published : 20220000

Abstract

Microtube-like porous carbon (MPC) and tube-like porous carbon-sulfur (MPC-S) composites were synthesized by carbonizing milkweed pappus with sulfur, and they were used as cathodes for lithium-sulfur batteries. The morphology and uniformity of these materials were characterized using X-ray powder diffraction, Raman spectroscopy, scanning electron microscopy, transmission electron microscopy with an energy-dispersive X-ray analyzer, thermogravimetric analysis, and X-ray photoelectron spectrometry. The electrochemical performance of the MPC-S cathodes was measured using the charge/discharge cycling performance, C rate, and AC impedance. The composite cathodes with 93.8 wt.% sulfur exhibited a stable specific capacity of 743 mAh g-1 after 200 cycles at a 0.5 C.

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Acknowledgement

This work was funded by the Ministry of Education, Korea (PGE093), and the Ministry of Science and ICT of Korea via the KBSI (Grant No. C123000).