Membrane and Water Treatment

  • 제13권5호
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  • Pages.227-233
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  • 2022
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Adsorptive and kinetic studies of toxic metal ions from contaminated water by functionalized silica

  • Kumar, Rajesh (Water Quality Management Group, Desert Environmental Science and Technology Division) ;
  • Verma, Sunita (Water Quality Management Group, Desert Environmental Science and Technology Division) ;
  • Harwani, Geeta (Water Quality Management Group, Desert Environmental Science and Technology Division) ;
  • Patidar, Deepesh (Water Quality Management Group, Desert Environmental Science and Technology Division) ;
  • Mishra, Sanjit (Water Quality Management Group, Desert Environmental Science and Technology Division)
  • 투고 : 2020.04.04
  • 심사 : 2022.09.07
  • 발행 : 2022.09.25
⟨ 이전 논문 다음 논문 ⟩

초록

The objective of the study, to develop adsorbent based purifier for removal of radiological and nuclear contaminants from contaminated water. In this regard, 3-aminopropyl silica functionalized with ethylenediamine tetraacetic acid (APS-EDTA) adsorbent prepared and characterized by Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM) and X-ray Diffraction (XRD). Prepared APS-EDTA used for adsorptive studies of Cs(I), Co(II), Sr(II), Ni(II) and Cd(II) from contaminated water. The effect on adsorption of various parameters viz. contact time, initial concentration of metal ions and pH were also analyzed. The batch method has been employed using metal ions in solution from 1000-10000 ㎍/L, contact time 5-60 min., pH 4-10 and material quantities 50-200 mg at room temperature. The obtained adsorption data were used for drawing Freundlich and Langmuir isotherms model and both models were found suitable for explaining the metal ions adsorption on APS-EDTA. The adsorption data were followed pseudo second order reaction kinetics. The maximum adsorption capacity obtained 1.3037-1.4974 mg/g for above said metal ions. The results show that APS-EDTA have great potential to remove Cd(II), Co(II), Cs(I), Ni(II) and Sr(II) from aqueous solutions through chemisorption and physio-sorption.

키워드

과제정보

We gratefully acknowledge the support, encouragement and valuable suggestion which we received from Sh. Ravindra Kumar, Director, Defence laboratory. Authors would like to thank Dr. Yojana Janu for XRD characterization of material. The authors thank to all members of Water Quality Management Group for direct and indirect support and help during this study.

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