DOI QR코드

DOI QR Code

Morphological study of synthesized PVDF membrane using different non-solvents for coagulation

  • Yadav, Meenakshi (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Upadhyay, Sushant (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Singh, Kailash (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Chaturvedi, Tarun Kumar (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Vashishtha, Manish (Department of Chemical Engineering, Malaviya National Institute of Technology)
  • 투고 : 2022.02.04
  • 심사 : 2022.05.31
  • 발행 : 2022.07.25

초록

Polyvinylidene fluoride (PVDF) flat sheet hydrophobic membranes were prepared using 16 wt% PVDF in Dimethyl acetamide (DMAc) by phase inversion technique for desalination application using Membrane Distillation (MD). In this work, the effect of coagulation mediums such as ethanol and water as well their synergistic behavior on the fabricated PVDF membrane morphology was studied using SEM. Moreover, other characteristics required for the membrane distillation applications namely porosity, hydrophobicity and tensile strength were measured using the gravimetric method, sessile drop method and universal testing machine respectively. It was observed that the membrane morphology paradigm shifted from the finger-like structure to the sponge-like structure on increasing the ethanol concentration in coagulant. The porosity of the fabricated membrane was under the required MD range and found to be 57.3% at 16 weight % of PVDF in DMAc solvent under a pure ethanol coagulant bath. Moreover, the top surface contact angle ranges from 85° to 115° on increasing the bath concentration from CBC 0 to CBC 100 at 16 weight % of PVDF in DMAc solvent.

키워드

참고문헌

  1. Abdel-karim, A., Leaper, S., Alberto, M., Vijayaraghavan, A., Fan, X., Holmes, S.M., Souaya, E.R., Badawy, M.I. and Gorgojo, P. (2018), "High flux and fouling resistant flat sheet polyethersulfone membranes incorporated with graphene oxide for ultra filtration applications", Chem. Eng. J., 334, 789-799. https://doi.org/10.1016/j.cej.2017.10.069.
  2. Baghel, R., Upadhyaya, S., Singh, K. and Chaurasia, S.P. (2017), "A review on membrane applications and transport mechanisms in vacuum membrane distillation", Rev. Chem. Eng., 34(1), 73-106. https://doi.org/10.1515/revce-2016-0050.
  3. Baghel, R., Kalla, S., Upadhyaya, S., Chaurasia, S.P. and Singh, K. (2020), "Chemical Engineering Research and Design CFD modeling of vacuum membrane distillation for removal of Naphthol blue black dye from aqueous solution using COMSOL multiphysics", Chem. Eng. Res. Des., 158, 77-88. https://doi.org/10.1016/j.cherd.2020.03.016.
  4. Chang, H.H., Tsai, C.H., Wei, H.C. and Cheng, L.P. (2014), "Effect of structure of PVDF membranes on the performance of membrane distillation", Membr. Water Treat., 5(1), 41-56. https://doi.org/10.12989/MWT.2014.5.1.041
  5. Deshmukh, S.P. and Li, K. (1998), "Effect of ethanol composition in water coagulation bath on morphology of PVDF hollow fibre membranes", J. Membr. Sci., 150(1), 75-85. https://doi.org/10.1016/S0376-7388(98)00196-3.
  6. Essalhi, M. and Khayet, M. (2012), "Surface segregation of fluorinated modifying macromolecule for hydrophobic/ hydrophilic membrane preparation and application in air gap and direct contact membrane distillation", J. Membr. Sci., 417-418, 163-173, https://doi.org/10.1016/j.memsci.2012.06.028.
  7. Garcia-Payo, M.C., Essalhi, M., Khayet, M., Garcia-Fernandez, L., Charfi, K. and Arafat, H. (2010), "Water desalination by membrane distillation using PVDF-HFP hollow fiber membranes", Membr. Water Treat., 1(3), 215-230. https://doi.org/10.12989/MWT.2010.1.3.215
  8. Gholami, A., Moghadassi, A. R., Hosseini, S. M., Shabani, S. and Gholami, F. (2013), "Preparation and characterization of polyvinyl chloride based nanocomposite nanofiltration- membrane modified by iron oxide nanoparticles for lead removal from water", J. Ind. Eng. Chem., 6-11, https://doi.org/10.1016/j.jiec.2013.07.041.
  9. Gryta, M. (2010), "Application of membrane distillation process for tap water purification", Membr. Water Treat., 1(1), 1-12. https://doi.org/10.12989/MWT.2010.1.1.001
  10. Haan, T.Y., Shah, M., Chun, H.K. and Mohammad, A.W. (2018). "A study on membrane technology for surface water treatment: Synthesis, characterization and performance test", Membr. Water Treat., 9(2), 69-77. https://doi.org/10.12989/MWT.2018.9.2.069
  11. Hou, D., Wang, J., Qu, D., Luan, Z. and Ren, X. (2009), "Fabrication and characterization of hydrophobic PVDF hollow fiber membranes for desalination through direct contact membrane distillation", Sep. Purif. Technol., 69(1), 78-86. https://doi.org/10.1016/j.seppur.2009.06.026.
  12. Kotsilkova, R., Borovanska, I., Todorov, P., Ivanov, E., Menseidov, D., Chakraborty, S. and Bhattacharjee, C. (2018), "Tensile and Surface Mechanical Properties of Polyethersulphone (PES) and Polyvinylidene Fluoride (PVDF) Membranes", J. Theor. Appl. Mech., 48(3), 85-99, https://doi.org/10.2478/jtam-2018-0018.
  13. Li, Q., Xu, Z.L. and Liu, M. (2011), "Preparation and characterization of PVDF microporous membrane with highly hydrophobic surface", Polym. Adv. Technol., 22 (5), 520-531. https://doi.org/10.1002/pat.1549.
  14. Macedonio, F. and Drioli, E. (2010), "Membrane engineering progresses in desalination and water reuse", Membr. Water Treat., 1(1), 75-81. https://doi.org/10.12989/MWT.2010.1.1.075.
  15. Munirasu, S., Banat, F., Ahmed, A. and Abu, M. (2017), "Intrinsically superhydrophobic PVDF membrane by phase inversion for membrane distillation", Desalination ,417, 77-86. https://doi.org/10.1016/j.desal.2017.05.019.
  16. Pagliero, M., Bottino, A., Comite, A. and Costa, C. (2020), "Novel hydrophobic PVDF membranes prepared by nonsolvent induced phase separation for membrane distillation", J. Membr. Sci., 596, 117575. https://doi.org/10.1016/j.memsci.2019.117575.
  17. Peydayesh, M., Mohammadi, T. and Kordmirza, S. (2020), "A positively charged composite loose nanofiltration membrane for water purification from heavy metals", J. Membr. Sci., 611, 118205. https://doi.org/10.1016/j.memsci.2020.118205.
  18. Razmjou, A., Arifin, E., Dong, G.,Mansouri, J. and Chen, V. (2012), "Superhydrophobic modification of TiO2 nanocomposite PVDF membranes for applications in membrane distillation", J. Membr. Sci., 415-416, 850-863. https://doi.org/10.1016/j.memsci.2012.06.004.
  19. Singh, J.K., Upadhyaya, S., Chaurasia, S.P. and Baghel, R. (2017), "Study on membrane fouling in vacuum membrane distillation for desalination", J. Basic Appl. Eng. Res., 4(3), 229-233.
  20. Sui, Y., Wang, Z., Gao, X. and Gao, C. (2012), "Antifouling PVDF ultrafiltration membranes incorporating PVDF-g-PHEMA additive via atom transfer radical graft polymerizations", J. Membr. Sci., 413-414, 38-47. https://doi.org/10.1016/j.memsci.2012.03.055.
  21. Sukitpaneenit, P. and Chung, T.S. (2009), "Molecular elucidation of morphology and mechanical properties of PVDF hollow fiber membranes from aspects of phase inversion, crystallization and rheology", J. Membr. Sci., 340(1-2), 192-205. https://doi.org/10.1016/j.memsci.2009.05.029.
  22. Tae, J., Kim, J.F., Hyun, H., Drioli, E. and Moo, Y. (2016), "Understanding the non-solvent induced phase separation (NIPS) effect during the fabrication of microporous PVDF membranes via thermally induced phase separation (TIPS)", J. Membr. Sci., 514, 250-263. https://doi.org/10.1016/j.memsci.2016.04.069.
  23. Tibi, F., Charfi, A., Cho, J. and Kim, J. (2020), "Fabrication of polymeric membranes for membrane distillation process and application for wastewater treatment: Critical review", Proc. Safe. Environ. Protect., 141, 190-201. https://doi.org/10.1016/j.psep.2020.05.026.
  24. Upadhyaya, S., Singh, K., Chaurasia, S.P., Dohare, R.K. and Agarwal, M. (2016), "Mathematical and CFD modeling of vacuum membrane distillation for desalination", Desalin. Water Treat., 57(26), 11956-11971. https://doi.org/10.1080/19443994.2015.1048306a.
  25. Upadhyaya, S., Singh, K., Chaurasia, S.P. and Dohare, R.K. (2016), "Recovery and development of correlations for heat and mass transfer in vacuum membrane distillation for desalination", Desalin. Water Treat., 3994. https://doi.org/10.1080/19443994.2016.1189245b.
  26. Xu, K., Cai, Y., Tavajohi, N., Cheng, Y., Li, X. and Wang, X. (2019), "ECTFE membrane fabrication via TIPS method using ATBC diluent for vacuum membrane distillation", Desalination, 456, 13-22. https://doi.org/10.1016/j.desal.2019.01.004.
  27. Yadav, M., Upadhyaya, S., Singh, K. and Vashishtha, M., (2021), "Morphological study of fabricated PVDF based hydrophobic membrane for different additives and coagulation bath temperature", Asian J. Water Environ. Pollut., 18(3), 39-47. https://doi.org/10.3233/AJW210027.
  28. Zahirifar, J., Moosavian, S.M.A., Hadi, A., Khadiv-Parsi, P. and Karimi-Sabet, J. (2018), "Fabrication of a novel octadecylamine functionalized graphene oxide/PVDF dual-layer flat sheet membrane for desalination via air gap membrane distillation", Desalination, 428, 227-239. https://doi.org/10.1016/j.desal.2017.11.028.
  29. Zhang, J., Li, J. and Gray, S. (2011), "Effect of applied pressure on performance of PTFE membrane in DCMD", J. Membr. Sci., 369(1-2), 514-525. https://doi.org/10.1016/j.memsci.2010.12.033.
  30. Zhu, H., Wang, H., Wang, F., Guo, Y., Zhang, H. and Chen, J. (2013), "Preparation and properties of PTFE hollow fiber membranes for desalination through vacuum membrane distillation", J. Membr. Sci., 446, 145-153. https://doi.org/10.1016/j.memsci.2013.06.037.