Journal of Electrochemical Science and Technology

  • 제13권2호
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  • Pages.227-236
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  • 2022
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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A New Perspective on the Advanced Microblade Cutting Method for Reliable Adhesion Measurement of Composite Electrodes

  • Song, Jihun (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST)) ;
  • Shin, Dong Ok (Intelligent Sensors Research Section, Electronics and Telecommunications Research Institute (ETRI)) ;
  • Byun, Seoungwoo (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST)) ;
  • Roh, Youngjoon (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST)) ;
  • Bak, Cheol (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST)) ;
  • Song, Juhye (Intelligent Sensors Research Section, Electronics and Telecommunications Research Institute (ETRI)) ;
  • Choi, Jaecheol (Intelligent Sensors Research Section, Electronics and Telecommunications Research Institute (ETRI)) ;
  • Lee, Hongkyung (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST)) ;
  • Kwon, Tae-Soon (Railroad Safety Research Division, Korea Rairoad Research Institute (KRRI)) ;
  • Lee, Young-Gi (Intelligent Sensors Research Section, Electronics and Telecommunications Research Institute (ETRI)) ;
  • Ryou, Myung-Hyun (Department of Chemical and Biological Engineering, Hanbat National University) ;
  • Lee, Yong Min (Department of Energy Science and Engineering, Daegu Gyeongbuk Institute of Science and Technology (DGIST))
  • 투고 : 2021.10.06
  • 심사 : 2021.10.25
  • 발행 : 2022.05.28
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초록

The microblade cutting method, so-called SAICAS, is widely used to quantify the adhesion of battery composite electrodes at different depths. However, as the electrode thickness or loading increases, the reliability of adhesion values measured by the conventional method is being called into question more frequently. Thus, herein, a few underestimated parameters, such as friction, deformation energy, side-area effect, and actual peeing area, are carefully revisited with ultrathick composite electrodes of 135 ㎛ (6 mAh cm-2). Among them, the existence of side areas and the change in actual peeling area are found to have a significant influence on measured horizontal forces. Thus, especially for ultrahigh electrodes, we can devise a new SAICAS measurement standard: 1) the side-area should be precut and 2) the same actual peeling area must be secured for obtaining reliable adhesion at different depths. This guideline will practically help design more robust composite electrodes for high-energy-density batteries.

키워드

과제정보

This work was supported by an Electronics and Telecommunications Research Institute (ETRI) grant funded by the Korean government [21ZB1200, Development of ICT Materials, Components, and Equipment Technologies], the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (No. 2020R1A4A4079810) and the grant from R&D Program of the Korea Railroad Research Institute (KRRI), Republic of Korea. We are also very grateful for the support from the DGIST Supercomputing and Bigdata Center.

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