Membrane and Water Treatment

  • 제13권3호
  • /
  • Pages.139-145
  • /
  • 2022
  • /
  • 2005-8624(pISSN)
  • /
  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Cellulose acetate membrane preparation by phase inversion to estimate optimized parameters and its performance study

  • Katariya, Heena N (Department of Chemical Engineering, S. S Agrawal Institute of Engineering & Technology) ;
  • Patel, Tejal M (Department of Chemical Engineering, G H Patel College of Engineering & Technology)
  • 투고 : 2021.11.10
  • 심사 : 2022.03.12
  • 발행 : 2022.05.25
⟨ 이전 논문 다음 논문 ⟩

초록

Development in advanced separation processes leads to the significant advancement in polymeric membrane preparation methodology. Therefore, present research investigated the preparation and characterization of cellulose acetate membrane by phase inversion separation method to determine optimized operating parameters. Prepared CA membrane's performance was been analyzed in terms of % rejection and flux. Investigation was conducted to study effect of different parameters such as polymer concentration, evaporation rate, thickness of film, coagulation bath properties, temperature of polymer solution and of the coagulation bath etc. CA membrane was fabricated by taking polymer concentration 10wt% and 11wt% with zero second evaporation time and varying film thickness over non-woven polyester fabric. Effect of coagulation bath temperature (CBT) and casting solution temperature were also been studied. The experimental results from SEM showed that the surface morphology had been changed with polymer r concentration, coagulation bath and casting solution temperature, etc. Lower polymer concentration leads to lower precipitation time giving porous membrane. The prepared membrane was tested for advanced waste water treatment of relevant effluent stream in pilot plant to study flux and rejection behavior of the membrane.

키워드

과제정보

The authors are thankful to Department of Chemical Engineering, S.S. Agrawal Institute of Engineering & Technology, management of G H Patel College of Engineering & Technology, Vallabh Vidyanagar, Gujarat (India) for their support towards setting of membrane laboratory and for permission to publish research work.

참고문헌

  1. Alihemati, Z., Hashemifard, S.A., Matsuura, T., Ismail, A.F. and Hilal, N. (2020), "Current status and challenges of fabricating thin film composite forward osmosis membrane: A comprehensive roadmap", Desalination, 491(April), 1-31. https://doi.org/10.1016/j.desal.2020.114557.
  2. Amirilargani, M., Saljoughi, T., Mohammadi, T. and Moghbeli, M. (2010), "Effects of coagulation bath temperature and polyvinylpyrrolidone content on flat sheet asymmetric polyethersulfone membranes", Polym. Eng. Sci., 50(5), 885-893. https://doi.org/10.1002/pen.21603.
  3. Bagheripour, E., Moghadassi, A.R. and Hosseini, S.M. (2016), "Preparation and characterization of pes-blend-sulfonated PVC nanofiltration membranes: Investigation of polymers blend ratio", Arab. J. Sci. Eng., 41(7), 2545-2552. https://doi.org/10.1007/s13369-016-2026-5.
  4. Buonomenna, M.G., Macchi, P., Davoli, M. and Drioli, E. (2007), "Poly(vinylidene fluoride) membranes by phase inversion: The role the casting and coagulation conditions play in their morphology, crystalline structure and properties", Eur. Polym. J., 43(4), 1557-1572. https://doi.org/10.1016/j.eurpolymj.2006.12.033.
  5. El-Gendi, A., Abdalla, H. and Ali, S. (2012), "Construction of ternary phase diagram and membrane morphology evaluation for polyamide/formic acid/water system", Austral. J. Basic Appl. Sci., 6(5), 62-68.
  6. Guillen, G.R., Pan, Y., Li, M. and Hoek, E.M.V. (2011), "Preparation and characterization of membranes formed by nonsolvent induced phase separation: A review", Ind. Eng. Chem. Res., 50(7), 3798-3817. https://doi.org/10.1021/ie101928r.
  7. Haan, T., Shah, M., Chun, H., Wahab, M. (2018), "A study on membrane technology for surface water treatment: Synthesis, characterization and performance test", Membr. Water Treat., 9(2), 69-77. https://doi.org/10.12989/mwt.2018.9.2.069.
  8. Hazrati, H., Karimi, N., Jafarzadeh, Y. (2020), "Performance and antifouling properties of PVDF/PVP and psf membranes in MBR: A comparative study", Membr. Water Treat., 11(2), 159-166. https://doi.org/10.12989/mwt.2020.11.2.159.
  9. Hwang, J.R., Koo, S.H., Kim, J.H., Higuchi, A. and Tak, T.M. (1996), "Effects of casting solution composition on performance of poly(ether sulfone) membrane", J. Appl. Polym. Sci., 60(9), 1343-1348. https://doi.org/10.1002/(SICI)1097-4628(19960531) 60:9<1343::AID-APP9>3.0.CO;2-J.
  10. Keller, A., Sakthivadivel, R. and Seckler, D. (2000), "Water scarcity and the role of storage in development", Research Report No. R39; International Water Management Institute, Colombo, Srilanka.
  11. Kusumawati, N., Setiarso, P. and Muslim, S. (2018), "Polysulfone/polyvinylidene fluoride composite membrane: Effect of coating dope composition on membrane characteristics and performance", Rasayan J. Chem., 11(3), 1034-1041. https://doi.org/10.31788/RJC.2018.1133020.
  12. Kusworo, T.D., Budiyono, Ikhsan, D., Rokhati, N., Prasetyaningrum, A., Mutiara, F.R. and Sofiana, N.R. (2017), "Effect of combination dope composition and evaporation time on the separation performance of cellulose acetate membrane for demak brackish water treatment", MATEC Web Conf., 101, 01004. https://doi.org/10.1051/matecconf/201710101004.
  13. Mulder, M. (1996), Basic Principles of Membrane Technology, Kluwer Academic Publishers, Dordrecht, Netherlands.
  14. Phale, J.S. and Chendake, Y.J. (2013), "Polysulfone based ultrafiltration membrane preparation by phase inversion: parameter optimization", Int. J. Sci. Res., 5(6), 2319-7064.
  15. Pinem, J.A. (2016), "Performance of cellulose acetate membrane for water treatment in riau coastal region", Int. J. Sci. Res., 5(10), 2013-2016.
  16. Sifat, S., Membran, M., Rata, K., Vinilidena, P., Kesan, T., Polimer, K., Nasib, A.M., Hatim, I., Jullok, N. and Alamery, H.R. (2017), "Morphological properties of poly (vinylidene fluoride-co- tetrafluoroethylene membrane) : Effect of solvents and polymer concentration", 21(2), 356-364. https://doi.org/10.17576/mjas-2017-2102-10.
  17. Sutedja, A., Josephine, C. and Mangindaan, D. (2017), "Polysulfone thin film composite nanofiltration membranes for removal of textile dyes wastewater", Proceeding of the International Conference on Eco Engineering Development, Yogyakarta, Indonesia, November.
  18. Tan, X.M. and Rodrigue, D. (2019), "A review on porous polymeric membrane preparation. Part II: Production techniques with polyethylene, polydimethylsiloxane, polypropylene, polyimide, and polytetrafluoroethylene", Polymers, 11(8). https://doi.org/10.3390/polym11081310.
  19. Tiron, L.G., Pintilie, C., Vlad, M., Birsan, I.G. and Balta. (2017), "Characterization of polysulfone membranes prepared with thermally induced phase separation technique", Proceedings of the International Conference on Innovative Research, Iasi, Romania, June.
  20. Wang, X., Ba, X., Cui, N., Ma, Z., Wang, L., Wang, Z. and Gao, X. (2019), "Preparation, characterisation, and desalination performance study of cellulose acetate membranes with MIL-53(Fe) additive", J. Membr. Sci., 590, 117057. https://doi.org/10.1016/j.memsci.2019.04.061.
  21. Zinadini, S. and Gholami, F. (2016), "Preparation and characterization of high flux PES nanofiltration membrane using hydrophilic nanoparticles by phase inversion method for application in advanced wastewater treatment", J. Appl. Res. Water Wastewater, 3(1), 232-235.