DOI QR코드

DOI QR Code

총유기탄소 분석을 위한 유리섬유를 이용한 이산화티타늄 광촉매 반응

TiO2 Photocatalytic Reaction on Glass Fiber for Total Organic Carbon Analysis

  • 박범근 (한국세라믹기술원 소재융합고도화연구본부) ;
  • 이영진 (한국세라믹기술원 소재융합고도화연구본부) ;
  • 신정희 (한국세라믹기술원 소재융합고도화연구본부) ;
  • 백종후 (한국세라믹기술원 소재융합고도화연구본부)
  • Park, Buem Keun (Advanced Materials Convergence R&D Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Lee, Young-Jin (Advanced Materials Convergence R&D Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Shin, Jeong Hee (Advanced Materials Convergence R&D Division, Korea Institute of Ceramic Engineering & Technology) ;
  • Paik, Jong-Hoo (Advanced Materials Convergence R&D Division, Korea Institute of Ceramic Engineering & Technology)
  • 투고 : 2022.01.22
  • 심사 : 2022.03.18
  • 발행 : 2022.03.31

초록

Currently, the demand for real-time monitoring of water quality has increased dramatically. Total organic carbon (TOC) analysis is a suitable method for real-time analysis compared with conventional biochemical oxygen demand (BOD) and chemical oxygen demand (COD) methods in terms of analysis time. However, this method is expensive because of the complicated internal processes involved. The photocatalytic titanium dioxide (TiO2)-based TOC method is simpler as it omits more than three preprocessing steps. This is because it reacts only with organic carbon (OC) without extra processes. We optimized the rate between the TiO2 photocatalyst and binder solution and the TiO2 concentration. The efficiency was investigated under 365 nm UV exposure onto a TiO2 coated substrate. The optimized conditions were sufficient to apply a real-time monitoring system for water quality with a short reaction time (within 10 min). We expect that it can be applied in a wide range of water quality monitoring industries.

키워드

과제정보

본 연구는 2020년도 환경부 환경기술개발사업 '상하수도 혁신기술개발사업 (No. RE202001418)'의 지원을 받아 수행되었다.

참고문헌

  1. J. H. Park, B. K. Park, J. K. Lee, and D. H. Rhew, "Necessity of Refractory Organic Matters Management in Total Maximum Daily Loads (TMDLs)", J. Korean Soc. Water Environ., Vol. 29, No. 3, pp. 393-399, 2013.
  2. I. K. Choi, J. H. Kim, J. K. Im, T. J. Park, S. Y. Kim, D. H. Son, I. A. Huh, D. H. Rhew, and S. J. Yu, "Application of TOC Standards for Managing Refractory Organic Compounds in Industrial Wastewater", J. Korean Soc. Water Environ., Vol. 31, No. 1, pp. 29-34, 2015. https://doi.org/10.15681/KSWE.2015.31.1.29
  3. G. Visco, L. Campanella, and V. Nobili, "Organic carbons and TOC in waters: an overview of the international norm for its measurements", Microchem. J., Vol. 79, No. 1-2, pp. 185-191, 2005. https://doi.org/10.1016/j.microc.2004.10.018
  4. J. K. Kim, J. C. Jung, and T. J. Kim, "A Study on Measurement of Biochemical Oxygen Demand of Livestock Wastewater", J. Applied Micromagnetic Energy, Vol. 3, No. 1, pp. 7-11, 2005.
  5. S. Jouanneau, L. Recoules, M. J. Durand, A. Boukabache, V. Picot, Y. Primault, A. Lakel, M. Sengelin, B. Barillon, and G. Thouand, "Methods for assessing biochemical oxygen demand (BOD): A review", Wat. Res., Vol. 49, pp. 62-82, 2014. https://doi.org/10.1016/j.watres.2013.10.066
  6. D. Mamais, D. Jenkins, and P. Prrr, "A rapid physicalchemical method for the determination of readily biodegradable soluble COD in municipal wastewater", Wat. Res., Vol. 27, No. 1, pp. 195-197, 1993. https://doi.org/10.1016/0043-1354(93)90211-Y
  7. S. H. Choi, M. E. Jeong, K. Y. Joo, Y. J. Choi, N. N. Yoon, J. S. Kwak, J. H. Lee, Y. R. Kim and D. Y. Jeon, "Study on Correlations between Total Organic Carbon and Organic Matter Indexes in Industrial Wastewater from Busan", J. Environ. Anal., Vol. 23, No. 1, pp. 1-8, 2020.
  8. B. A. Schumacher, "Methods for the determination of total organic carbon (TOC) in soils and sediments", NCEA-C-1282, Washington, DC, pp.1-23, 2002.
  9. B. K. Park, S. M. Kim, Y. J. Lee, J. H. Paik and J. H. Shin, "The method for total organic carbon analysis employing TiO2 photocatalyst", J. Sens. Sci. Technol., Vol. 30, No. 5, pp. 320-325, 2021. https://doi.org/10.46670/JSST.2021.30.5.320
  10. S. D. Kim, D. G. Jung, S. Y. Kwon, Y. C. Choi, J. Y. Lee, S. M. Koo, and S. H. Kong, "Total Organic Carbon Analysis Chip Based on Photocatalytic Reaction", J. Sens. Sci. Technol., Vol. 29, No. 2, pp. 128-132, 2020. https://doi.org/10.5369/JSST.2020.29.2.128
  11. J. Y. Kim, J. S. Lee, J. H. Hwang, T. Y. Lim, M. J. Lee, S. K. Hyun, and J. H. Kim, "Fabrication of Hydrophobic Anti-reflection Coating Film by Using Sol-gel Method", Korean J. Mater. Res., Vol. 24, No. 12, pp. 689-693, 2014. https://doi.org/10.3740/MRSK.2014.24.12.689