DOI QR코드

DOI QR Code

CO2 Capture from the Hydrogen Production Processes

수소생산 공정에서의 이산화탄소 포집

  • Yeon Ki, Hong (School of Chemical and Material Engineering, Korea National University of Transportation)
  • 홍연기 (한국교통대학교 응용화학에너지공학부)
  • Received : 2022.11.01
  • Accepted : 2022.11.18
  • Published : 2022.11.30

Abstract

Interest in hydrogen production to respond to climate change is increasing. Until now, hydrogen has been mainly produced through the SMR (Steam Methane Reforming) process using natural gas. A large amount of CO2 is emitted in the hydrogen production process through SMR, and the gas flow including CO2 generated in the SMR process has different characteristics for each emission source, so it is important to apply a suitable CO2 capture process. In the case of PSA tail gas or synthesis gas, the applicability of an amine-based process has been confirmed or demonstrated close to a commercial level. However, in the case of the flue gas generated from the reformer, it is still difficult to apply the conventional amine-based process because the partial pressure of CO2 is relatively low. Energy-saving innovative absorbents such as phase separation absorbents can be a solution to these difficulties.

Keywords

Acknowledgement

본 연구는 2022년 한국교통대학교의 지원을 받아 수행하였음

References

  1. IEA, Net Zero by 2050-A Roadmap for the Global Energy Sector, 2021.
  2. Digital Refining, Options for CO2 capture from SMR, https://www.digitalrefining.com/article/1001013, 2014.
  3. S. Reddy and S. Vyas, "Recovery of Carbon Dioxide and Hydrogen from PSA Tail Gas," Energy Procedia, 1, 149, 2009.
  4. P. Terrien, F. Lockwood, L. Granadas, and T. Morel, "CO2 Capture from H2 Plants: Implementation for EOR," Energy Procedia, 63, 7861, 2014.
  5. D. Pichot, L. Granados, T. Morel, A. Schuller, R. Dubettier, and F. Lockwood, "Start-up of Port-Jerome CRYOCAPTM Plant: Optimized Cryogenic CO2 Capture from H2 Plant," Energy Procedia, 114, p. 2682, 2017.
  6. L. Rock, S. O'Brien, S. Tessarolo, J. Duer, V. O. Bacci, B. Hirst, D. Randell, M. Helmy, J. Blackmore, C. Duong, A. Halladay, N. Smith, T. Dixit, S. Kassam, and M. Yaychuk, "The Quest CCS Project: 1st Year Review Post Start of Injection," Energy Procedia, 114, p.5320, 2017.
  7. A. Busse, G. Power, and J. MacMurray, "Demonstration of Carbon Capture and Sequestration of Steam Methane Reforming Process Gas Used for LargeScale Hydrogen Product," Interim Technical Report to US DOE, DE-FE0002381, Air Products and Chemicals Inc., 2017.
  8. Axens, "What options are there for CO2 capture from a SMR based hydrogen unit?", https://www.axens. net/resources-events/faq/faq-what-options-are-there-c o2-capture-smr-based-hydrogen-unit.
  9. A. Bhadola, V. Patel, S. Potdar, and S. Mallick, "Technology Scouting Carbon Capture: From Today's to Novel Technologies," Concawe Report, 2020.
  10. Shell Catalysts & Technologies, "Carbon Dioxide Capture Options for Steam Methane Reforming Based Hydrogen Manufacturing Units," White paper, 2021.