Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
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Recent Research Trend of Zeolitic Imidazolate Framework-67 for Bifunctional Catalyst

ZIF-67을 이용한 이기능성 촉매의 최신연구 동향

  • Kim, Sang Jun (Department of Materials Science and Engineering, Pusan National University) ;
  • Jo, Seung Geun (Department of Materials Science and Engineering, Pusan National University) ;
  • Park, Gil-Ryeong (Department of Materials Science and Engineering, Pusan National University) ;
  • Lee, Eun Been (Department of Materials Science and Engineering, Pusan National University) ;
  • Lee, Jae Min (Department of Materials Science and Engineering, Pusan National University) ;
  • Lee, Jung Woo (Department of Materials Science and Engineering, Pusan National University)
  • 김상준 (부산대학교 재료공학과) ;
  • 조승근 (부산대학교 재료공학과) ;
  • 박길령 (부산대학교 재료공학과) ;
  • 이은빈 (부산대학교 재료공학과) ;
  • 이재민 (부산대학교 재료공학과) ;
  • 이정우 (부산대학교 재료공학과)
  • Received : 2022.01.09
  • Accepted : 2022.02.07
  • Published : 2022.02.27
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Abstract

Metal-organic frameworks (MOFs) are widely used in various fields because they make it easy to control porous structures according to combinations of metal ions and organic linkers. In addition, ZIF (zeolitic imidazolate framework), a type of MOF, is made up of transition metal ions such as Co2+ or Zn2+ and linkers such as imidazole or imidazole derivatives. ZIF-67, composed of Co2+ and 2-methyl imidazole, exhibits both chemical stability and catalytic activity. Recently, due to increasing need for energy technology and carbon-neutral policies, catalysis applications have attracted tremendous research attention. Moreover, demand is increasing for material development in the electrocatalytic water splitting and metal-air battery fields; there is also a need for bifunctional catalysts capable of both oxidation/reduction reactions. This review summarizes recent progress of bifunctional catalysts for electrocatalytic water splitting and metal-air batteries using ZIF-67. In particular, the field is classified into areas of thermal decomposition, introduction of heterogeneous elements, and complex formation with carbon-based materials or polyacrylonitrile. This review also focuses on synthetic methods and performance evaluation.

Keywords

Acknowledgement

This work was supported by a 2-Year Research Grant of Pusan National University.

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