DOI QR코드

DOI QR Code

Characteristics of Chloride Diffusion and Compressive Strength in the Mortar containing C12A7 based Binder and Anhydrite

C12A7계 바인더와 무수석고를 혼입한 모르타르의 염화물 확산 및 압축강도 특성

  • Byeong-Cheol, Lho (Department of Civil Engineering, Sangji University) ;
  • Yong-Sik, Yoon (Department of Civil and Environmental Engineering, Hannam University)
  • 노병철 (상지대학교 건설시스템공학과 ) ;
  • 윤용식 (한남대학교 토목환경공학과)
  • Received : 2022.11.10
  • Accepted : 2022.12.02
  • Published : 2022.12.30

Abstract

In this study, as the preliminary research on the development of heating concrete members, compressive strength and accelerated chloride diffusion behavior in the mortar specimens containing C12A7 based binder and anhydrite was evaluated. Also, the effect of the mixing ratio of the citric acid based retarder was quantitatively evaluated by considering 4 levels of mixing cases. The compressive strength tests of the mortar specimen were performed referred to KS L ISO 679, and the accelerated chloride diffusion tests were performed according to NT BUILD 492 and ASTM C 1202. In the mortar with 0.3 % of retarder, the highest compressive strength was evaluated, which showed the strength development ratio of 127.6 % compared to the control case. It was considered that engineering performance was improved by effectively securing setting and curing time with 0.3 % of citric acid based retarder. As the result of the evaluation of the passed charge and the accelerated chloride diffusion coefficient, the evaluation results had similar behavior with the results of compressive strength. According to the previous study, the strength behavior and the chloride diffusion behavior had a linear relationship. The mixture showing the highest strength performance had the highest durability performance for chloride ingress, and the heating concrete development from this study will be performed in the future.

본 연구에서는 발열 콘크리트 부재 개발의 사전 연구로써 C12A7계 바인더와 무수석고를 혼입한 모르타르 시편의 압축강도 및 촉진 염화물 확산 거동을 분석하였다. 또한, 무수구연산계 지연제의 혼입률 4수준을 고려하여 지연제 혼입률이 미치는 영향을 정량적으로 평가하였다. 모르타르 시편의 압축강도는 KS L ISO 679, 촉진 염화물 확산 시험은 NT BUILD 492 및 ASTM C 1202에 준하여 수행하였다. 무수구연산 지연제 혼입률이 0.3 %인 경우에서 가장 높은 강도가 평가되었으며 이는 컨트롤 케이스 대비 127.6 %의 강도 증진률을 나타내었다. 무수구연산 지연제 혼입률 0.3 %에서 효과적으로 가사시간 및 경화 시간을 확보하여 성능이 개선된 것으로 사료된다. 통과 전하량 및 촉진 염화물 확산계수 평가 결과 압축강도와 비슷한 성능 평가 결과가 도출되었으며, 기존의 연구에 따르면 강도 거동과 염화물 확산 거동은 선형적 관계를 갖기 때문이다. 가장 높은 강도 성능을 나타낸 배합에서 가장 높은 염해 저항성을 나타내었으며, 본 연구 결과를 기반으로 추후 발열 콘크리트 부재 개발을 수행할 계획이다.

Keywords

Acknowledgement

본 연구는 국토교통부/국토교통과학기술진흥원의 지원으로 수행되었음(과제번호22RITD-C162337-02).

References

  1. ASTM C 1202 (2005). Standard test method for electrical indication of concrete's ability to resist chloride ion penetration, American Society for Testing and Materials, USA.
  2. Berke, N.S., Hicks, M.C. (1994). Predicting chloride profiles in concrete, Corrosion, 50(3), 234-239. https://doi.org/10.5006/1.3293515
  3. Broomfield, J.P. (1997). Corrosion of steel in concrete - Understanding, investigation and repair, E&FN, London, 1-15.
  4. Choi, M.S., Jang, S.H., Lee, B.H. (2013). High performance wet-mix shotcrete using alkali-free accelerator and HPA for early and high stabilization of tunnel, Magazine of Korean Recycled Construction Resources Institute, 8(3), 36-40 [In Korean].
  5. Jo, B.W., Kim, S.K., Choi, J.S., Kim, D., Kim, T.Y. (2013). "Basic study by multi-walled carbon nanotube(MWCNT) for radiation shielding concrete", The Conference of Korea Society of Civil Engineers, 10, 16-18 [In Korean].
  6. KS L ISO 679 (2021). Methods of testing cements - Determination of strength, Korea Standard Service Network, Korea [In Korean].
  7. Kim, Y.M., Lim, C.M., Kwon, H.W., Lee, G.C. (2022). "Heat generation characteristics of the heating mortar according to repeated electricity supply", The Spring Conference of Korea Institute Building Construction, 20-22 [In Korean].
  8. Lee, S.K., Zielske, J. (2014). An FHWA special study: Post-tensioning tendon grout chloride thresholds(FHWA-HRT14-039), Federal Highway Administration, McLean, 7-20.
  9. Metha, P.K., Monteiro, P.M. (2009). Concrete - Structure, properties, and materials, 2nd Edition, Prentice Hall, New-Jersey, 113-178.
  10. NT BUILD 492 (1999). Concrete, mortar and cement-based repair materials: Chloride migration coefficient from non-stead-state migration experiments, Nordtest, Espoo, Finland.
  11. Oh, K.S., Moon, J.M., Park, K.T., Kwon, S.J. (2016). Evaluation of load capacity reduction in RC beam with corroded FRP hybrid bar and steel, Journal of the Korea Institute for Structural Maintenance and Inspection, 20(2), 10-17 [In Korean].
  12. Oh, S.W., Oh, K.S., Jung, S.H., Chung, W.S., Yoo, S.W. (2017). Effects of CNT additions on mechanical properties and microstructures of cement, Journal of the Korea Institute for Structural Maintenance and Inspection, 21(6), 162-168 [In Korean].
  13. Park, S.H., Chu, Y.S., Seo, S.K., Park, J.W. (2013). Properties of shrinkage reducing agent and mortar used Anhydrite and CA7-based slag, Journal of Korean Recycled Construction Resources Institute, 1(2), 101-106 [In Korean]. https://doi.org/10.14190/JRCR.2013.1.2.101
  14. Park, S.H., Lee, H.Y., Chung, W.S. (2018). Experimental study on voltage supply efficiency of nano cement composite for prevention of road icing, Journal of The Korean Society of Hazard Mitigation, 18(6), 221-228 [In Korean].
  15. Park, S.H., An,S.J., Lee, H.Y., Kim, D.H., Chung, W.S. (2021). Heating performance of MWCNT module according to size effect, Journal of The Korean Society of Hazard Mitigation, 21(5), 175-182 [In Korean]. https://doi.org/10.9798/KOSHAM.2021.21.5.175
  16. Williams, D.D., Williams, N.E., Cao, Y. (2000). Road salt contamination of groundwater in a major metropolitan area and development of a biological index to monitor its impact, Water Research, 34(1), 127-138.
  17. Won, J.P., Hwang, U.J., Lee, S.J., Lee, J.H., Jang, S.B. (2014). Long-term strength of shotcrete with improved C12A7 based mineral accelerator, Journal of Korean Tunnelling and Underground Space Association, 16(2), 135-148 [In Korean]. https://doi.org/10.9711/KTAJ.2014.16.2.135
  18. Yoon, Y.S., Ryu, H.S., Lim, H.S., Koh, K.T., Kim, J.S., Kwon, S.J. (2018a). Effect of grout conditions and tendon location on corrosion pattern in PS tendon in grout, Construction and Building Materials, 186(2018), 1005-1015. https://doi.org/10.1016/j.conbuildmat.2018.08.023
  19. Yoon, Y.S., Lim, H.S., Kwon, S.J. (2018b). Evaluation of apparent chloride diffusion coefficient of fly ash concrete by marine environment exposure tests, Journal of the Korea Institute for Structural Maintenance and Inspection, 23(3), 1-8 [In Korean].
  20. Yoon, Y.S., Kwon, S.J. (2018). Evaluation of time-dependent chloride resistance in HPC containing fly ash cured for 1 year, Journal of the Korea Institute for Structural Maintenance and Inspection, 22(4), 52-59 [In Korean].