DOI QR코드

DOI QR Code

잡곡 농산물의 잔류농약 안전성 조사

A Study on the Safety of Residual Pesticides in Cereal Grains and Pulses Agricultural Products Excluding Rice

  • 한나은 (경기도보건환경연구원 안산농수산물검사소) ;
  • 김재관 (경기도보건환경연구원 안산농수산물검사소) ;
  • 윤희정 (경기도보건환경연구원 안산농수산물검사소) ;
  • 강민성 (경기도보건환경연구원 안산농수산물검사소) ;
  • 조영선 (경기도보건환경연구원 안산농수산물검사소) ;
  • 송지원 (경기도보건환경연구원 안산농수산물검사소) ;
  • 김병태 (경기도보건환경연구원 안산농수산물검사소) ;
  • 이성남 (경기도보건환경연구원 안산농수산물검사소) ;
  • 최옥경 (경기도보건환경연구원 안산농수산물검사소)
  • Han, Na-Eun (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Kim, Jae-Gwan (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Yun, Hee-Jeong (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Kang, Min-Seong (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Cho, Young-Seon (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Song, Ji-Won (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Kim, Byeong-Tae (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Lee, Seong-Nam (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment) ;
  • Choi, Ok-Kyung (Ansan Agricultural and Fishery Products Inspection Center Gyeonggi Province Institute of Health and Environment)
  • 투고 : 2021.12.27
  • 심사 : 2022.02.04
  • 발행 : 2022.02.28

초록

본 연구는 2021년 2월부터 7월까지 잡곡 106건을 수거하여 잔류농약 실태조사를 하였다. 대형, 중소형 및 온라인 유통매장을 중심으로 국내 잡곡 40건과 수입 잡곡 66건을 수거하였고, GC/MSMS, GC/ECD, GC/NPD, LC/MSMS, UPLC/PDA, HPLC/FLD를 이용하여 다종농약 다성분분석법으로 잔류농약 341종을 분석하였다. 잔류농약이 검출된 잡곡은 대형유통매장 1건, 중소형 유통매장 2건, 온라인 유통매장 5건으로 총 8건(7.5%)이었고, 5건(4.7%)에서는 농약잔류허용기준을 초과하였다. 이들 잡곡에서는 MGK-264, chlorpyrifos, thiamethoxam, malathion, piperonyl butoxide, pirimiphos-methyl 등 6종의 농약 성분이 검출되었다. 검출된 잡곡은 강낭콩(1건), 녹두(6건), 수수(1건)이다. 검출된 잡곡 중 농약잔류허용기준을 초과한 품목은 수입 녹두(5건)로 미얀마산이었고, 초과한 농약 성분은 thiamethoxam이었다.

In this study, the pesticide residues in 106 commercial cereal grains were monitored from February to July 2021. For the investigation, 40 domestic and 66 imported products from large, small-to-medium sized offline and online distribution channels, were collected and analyzed by using the multiresidue method for 341 pesticides on GC/ECD, GC/NPD, GC/MSMS, UPLC/PDA, HPLC/FLD, LC/MSMS. Pesticides were detected in total of 8 samples (7.5%), of which one was from big box retailers, two from small and medium-sized distribution stores, and five from online shopping mall. Five (4.7%) samples were found to have pesticide residues greater than the maximum residue limits (MRLs). The detected pesticides in kidney beans (1 case), mung beans (6 cases), and sorghum (1 case), were MGK-264, chlorpyrifos, thiamethoxam, malathion, piperonyl butoxide, and pirimiphos-methyl. Specifically, an excessive amount of thiamethoxam was found from the imported mung bean (5 cases).

키워드

참고문헌

  1. Kim, Y.S., Lee, M.S., Song, D.J., Oh, Y.J., A survey on the consumption and satisfaction degree of the cooked rice mixed with multi-grain in Seoul.Kyeonggi and Kangwon area. J. Korean Sco. Food Cult., 21, 661-669 (2006).
  2. Kang, M.S., Nutritional composition and cooking characteristics of mixed cereals. MA thesis, Jeju National University, Jeju, Korea (2002).
  3. Lim, S.B., Kang, M.S., Jwa, M.K., Song, D.J., Oh, Y.J., Characteristics of cooked rice by adding grains and legumes. J. Korean Soc. Food Sci. Nutr., 32, 52-57 (2003). https://doi.org/10.3746/JKFN.2003.32.1.052
  4. Kwak, C.S, Lim, S.J., Kim, S.A., Park, S.C., Lee, M.S., Antioxidative and antimutagenic effects of Korean buckwheat, sorghum, millet and Job's tears. J. Korean Soc. Food Sci. Nutr., 33, 921-929 (2004). https://doi.org/10.3746/JKFN.2004.33.6.921
  5. Jung, S.K., 1998. Perspectives and strategies. Proceedings KSCS and KBS Symposium For 50th Anniverary GSNU, Cheong-ju, Korea, pp. 266 - 287.
  6. Park, K.S., Im, M.H., Choi, D.M., Jeong, J.Y., Chang, M.I., Kwon, K.I., Hong, M.K., Lee, C.W., Establishment of Korean maximum residue limits for pesticides in foods. Korean J. Pestic. Sci., 9, 51-59 (2005).
  7. Jung, Y.J., Cho, Y.J., Kim, K.W., Yoon, K.Y., Current Status and development plan of the Korean mixed grains industry. Food Preserv Processing Indust, 12, 31-39 (2013).
  8. Jeon, Y.H., Kim, H.Y., Hwang, J.I., Kim, J.H., Do, J.A., Im, M.H., Oh, J.H. Kwon, K.S., Lee, J.K., Lee, Y.D., Kim, J.E., Application of multiresidue analysis method of unregistered pesticides in Korea for imported food. Korean J. Environ. Agric., 30, 339-345 (2011). https://doi.org/10.5338/KJEA.2011.30.3.339
  9. Ministry of Food an Drug Safety, (2022, January 27). New System for Management of Pesticide Residues in Food(PLS). Retrieved from https://mfds.go.kr/brd/m_74/view.do?seq=36124&srchFr=&srchTo=&srchWord=&srchTp=&itm_seq_1=0&itm_seq_2=0&multi_itm_seq=0&company_cd=&company_nm=&page=69
  10. Park, J.H., Kim, T.K., Oh, C.H., Kim, J.H., Lee, Y.D., Kim, J.E., Analysis of multiple pesticide residues in apples and pears using gas-liquid chromatography. Korean J. Environ. Agric., 23, 148-157 (2004). https://doi.org/10.5338/KJEA.2004.23.3.148
  11. Ministry of Food and Drug Safety, (2022, January 27). Korean Food Code. Retrieved from https://www.mfds.go.kr/brd/m_211/view.do?seq=14583&srchFr=&srchTo=&srchWord=%EC%8B%9D%ED 92%88&srchTp=0&itm_seq_1=0&itm_seq_2=0&multi_itm_seq=0&company_cd=&company_nm=&Data_stts_gubun=C9999&page=3
  12. Ministry of Food and Drug Safety, (2022, January 27). Analytical practices manual for pesticide residues in foods. 5th Ed. 3. Retrieved from https://www.foodsafetykorea.go.kr/residue/article/view.do?articleKey=18&searchTitleFlag=1&boardKey=0&menuKey=4&subMenuKey=5¤tPageNo=1
  13. The International council for harmonisation of technical requirements for pharmaceuticals for human use (ICH), Quality Guidelines, Validation of Analytical Procedures, (2022, January 27). Retrieved from https://database.ich.org/sites/default/files/Q2_R1__Guideline.pdf
  14. Ministry of Food and Drug Safety, Guidelines on standard procedures for preparing analysis method, 15-16 (2016).
  15. CODEX ALIMENTARIUS., (2022, January 27). Joint FAO/WHO Food Standards Programme CODEX Alimentarius Commission. Retrieved from https://silbrico.com/wp-content/uploads/2018/10/Codex-Alimentarius.pdf
  16. Lee, P., Barefoot A., Murphy J., Aizawa, H., 2003. Handbook of residue analytical methods for agrochemicals. JohnWiley and Sons, New York, NY, USA, pp. 13-37.
  17. Gyeonggi Province Institute of Health and Environment., (2021 May 24). 2020 Statistical Yearbook of Agricultural Residual Pesticides in Gyeonggi Province. Retrieved from https://www.gg.go.kr/gg_health/gg_health_lib-science-bog un?v_mode=detail&ggd_p_id=4163244
  18. Korean Statistical Information Service, (2022, January 27). Retrieved from https://kosis.kr/statHtml/statHtml.do?orgId=145&tblId=DT_14505_2018&conn_path=I2
  19. National Pesticide Information Center, (2021, Agust 19). MGK-264. Retrieved from http://npic.orst.edu/ingred/mgk264.html
  20. Jung, K.M., Lee, H.M., Lee, E.H., Lee, S.H., Kim, J.H., Sim, Y.Y., Hong, J.T., Lee, Y.W., Human dermal risk assessment on chlorpyrifos of Korea farmers. Environment Mutagens & Carcinogens, 22, 187-198 (2002).
  21. Korea Crop Protection Association, 2009. Instructions for use of pesticide, pp. 570.
  22. Ahn, K.S., Yoon, C., Kim, K.H., Nam, S.Y., Oh, M.G., Kim, G.H., Evaluation of acute and residual toxicity of insecticides registered on strawberry against honeybee (Apis mellifera). Korean J. Pestic. Sci., 17, 185-192 (2013). https://doi.org/10.7585/kjps.2013.17.3.185
  23. Yu, J.H., Park, C.K., Decomposition characteristics of DDVP, malathion and diazinon emusifiable concentrates. Korea J. Environ. Agric., 11, 146-154 (1992).
  24. Choi, S.H., Trans-generational toxicity of piperonyl butoxide in Daphnia magna. MA thesis, University of Seoul, Seoul, Korea (2017).
  25. Seo, J.S., Chang, H.R., Hamer, M., Kim, K., Bioconcentration of pirimiphos-methyl in killifish (Oryzias latipes). Korean J. Environ. Agric., 28, 453-461 (2009). https://doi.org/10.5338/KJEA.2009.28.4.453