Textile Science and Engineering (한국섬유공학회지)

The Korean Fiber Society (한국섬유공학회)
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Cellulose Asymmetric Carbon Hollow Fiber Membrane Controlled by Radiation and Heat Treatment Conditions

방사 및 열처리 조건에 의해 제어된 셀룰로스계 비대칭 탄소 중공사막

  • In-Ju, Jang (Department of Carbon Composites Convergence Materials Engineering) ;
  • Hyun-Jae, Cho (Department of Carbon Composites Convergence Materials Engineering) ;
  • Young-Hoon, Seo (Research and Development, HUVIS) ;
  • Yong-Sik, Chung (Department of Division of Polymer-nano & Textile Engineering/Organic Materials and Textile Engineering)
  • 장인주 (전북대학교 탄소융복합재료공학과) ;
  • 조현재 (전북대학교 탄소융복합재료공학과) ;
  • 서영훈 ((주)휴비스) ;
  • 정용식 (전북대학교 유기소재섬유공학전공)
  • Received : 2022.12.07
  • Accepted : 2022.12.24
  • Published : 2022.12.31
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Abstract

This study investigated the effect of spinning and heat treatment conditions on the cellulose carbon hollow fiber membrane. A cellulose-based asymmetric carbon hollow fiber membrane has been prepared by wet spinning process and heat treatment. Cellulose was dissolved using EmimAc/DMSO and discharged in a coagulation bath at 60℃ to form asymmetric pores. To maintain the formed asymmetric pores even after the drying process, there was a stepped exchange process of solvent for the elimination of water in the fiber. The formed asymmetric pores are composed of a selective layer with dense pores and a support layer with finger-like pores. These asymmetric pores are important structures for increasing the selectivity and permeability of the carbon hollow fiber membrane. The pore structure according to the heat treatment temperature was analyzed. Because the pore size and micropores are controlled by the heat treatment condition, we applied different temperatures (550-850℃) in the heat treatment process. It was confirmed by BET that the surface area and pore size distribution improved 18.5%. As a result, it was confirmed that the structure and pore size of the cellulose carbon hollow fiber membrane were significantly affected by the spinning, solvent exchange, and heat treatment process conditions.

Keywords

References

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