DOI QR코드

DOI QR Code

에어로졸 증착한 세라믹/금속 복합막의 금속 함량에 따른 습도 감지 특성 연구

Study of Humidity Sensing Properties Related to Metal Content of Aerosol Deposited Ceramic/Metal Composite Films

  • 김익수 (광운대학교 전자재료공학과) ;
  • 구상모 (광운대학교 전자재료공학과) ;
  • 박철환 (광운대학교 화학공학과) ;
  • 신원호 (광운대학교 전자재료공학과) ;
  • 이동원 (광운대학교 전자재료공학과) ;
  • 오종민 (광운대학교 전자재료공학과)
  • Kim, Ik-Soo (Department of Electronic Materials Engineering, Kwangwoon University) ;
  • Koo, Sang-Mo (Department of Electronic Materials Engineering, Kwangwoon University) ;
  • Park, Chulhwan (Department of Chemical Engineering, Kwangwoon University) ;
  • Shin, Weon Ho (Department of Electronic Materials Engineering, Kwangwoon University) ;
  • Lee, Dong-Won (Department of Electronic Materials Engineering, Kwangwoon University) ;
  • Oh, Jong-Min (Department of Electronic Materials Engineering, Kwangwoon University)
  • 투고 : 2021.05.14
  • 심사 : 2021.06.07
  • 발행 : 2021.09.01

초록

Controlling ambient humid condition through high performance humidity sensors has become important for various fields, including industrial process, food storage, and the preservation of historic remains. Although aerosol deposited humidity sensors using ceramic BaTiO3 (BT) material have been widely studied because of their longtime stability, there remain critical disadvantages, such as low sensitivity, low linearity, and slow response/recovery time in case of the sensors fabricated at room temperature. To achieve superior humidity sensing properties even at room temperature condition, BT-Cu composite films utilizing aerosol deposition (AD) process have been proposed based on the percolation theory. The BT-Cu composite films showed gradually improved sensing properties until the Cu concentration reached 15 wt% in the composite film. However, the excessive Cu (above 30 wt%) containing BT-Cu composite films showed a rapid decrease of the sensing properties. The results of observed surface morphology of the AD fabricated composite films, to figure out the metal filler effect, showed correlation between surface topography as well as size and the amount of open pores according to the metal filler content. Overall, it is very important not only dielectric constant of the humidity sensing films but also microstructures, because they affect either the variation range of capacitance by ambient humidity or adsorption/desorption of ambient humidity onto/from the humidity sensing films.

키워드

과제정보

본 연구는 산업통상자원부 재원으로 한국산업기술진흥원의 지원(P0012451, 산업혁신인재성장지원사업)과 한국연구재단의 지원(과제번호: 2018R1D1A1B07045295, 2020R1F1A1073491, 2021R1F1A1057620)을 받아 수행한 연구 과제입니다.

참고문헌

  1. H. Khayyam, B. Javadi, M. Jalili, and R. N. Jazar, Nonlinear Approaches in Engineering Applications, p. 39-68 (2020). [DOI: https://doi.org/10.1007/978-3-030-18963-1_2]
  2. Y. Ma, Z. Wang, H. Yang, and L. Yang, IEEE/CAA J. Autom. Sin., 7, 315 (2020). [DOI: https://doi.org/10.1109/JAS.2020.1003021]
  3. A. D. Boursianis, M. S. Papadopoulou, P. Diamantoulakis, A Liopa-Tsakalidi, P. Barouchas, G. Salahas, G. Karagiannidis, S. Wan, and S. K. Goudos, Internet Things, 100187, 2542 (2020). [DOI: https://doi.org/10.1016/j.iot.2020.100187]
  4. T. Joyashiki and C. Wada, Sensors, 20, 942 (2020). [DOI: https://doi.org/10.3390/s20030942]
  5. J. Shin, B. Jeong, J. Kim, V. B. Nam, Y. Yoon, J. Jung, S. Hong, H. Lee, H. Eom, J. Yeo, J. Choi, D. Lee, and S. H. Ko, Adv. Mater., 32, 1905527 (2020). [DOI: https://doi.org/10.1002/adma.201905527]
  6. W. Yang, J. Chen, X. Wen, Q. Jing, J. Yang, Y. Su, G. Zhu, W. Wu, and Z. L. Wang, ACS Appl. Mater. Interfaces, 6, 7479 (2014). [DOI: https://doi.org/10.1021/am500864t]
  7. K. Morimoto, A. Ardelean, M. L. Wu, A. C. Ulku, I. M. Antolovic, C. Bruschini, and E. Charbon, Optica, 7, 346 (2020). [DOI: https://doi.org/10.1364/OPTICA.386574]
  8. Z. Duan, Q. Zhao, S. Wang, Q. Huang, Z. Yuan, Y. Zhang, Y. Jiang, and H. Tai, Sens. Actuators, B, 317, 128204 (2020). [DOI: https://doi.org/10.1016/j.snb.2020.128204]
  9. K. S. Chou, T. K. Lee, and F. J. Liu, Sens. Actuators, B, 56, 106 (1999). [DOI: https://doi.org/10.1016/S0925-4005(99)00187-2]
  10. J. G. Liang, C. Wang, Z. Yao, M. Q. Liu, H. K. Kim, J. M. Oh, and N. Y. Kim, ACS Appl. Mater. Interfaces, 10, 851 (2018). [DOI: https://doi.org/10.1021/acsami.7b14082]
  11. H. N. Abid, U. M. Nayef, and F.A.H. Mutlak, Optik, 178, 379 (2019). [DOI: https://doi.org/10.1016/j.ijleo.2018.09.167]
  12. D. Hernandez-Rivera, G. Rodriguez-Roldan, R. Mora-Martinez, and E. Suaste-Gomez, Sensors, 17, 1009 (2017). [DOI: https://doi.org/10.3390/s17051009]
  13. J. G. Liang, E. S. Kim, C. Wang, M. Y. Cho, J. M. Oh, and N. Y. Km, Sens. Actuators, B, 265, 632 (2018). [DOI: https://doig.org/10.1016/j.snb.2018.03.093]
  14. E. S. Kim, J. G. Liang, C. Wang, M. Y. Cho, J. M. Oh, and N. Y. Kim, Sci. Rep., 9, 680 (2019). [DOI: https://doi.org/10.1038/s41598-018-37416-7]
  15. I. S. Kim, P. J. Ko, M. Y. Cho, H. K. Kim, D. W. Lee, S. M. Koo, D. Lee, C. Park, and J. M. Oh, Ceram. Int., 45, 20634 (2019). [DOI: https://doi.org/10.1016/j.ceramint.2019.07.046]
  16. I. S. Kim, M. Y. Cho, Y. Jeong, Y. C. Shin, D. W. Lee, C. Park, S. M. Koo, W. H. Shin, W. J. Yang, Y. Park, H. Sohn, and J. M. Oh, J. Am. Ceram. Soc., 10, 1716 (2021). [DOI: https://doi.org/10.1111/jace.17609]
  17. M. Y. Cho, S. Kim, I. S. Kim, E. S. Kim, Z. J. Wang, N. Y. Kim, S. W. Kim, and J. M. Oh, Adv. Funct. Mater., 30, 1907449 (2020). [DOI: https://doi.org/10.1002/adfm.201907449]
  18. X. Ning, P. Y. Ping, and W. Zhuo, J. Am. Ceram. Soc., 95, 999 (2012). [DOI: https://doi.org/10.1111/j.1551-2916.2011.04895.x]
  19. C. Pecharroman, F. Esteban-Betegon, J. F. Bartolome, S. Lopez-Esteban, and J. S. Moya, Adv. Mater., 13, 1541 (2001). [DOI: https://doi.org/10.1002/1521-4095(200110)13:20<1541::AIDADMA1541>3.0.CO;2-X]
  20. F. He, S. Lau, H. L. Chan, and J. Fan, Adv. Mater., 21, 710 (2009). [DOI: https://doi.org/10.1002/adma.200801758]
  21. Y. H. Kim, M. Osada, H. K. Kim, and S. M. Nam, Jpn. J. Appl. Phys., 51, 09LC07 (2012). [DOI: https://doi.org/10.1143/JJAP.51.09LC07]
  22. M. Y. Cho, D. W. Lee, W. J. Kim, Y. N. Kim, S. M. Koo, D. Lee, K. S. Moon, and J. M. Oh, Ceram. Int., 44, 18736 (2018). [DOI: https://doi.org/10.1016/j.ceramint.2018.07.103]