대한화학회지 (Journal of the Korean Chemical Society)

  • 제65권4호
  • /
  • Pages.254-259
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  • 2021
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  • 1017-2548(pISSN)
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  • 2234-8530(eISSN)
대한화학회 (Korean Chemical Society)
권호 표지
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Simultaneous Spectrometric Determination of Caffeic Acid, Gallic Acid, and Quercetin in Some Aromatic Herbs, Using Chemometric Tools

  • Kachbi, Abdelmalek (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia) ;
  • Abdelfettah-Kara, Dalila (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia) ;
  • Benamor, Mohamed (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia) ;
  • Senhadji-Kebiche, Ounissa (Laboratoire des Procedes Membranaires et des Techniques de Separation et de Recuperation, Faculty of Technology, Universite de Bejaia)
  • 투고 : 2020.10.14
  • 심사 : 2021.05.21
  • 발행 : 2021.08.20
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초록

The purpose of this work is the development of a method for an effective, less expensive, rapid, and simultaneous determination of three phenolic compounds (caffeic acid, gallic acid, and quercetin) widely present in food resources and known for their antioxidant powers. The method relies on partial least squares (PLS) calibration of UV-visible spectroscopic data. This model was applied to simultaneously determine, the concentrations of caffeic acid (CA), gallic acid (GA), and quercetin (Q) in six herb infusion extracts: basil, chive, laurel, mint, parsley, and thyme. A wavelength range (250-400) nm, and an experimental calibration matrix with 21 samples of ternary mixtures composed of CA (6.0-21.0 mg/L), GA (10.0-35.2 mg/L), and Q (6.4-17.5 mg/L) were chosen. Spectroscopic data were mean-centered before calibration. Two latent variables were determined using the contiguous block cross-validation procedure after calculating the root mean square error cross-validation RMSECV. Other statistic parameters: RMSEP, R2, and Recovery (%) were used to determine the predictive ability of the model. The results obtained demonstrated that UV-visible spectrometry and PLS regression were successfully applied to simultaneously quantify the three phenolic compounds in synthetic ternary mixtures. Moreover, the concentrations of CA, GA and Q in herb infusion extracts were easily predicted and found to be 3.918-18.055, 9.014-23.825, and 9.040-13.350 mg/g of dry sample, respectively.

키워드

과제정보

The authors are grateful to the Algerian MESRS for the financial support in the CNEPRU program no. A16N01UN060120140005. Publication cost of this paper was supported by the Korean Chemical Society.

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