Computers and Concrete

  • 제27권6호
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  • Pages.597-606
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  • 2021
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  • 1598-8198(pISSN)
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  • 1598-818X(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Experimental investigation of mechanical properties of geopolymer mortars produced with metakaolin, red mud and glass powder

  • Awad, Ashraf (Department of Civil Engineering, Faculty of Engineering, Eastern Mediterranean University) ;
  • Akcaoglu, Tulin (Department of Civil Engineering, Faculty of Engineering, Eastern Mediterranean University) ;
  • Cubukcuoglu, Beste (Department of Civil Engineering, Faculty of Civil and Environmental Engineering, Near East University) ;
  • Canpolat, Orhan (Civil Engineering Department, Yildiz Technical University, Davutpasa Campus)
  • 투고 : 2010.12.25
  • 심사 : 2021.05.17
  • 발행 : 2021.06.25
⟨ 이전 논문 다음 논문 ⟩

초록

Three different materials GP, RM and GGBFS in addition to MK were used to produce geopolymer mortars which were activated by using NaOH and Na2SiO3. In addition to these materials, GF was also introduced into the mixtures. The performance of the produced geopolymers was investigated by means of compressive strength, flexural strength, split tensile strength, chemical analysis and abrasion resistance measurements and microstructure investigation by means of SEM. In geopolymer mortar production MK is found more compatible with RM than GP in terms of strength development and abrasion resistance. Moreover, positive effect of GF (6 mm and 12 mm) addition was found to increase with the presence of GP and also with increased length of the fiber length.

키워드

과제정보

The research described in this paper was encouraged by the BAP Project "Determination of mechanical and durability properties of sustainable geopolymer composites with waste concrete aggregate additives" conducted by Yildiz Technical University in Turkey under the code: FBA-2019-3558.

참고문헌

  1. Al-Majidi, M.H., Lampropoulos, A., Cundy, A. and Meikle, S. (2016), "Development of geopolymer mortar under ambient temperature for in situ applications", Constr. Build. Mater., 120, 198-211. https://doi.org/10.1016/j.conbuildmat.2016.05.085.
  2. Al-Mashhadani, M.M., Canpolat, O., Aygormez, Y., Uysal, M. and Erdem, S. (2018), "Mechanical and microstructural characterization of fiber reinforced fly ash based geopolymer composites", Constr. Build. Mater., 167, 505-513. https://doi.org/10.1016/j.conbuildmat.2018.02.061.
  3. Al Bakri, M.M., Mohammed, H., Kamarudin, H., Niza, I.K. and Zarina, Y. (2011), "Review on fly ash-based geopolymer concrete without Portland Cement", J. Eng. Technol. Res., 3. 1-4. https://doi.org/10.5897/JETR.9000070.
  4. Alomayri, T., Shaikh, F.U.A. and Low, I.M. (2014), "Synthesis and mechanical properties of cotton fabric reinforced geopolymer composites", Compos. Part B: Eng., 60, 36-42. https://doi.org/10.1016/j.compositesb.2013.12.036.
  5. Ascensao, G., Seabra, M.P., Aguiar, J.B. and Labrincha, J.A. (2017), "Red mud-based geopolymers with tailored alkali diffusion properties and pH buffering ability", J. Clean. Prod., 148, 23-30. https://doi.org/10.1016/j.jclepro.2017.01.150.
  6. Bhalchandra, S.A. and Bhosle, A.Y. (2013), "Properties of glass fibre reinforced geopolymer concrete", Int. J. Modern Eng. Res. (IJMER), 3(4), 2007-2010.
  7. Burciaga-Diaz, O., Escalante-Garcia, J.I. and Magallanes-Rivera, R.X. (2015), "Compressive strength and microstructural evolution of metakaolin geopolymers exposed at high temperature", ALCOMPAT J., 5. 54-72.
  8. Celik, A., Yilmaz, K., Canpolat, O., Al-Mashhadani, M.M., Aygormez, Y. and Uysal, M. (2018), "High-temperature behavior and mechanical characteristics of boron waste additive metakaolin based geopolymer composites reinforced with synthetic fibers", Constr. Build. Mater., 187, 1190-1203, https://doi.org/10.1016/j.conbuildmat.2018.08.062.
  9. Chen, R., Ahmari, S. and Zhang, L. (2014), "Utilization of sweet sorghum fiber to reinforce fly ash-based geopolymer", J. Mater. Sci., 49(6), 2548-2558. https://doi.org/10.1007/s10853-013-7950-0.
  10. Davidovits, J. (1994), "Geopolymers: Man-made rock geosynthesis and the resulting development of very early high strength cement", J. Mater. Edu., 16, 91-137.
  11. Detphan, S. and Chindaprasirt, P. (2009), "Preparation of fly ash and rice husk ash geopolymer", Int. J. Min., Metal. Mater., 16(6), 720-726. https://doi.org/10.1016/S1674-4799(10)60019-2.
  12. Duxson, P. (2006), "The structure and thermal evolution of metakaolin geopolymers", PhD Thesis, Department of Chemical & Biomolecular Engineering, The University of Melbourne.
  13. Duxson, P., Fernandez-Jimenez, A., Provis, J.L., Lukey, G.C., Palomo, A. and van Deventer, J.S. (2007), "Geopolymer technology: The current state of the art", J. Mater. Sci., 42, 2917-2933. https://doi.org/10.1007/s10853-006-0637-z.
  14. Garcia-Lodeiro, I., Palomo, A.Y. and Fernandez-Jimenez, A. (2007), "Alkali-aggregate reaction in activated sly ash systems", Cement Concrete Res., 37, 175-183. https://doi.org/10.1016/j.cemconres.2006.11.002.
  15. Guo, X., Shi, H. and Dick, W.A. (2010), "Compressive strength and microstructural characteristics of class C fly ash geopolymer", Cement Concrete Compos., 32, 142-147. https://doi.org/10.1016/j.cemconcomp.2009.11.003.
  16. Hajjaji, W., Andrejkovicova, S., Zanelli, C., Alshaaer, M., Dondi, M., Labrincha, J.A. and Rocha, F. (2013), "Composition and technological properties of geopolymers based on metakaolin and red mud", Mater. Des., 52, 648-654. https://doi.org/10.1016/j.matdes.2013.05.058.
  17. He, J., Jie, Y., Zhang, J., Yu, Y. and Zhang, G. (2013), "Synthesis and characterization of red mud and rice husk ash-based geopolymer composites", Cement Concrete Compos., 37, 108-118. https://doi.org/10.1016/j.cemconcomp.2012.11.010.
  18. He, J., Zhang, J., Yu, Y. and Zhang, G. (2012), "The strength and microstructure of two geopolymers derived from metakaolin and red mud-fly ash admixture: A comparative study", Constr. Build. Mater., 30, 80-91. https://doi.org/10.1016/j.conbuildmat.2011.12.011.
  19. Ibrahim, M., Johari, M.A.M., Rahman, M.K. and Maslehuddin, M. (2017), "Effect of alkaline activators and binder content on the properties of natural pozzolan-based alkali activated concrete", Constr. Build. Mater., 147, 648-660. https://doi.org/10.1016/j.conbuildmat.2017.04.163.
  20. Jaya, N.A., Liew, Y.M., Heah, C.Y. and Abdullah, M.M.A.B. (2018), "Effect of solid-to-liquid ratios on metakaolin geopolymers", AIP Conf. Proc., 045(1), 020099. https://doi.org/10.1063/1.5080912.
  21. Jindal, B.B. (2018), "Feasibility study of ambient cured geopolymer concrete-A review", Adv. Concrete Constr., 6(4), 387. https://doi.org/10.12989/acc.2018.6.4.387.
  22. Juenger, M.C.G., Winnefeld, F., Provis, J.L. and Ideker, J.H. (2011), "Advances in alternative cementitious binders", Cement Concrete Res., 41, 1232-1243. https://doi.org/10.1016/j.cemconres.2010.11.012.
  23. Kim, Y., Kim, K. and Jeong, G.Y. (2017), "Study of detailed geochemistry of hazardous elements in weathered coal ashes", Fuel, 193, 343-350. https://doi.org/10.1016/j.fuel.2016.12.080.
  24. Kong, D.L. and Sanjayan, J.G. (2008), "Damage behavior of geopolymer composites exposed to elevated temperatures", Cement Concrete Compos., 30, 986-991. https://doi.org/10.1016/j.cemconcomp.2008.08.001.
  25. Kumar, A. and Kumar, S. (2013), "Development of paving blocks from synergistic use of red mud and fly ash using geopolymerization", Constr. Build. Mater., 38, 865-871. https://doi.org/10.1016/j.conbuildmat.2012.09.013.
  26. Lee, W.K.W. and Van Deventer, J.J. (2002), "Effects of anions on the formation of aluminosilicate gel in geopolymers", Indus. Eng. Chem. Res., 41(18), 4550-4558. https://doi.org/10.1021/ie0109410.
  27. Leong, H.Y., Ong, D.E.L., Sanjayan, J.G. and Nazari, A. (2016), "The effect of different Na2O and K2O ratios of alkali activator on compressive strength of fly ash based-geopolymer", Constr. Build. Mater., 106, 500-511. https://doi.org/10.1016/j.conbuildmat.2015.12.141.
  28. Lin, T., Jia, D., Wang, M., He, P. and Liang, D. (2009), "Effects of fibre content on mechanical properties and fracture behaviour of short carbon fibre reinforced geopolymer matrix composites", Bull. Mater. Sci., 32(1), 77-81. https://doi.org/10.1007/s12034-009-0011-2.
  29. Midhun, M.S., Rao, T.G. and Srikrishna, T.C. (2018), "Mechanical and fracture properties of glass fiber reinforced geopolymer concrete", Adv. Concrete Constr., 6(1), 29-45. https://doi.org/10.12989/acc.2018.6.1.029.
  30. Nematollahi, B., Sanjayan, J., Chai, J.X.H. and Lu, T.M. (2014), "Properties of fresh and hardened glass fiber reinforced fly ash based geopolymer concrete", Key Eng. Mater., 594, 629-633. https://doi.org/10.4028/www.scientific.net/KEM.594-595.629.
  31. Rowles, M. and O'connor, B. (2003), "Chemical optimization of the compressive strength of aluminosilicate Geopolymers synthesis by sodium silicate activation of metakaolinite", J. Mater. Chem., 13, 1161-1165. https://doi.org/10.1039/b212629j.
  32. Saridemir, M. and Celikten, S. (2017), "The strength properties of alkali-activated silica fume mortars", Comput. Concrete, 19, 153-159. https://doi.org/10.12989/cac.2017.19.2.153.
  33. Sathanandam, T., Awoyera, P.O., Vijayan, V. and Sathishkumar, K. (2017), "Low carbon building: Experimental insight on the use of fly ash and glass fibre for making geopolymer concrete", Sustain. Environ. Res., 27(3), 146-153. https://doi.org/10.1016/j.serj.2017.03.005.
  34. TS 2824 EN 1338 (2005), Concrete Paving Blocks-Requirements and Test Mmethods, TSI, Ankara.
  35. Uysal, M., Al-mashhadani, M.M., Aygormez, Y. and Canpolat, O. (2018), "Effect of using colemanite waste and silica fume as partial replacement on the performance of metakaolin-based geopolymer mortars", Constr. Build. Mater., 176, 271-282. https://doi.org/10.1016/j.conbuildmat.2018.05.034.
  36. Vafaei, M. and Allahverdi, A. (2016), "High strength geopolymer binder based on waste-glass powder", Adv. Powd. Technol., 28(1), 215-222. https://doi.org/10.1016/j.apt.2016.09.034.
  37. Xiao, R., Polaczyk, P., Zhang, M., Jiang, X., Zhang, Y., Huang, B. and Hu, W. (2020), "Evaluation of glass powder-based geopolymer stabilized road bases containing recycled waste glass aggregate", Tran. Res. Record: J. Tran. Res. Board, 2674(1), 22-32. https://doi.org/10.1177/0361198119898695.
  38. Xie, Z. and Xi, Y (2001), "Hardening mechanism of an alkalineactivated class F fly ash", Cement Concrete Res., 31, 1245-1249. https://doi.org/10.1016/S0008-8846(01)00571-3.
  39. Xu, H. and Van Deventer, J.S. (2002), "Geopolymerisation of multiple minerals", Min. Eng., 15, 1131-1139. https://doi.org/10.1016/S0892-6875(02)00255-8.
  40. Zailani, W.W.A., Abdullah, M.M.A., Arshad, M.F., Burduhos-Nergis, D.D. and Tahir, M.F.M. (2020), "Effect of iron oxide (Fe2O3) on the properties of fly ash based geopolymer", IOP Conf. Ser.: Mater. Sci. Eng., 877, 012017. https://doi.org/10.1088/1757-899X/877/1/012017.
  41. Zhang, P., Zheng, Y., Wang, K. and Zhang, J. (2018), "A review on properties of fresh and hardened geopolymer mortar", Compos. Part B Eng., 152, 79-95. https://doi.org/10.1016/j.compositesb.2018.06.031.