Membrane and Water Treatment

  • 제12권3호
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  • Pages.95-106
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  • 2021
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Enhanced transport of Lignosulfonate by integrating adsorption sweep in a liquid membrane module

  • Kumar, Vikas (Department of Chemical Engineering, National Institute of Technology Rourkela) ;
  • George, Prince (Department of Chemical Engineering, National Institute of Technology Rourkela) ;
  • Singh, Raghubansh K. (Department of Chemical Engineering, National Institute of Technology Rourkela) ;
  • Chowdhury, Pradip (Department of Chemical Engineering, National Institute of Technology Rourkela)
  • 투고 : 2019.01.11
  • 심사 : 2021.04.15
  • 발행 : 2021.05.25
⟨ 이전 논문 다음 논문 ⟩

초록

Carrier mediated liquid membrane (LM) processes are unique in a way where proper selection of a carrier can achieve complete separation of the targeted species. This aspect is particularly important in multi-component systems. However, resistance to transport across the membrane phase and low concentration gradient across the LM-strip interphase restricts the overall transport performance. This article proposes an improvised method in a LM transport by integrating adsorption sweep. The investigated species was Lignosulfonate (LS) and the preferred adsorbent was MIL-101 (Cr) metal organic framework (MOF). Pure adsorption study showed high affinity of MIL-101 (Cr) for LS with ca. 94% removal from its model solution. Langmuir isotherm best fits the equilibrium data and pseudo second order model best explains the kinetics. Adsorption sweep experiments showed an overall improvement in extraction percentage of LS from 92% (regular bulk liquid membrane study) to ca. 97%. The recovery percentage of LS was decreased from ca. 75% (regular bulk liquid membrane study) to <10% because of adsorption of LS from bulk stripping medium, leading to an increase in concentration gradient across LM-strip interphase. Favorable chemistry of the stripping medium was found to be important for maintaining suitable pH conditions for the success of adsorption sweep process. During LS transport this aspect was clearly observed when the pH of the stripping medium got reduced, owing to the formation of H2SO4, the resulting adsorption sweep was more pronounced.

키워드

과제정보

We gratefully acknowledge the financial support provided by SERB (DST, Govt. of India) in developing research facilities.

참고문헌

  1. Chen, C., Zhang, M., Guan, Q. and Li, W. (2012), "Kinetic and thermodynamic studies on the adsorption of xylenol orange ontoMIL-101(Cr)", Chem. Eng. J., 183, 60-67. https://doi.org/10.1016/j.cej.2011.12.021.
  2. Ehrenmann, J., Henninger, S.K. and Janiak, C. (2011), "Water adsorption characteristics of MIL-101 for heat-transformation applications of MOFs", Eur. J. Inorg. Chem., 471-474. https://doi.org/10.1002/ejic.201001156.
  3. Elsayed, E., Wang, H., Anderson, P.A., Al-Dadah, R., Mahmoud, S., Navarro, H., Ding, Y. and Bowen, J. (2017), "Development of MIL-101(Cr)/GrO composites for adsorption heat pump applications", Micropor. Mesopor. Mat., 244, 180-191. https://doi.org/10.1016/j.micromeso.2017.02.020.
  4. Feldman, D., Lacasse, M. and Beznaczuk, L.M. (1986), "Lignin-polymer systems and some applications", Prog. Polym. Sci., 12(4), 271-299. https://doi.org/10.1016/0079-6700(86)90002-X.
  5. Ferey, G., Draznieks, C.M., Serre, C., Millange, F., Dutour, J., Surble, S. and Margiolaki, I. (2005), "A chromium terephthalate-based solid with unusually large pore volumes and surface area", Science, 309(5743), 2040-2042. https://doi.org10.1126/science.1116275.
  6. Freundlich, H. (1926), Colloid and Capillary Chemistry, Methuen, London, U.K., 114-122.
  7. Grigg, R.B. and Bai, B. (2004), "Calcium lignosulfonate adsorption and desorption on Berea sandstone", J. Colloid. Interf. Sci., 279(1), 36-45. https://doi.org/10.1016/j.jcis.2004.06.035.
  8. Konowal, E., Modrzejewska, S.A. and Milczarek, G. (2015), "Synthesis and multifunctional properties of lignosulfonate-stabilized gold nanoparticles", Mater. Lett. 159, 451-454. https://doi.org/10.1016/j.matlet.2015.07.052.
  9. Kumar, V., Karnjkar, Y., Singh, R.K. and Chowdhury, P. (2018a), "Effective removal of Congo red using sunflower oil/tri-n-octylamine system in a bulk liquid membrane process and studying the transport kinetics", Chem. Pap., 72(8), 2055-2069. https://doi.org/10.1007/s11696-018-0438-2.
  10. Kumar, V., Singh, R.K. and Chowdhury, P. (2018b), "Efficient extraction and recovery of Lignosulfonate using sunflower oil as green solvent in liquid membrane transport: Equilibrium and kinetic study", J. Ind. Eng. Chem. 67, 109-122. https://doi.org/10.1016/j.jiec.2018.06.021.
  11. Langmuir, I. (1918), "The adsorption of gases on plane surfaces of glass, mica and platinum", J. Am. Chem. Soc., 40(9), 1361-1403. https://doi.org/10.1021/ja02242a004.
  12. Li, H.Q., Huang, G.H., An, C.J. and Zhang, W.X. (2012a), "Kinetic and equilibrium studies on the adsorption of calcium lignosulfonate from aqueous solution by coal fly ash", Chem. Eng. J., 200, 275-282. https://doi.org/10.1016/j.cej.2012.06.051.
  13. Li, Z., Pang, Y., Ge, Y. and Qiu, X. (2012b), "Adsorption of different molecular weight lignosulfonates on dimethomorphpowder in an aqueous system", J. Ind. Eng. Chem. 18(1), 532-537. https://doi.org/10.1016/j.jiec.2011.11.069.
  14. Luo, X.P., Fu, S.Y., Du, Y.M., Guo, J.Z. and Li, B. (2017), "Adsorption of methylene blue and malachite green from aqueous solution by sulfonic acid group modified MIL-101", Micropor. Mesopor. Mat., 237, 268-274. https://doi.org/10.1016/j.micromeso.2016.09.032.
  15. Matsushita, Y. and Yasuda, S. (2005), "Preparation and evaluation of lignosulfonates as a dispersant for gypsum paste from acid hydrolysis lignin", Bioresour. Technol., 96(4), 465-470. https://doi.org/10.1016/j.biortech.2004.05.023.
  16. Milczarek, G. (2009), "Lignosulfonate-modified electrodes: Electrochemical properties and electrocatalysis of NADH oxidation", Langmuir, 25(17), 10345-10353. https://doi.org/10.1021/la9008575.
  17. Modrzejewska, S.A., Konowal, E., Klapiszewski, L., Nowaczyk, G., Jurga, S., Jesionowski, T. and Milczarek, G. (2017), "Lignosulfonate-stabilized selenium nanoparticles and their deposition on spherical silica", Int. J. Biol. Macromol., 103, 403-408. https://doi.org/10.1016/j.ijbiomac.2017.05.083.
  18. Mondal, S.K. and Saha, P. (2018), "Separation of hexavalent chromium from industrial effluent through liquid membrane using environmentally benign solvent: A study of experimental optimization through response surface methodology", Chem. Eng. Res. Des. 132, 564-583. https://doi.org/10.1016/j.cherd.2018.02.001.
  19. Muthuraman, G. and Jahfar Ali, P. (2012). "Recovery of Golden yellow and Cibacron LSG dyes from aqueous solution by bulk liquid membrane technique", Membr. Water Treat., 3(4), 243-252. http://doi.org/10.12989/mwt.2012.3.4.243.
  20. Samokhvalov, A. (2015), "Adsorption on mesoporous metal-organic frameworks in solution: Aromatic and heterocyclic compounds", Chem. A Eur. J., 21(47), 16726-16742. https://doi.org/10.1002/chem.201502317.
  21. Shen, T., Luo, J., Zhang, S. and Luo, X. (2015), "Hierarchically mesostructured MIL-101 metal-organic frameworks with different mineralizing agents for adsorptive removal of methyl orange and methylene blue from aqueous solution", J. Environ. Chem. Eng., 3(2), 1372-1383. https://doi.org/10.1016/j.jece.2014.12.006.
  22. Sumerskii, I., Korntner, P., Zinovyev, G., Rosenau, T. and Potthast, A. (2015), "Fast track for quantitative isolation of lignosulfonates from spent sulfite liquors", RSC Adv., 5(112), 92732-92742. https://doi.org/10.1039/C5RA14080C.
  23. Wang, M., Leitch, M. and Xu, C. (2009), "Synthesis of phenol-formaldehyde resol resins using organosolv pine lignins", Eur. Polym. J., 45(12), 3380-3388. https://doi.org/10.1016/j.eurpolymj.2009.10.003.
  24. Wang, T., Zhao, P., Lu, N., Chen, H., Zhang, C. and Hou, X. (2016), "Facile fabrication of Fe3O4/MIL-101(Cr) for effective removal of acid red 1 and orange G from aqueous solution", Chem. Eng. J., 295, 403-413. https://doi.org/10.1016/j.cej.2016.03.016.
  25. Zulfikar, M.A., Mariske, E.D. and Djajanti, S.D. (2012), "Adsorption of lignosulfonate compounds using powdered eggshell", Songklanakarin J. Sci. Technol., 34(3), 309-316.