Advances in nano research

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Silver (I)- Schiff-base complex intercalated layered double hydroxide with antimicrobial activity

  • Barnabas, Mary Jenisha (Department of Polymer Science and Engineering, School of Chemical Engineering, Pusan National University) ;
  • Parambadath, Surendran (Department of Polymer Science and Engineering, School of Chemical Engineering, Pusan National University) ;
  • Nagappan, Saravanan (Department of Polymer Science and Engineering, School of Chemical Engineering, Pusan National University) ;
  • Chung, Ildoo (Department of Polymer Science and Engineering, School of Chemical Engineering, Pusan National University) ;
  • Ha, Chang-Sik (Department of Polymer Science and Engineering, School of Chemical Engineering, Pusan National University)
  • Received : 2018.12.26
  • Accepted : 2021.01.02
  • Published : 2021.04.25
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Abstract

In this work, silver nitrate complexes of sulfanilamide-5-methyl-2-thiophene carboxaldehyde (SMTCA) ligand intercalated Zn/Al-layered double hydroxide [Ag-SMTCA-LDH] were synthesized for the potential application as an antimicrobial system. The SMTCA ligand was synthesized by reacting sulfanilamide and 5-methyl-2-thiophene carboxaldehyde in methanol and further complexation with silver nitrate metal ions [Ag-SMTCA]. The structural analyses of synthesized compounds confirmed an intercalation of Ag-SMTCA into Zn/Al-NO3-LDH by flake/restacking method. SMTCA, Ag-SMTCA and Ag-SMTCA-LDH were characterized by 1H nuclear magnetic resonance (1H NMR) spectroscopy, Fourier-transform infrared (FTIR), ultraviolet-visible (UV-Vis) spectrophotometer, scanning electron microscopy (SEM) and transmission electron microscopy (TEM), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). It was found that Ag-SMTCA-LDH exhibited good antimicrobial activity against both gram-positive (Bacillus subtilis, [B. subtilis], Staphylococcus aures, [S. aureus]) and gram-negative (Escherichia coli, [E. coli], Pseudomonas aeruginosa [P. aeroginosa]) bacteria as well as excellent antioxidant activity.

Keywords

Acknowledgement

The work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Ministry of Science and ICT, Korea {NRF-2017R1A2B3012961) and Brain Korea 21 Plus Program (4199990414196)).

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