한국섬유공학회지 (Textile Science and Engineering)

  • 제58권2호
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  • Pages.106-112
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  • 2021
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  • 1225-1089(pISSN)
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  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
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탄소나노튜브 필름 Li Host의 Lithiophilicity가 리튬메탈배터리의 성능에 미치는 영향 연구

Effect of the Lithiophilicity of the Li Host of a Carbon Nanotube Film on the Performance of Li Metal Battery

  • 김라영 (숭실대학교 공과대학 유기신소재파이버공학과) ;
  • 김교식 (숭실대학교 공과대학 유기신소재파이버공학과) ;
  • 신명규 (숭실대학교 공과대학 유기신소재파이버공학과) ;
  • 김혜주 (숭실대학교 공과대학 유기신소재파이버공학과) ;
  • 송현준 (숭실대학교 공과대학 유기신소재파이버공학과) ;
  • 정영진 (숭실대학교 공과대학 유기신소재파이버공학과)
  • Kim, Rayoung (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Kim, Gyosik (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Shin, Myunggyu (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Kim, Haejoo (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Song, Hyeonjun (Department of Organic Materials and Fiber Engineering, Soongsil University) ;
  • Jeong, Youngjin (Department of Organic Materials and Fiber Engineering, Soongsil University)
  • 투고 : 2021.04.02
  • 심사 : 2021.04.15
  • 발행 : 2021.04.30
⟨ 이전 논문 다음 논문 ⟩

초록

Lithium (Li) has gained attention as an anode material because of its high specific capacity (3860 mAh g-1) and high energy density. However, its commercialization is limited owing to the dendrite growth on the surface of the electrode, which causes several drawbacks, such as low cycling stability, and safety issues, such as short circuits due to the penetration of the separator. Li hosts with various structures have been studied to address these problems. A 3D-scaffold structured host effectively suppresses the Li dendrite growth and improves the electrode performance. Carbon nanotube (CNT) is a promising candidate material for a Li host owing to its high surface area and excellent electrical conductivity. However, the lithiophobicity of CNT makes it difficult to utilize CNT as a Li host. In this study, we tried to improve the lithiophilicity of CNT film by direct pre-lithiation method and studied the effect of lithiophilicity on the performance of Li metal battery. Li could be uniformly plated inside the lithiophilic CNT film in contrast to lithiophobic CNT film, where it was plated unevenly on the surface. This Li plating behavior was reflected in the performance of the full cell, in which LiFePO4 (LFP) was used as a cathode. The full cell (LFP ∥ lithiophilic CNT film) exhibited remarkable cyclability owing to uniform Li plating inside lithiophilic CNT film.

키워드

과제정보

본 연구는 2020년도 정부(과학기술정보통신부)의 재원으로 한국연구재단의 지원을 받아 수행된 연구임(NO. NRF-2020R1A2C2006720).

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