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Biogas Treatment from Wastewater Treatment Plant by Micro-bubble Generation System with Neutralization Chemicals

중화약품과 마이크로버블 장치를 이용한 폐수처리장 바이오가스 처리

  • Jung, Jae-Ouk (Department of Radiological Science, Catholic University of Pusan) ;
  • Jung, Yong-Jun (Department of Environmental Engineering, Catholic University of Pusan)
  • 정재억 (부산가톨릭대학교 방사선학과) ;
  • 정용준 (부산가톨릭대학교 환경공학과)
  • Received : 2021.01.28
  • Accepted : 2021.02.09
  • Published : 2021.02.28

Abstract

DIWS system was introduced to remove hydrogen sulfide from the biogas of wastewater treatment plant. In the case of using water into the DIWS system more than 5,000mg/L of hydrogen sulfide, 25% of H2S removal efficiency was shown and required such further treatment process as incineration which was obtained more than 98%. When the inflow of hydrogen sulfide was 5,000mg/L, CH4 and CO2 were effectively discharged and the reduction was 8.7% and 28.6%, respectively. When such neutralization chemicals as Na2CO3 and NaOH were introduced into the DIWS system, H2S was removed more than 97.2% keeping pH in the range of 11.2 to 11.5.

폐수처리장에서 발생하는 바이오가스 중의 황화수소를 처리하기 위하여 습식스크러빙 장치가 적용되었다. 유입 H2S의 농도가 5,000mg/L이상에서 DIWS 장치에 물만을 사용할 경우 25%의 제거율을 나타내어 후속으로 소각처리 공정이 도입되어야만 98% 이상의 제거율을 나타냈다. 유입 H2S의 농도가 5,000mg/L일 때 CH4과 CO2는 각각 8.7%와 28.6% 감소하여 배출되었다. DIWS 장치에 중화약품으로 Na2CO3와 NaOH를 사용하였을 때 pH가 11.2~11.5를 유지하면서 H2S는 97.2% 제거되었다.

Keywords

References

  1. An, HS, Park, SS, Kim, KH, Kim, YH (2007). A study on optimization of spray type flue gas desulfurization (FGD) system, J. Korean Ind. Chem., 18(1), pp.29-35.
  2. Kim, GJ, Kim, LH (2016). Analysis of cause of engine failure during power generation using biogas in sewage treatment plant, J. of Energy Engineering, 25(4), pp.13-29 [Korea literature]. [https://doi.org/10.5855/ENERGY.2016.25.4.013]
  3. Kim, JG, Lee, JY, Park, BH, Choi, JS(2015). The simultaneous removal of NOx using wet scrubber. J. of Korean Oil Chemists' Soc., 32(2), pp.296-301 [Korea literature]. [http://dx.doi.org/10.12925/jkocs.2015.32.2.296]
  4. Kim, SH, Hong, BU, Lee, JW, Cha, WS, Kim, KJ, Moon, BK(2019). Evaluation of SO2 absorption efficiency for calcined oyster shell slurry using a simulated spray tipe-flue gas desulfurization (FGD) system: A comparative study with limestone slurry. Econ. Environ. Geol., 52(2), pp.119-128 [Korea literature]. [https://dx.doi.org/10.9719/EEG.2019.52.2.119]
  5. Kim, YJ, Jung, JO, Jung, YJ (2015). Hydrochloric acid gas removal from iron and steel industry using micro-bubbles of a dip injection wet scrubber system. J. Wet. Res., 17(1), pp.75-79 [Korea literature] [http://dx.doi.org/10.17663/JWR.2015.17.1.075]
  6. Jung, JO, Jung, YJ (2016). Industrial wastewater treatment containing high concentration of ammonia with low energy micro-bubble reactor. J. Wet. Res., 18(3), pp.286-291 [Korea literature] [http://dx.doi.org/10.17663/JWR.2016.18.3.286]
  7. Jung, JO, Jung, YJ(2020). Hydrogen sulfide removal of biogas from sewage treatment plant with micro-bubble generation system. J. of Wetlands Research, 22(4), pp.239-244 [Korea literature]. [https://doi.org/10.17663/JWR.2020.22.4.239].
  8. Jung, JO, Jung, YJ(2020). Treatment of exhaust pollutants from a lime kiln of paper-mill with micro-bubble system. J. of Env. Sci. Int., 29(11), pp.1025-1032 [Korea literature]. [https://doi.org/10.5322/JESI.2020.29.11.1025].
  9. Jung, YJ, Jung JO, Kim, YJ (2015). Treatment of hydrochloric acid from regeneration and scrubber system of cold rolling mill plant with micro-bubble. J. Wet. Res., 17(2), pp.118-123 [Korea literature] [http://dx.doi.org/10.17663/JWR.2015.17.2.118]
  10. Lim JH, Choi, YY, Kim, GY, Song, HJ, Kim, JH(2019). Modeling of wet flue gas desulfurization process for utilization of low-grade limestone. Korean Chem. Eng. Res., 57(5), pp.743-748 [Korea literature]. [https://doi.org/10.9713/kcer.2019.57.5.743]
  11. Park, SS, Hong, JP, An, YM, Park, SY, Eun, HM(2000). Operating results of 200MW-scale wet limestone based FGD system. J. of KSEE., 22(8), pp.1407-1416 [Korea literature]
  12. Seo, SK, Chu, YS, Shim, KB(2016). A study on the application with limestone sludge at limestome-gypsum wet flue gas desulfurization process. J. of Korean Inst. of Resources Recycling, 25(5), pp.44-49 [Korea literature]. [http://dx.doi.org/10.7844/kirr.2016.25.5.44]
  13. Tsang, YF, Wang, L, Chua, H(2015). Simultaneous hydrogen sulphide and ammonia removal in a biotrickling filter:Crossed inhibitory effects among selected pollutants and microbial community change. Chemical Engineering J, 281, pp.389-396 [http://dx.doi.org/10.1016/j.cej.2015.06.107]