Membrane and Water Treatment

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Removal of reactive black 5 dye by using polyoxometalate-membrane

  • Topaloglu, Ali Kemal (Department of Environmental Engineering, Zonguldak Bulent Ecevit University) ;
  • Yildirim, Yilmaz (Department of Environmental Engineering, Zonguldak Bulent Ecevit University)
  • Received : 2020.07.08
  • Accepted : 2021.02.01
  • Published : 2021.01.25
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Abstract

A POM-membrane was fabricated by immobilizing a keggin type polyoxometalate (POM) H5PV2Mo10O40 onto the surface of microporous flat-sheet polymeric polyvinylidene fluoride (PVFD) membrane using a chemical deposition method. The POM-membrane was characterized by FT-IR, SEM and EDX to confirm existing of the POM onto the membrane surface. The POM-membrane was used to remove an anionic textile dye (Reactive Black 5 named as an RB5) from aqueous phases with a cross-flow membrane filtration and a batch adsorption system. The dye removal efficiency of the POM-membrane using the cross-flow membrane filtration system and the batch adsorption system was about 88% and 98%, respectively. The influence factors such as contact time, adsorbent dosage, pH, and initial dye concentration were investigated to understand the adsorption mechanism of the RB5 dye onto the POM-membrane. To find the best fitting isotherm model, Langmuir, Freundlich, BET and Harkins-Jura isotherm models were used to analyze the experimental data. The isotherm analysis showed that the Langmuir isotherm model was found to the best fit for the adsorption data (R2 = 0.9982, qmax = 24.87 mg/g). Also, adsorption kinetic models showed the pseudo second order kinetic model was found the best model to fit the experimental data (R2 = 0.9989, q = 8.29 mg/g, C0 = 15 ppm). Moreover, after four times regeneration with HNO3 acid, the POM-membrane showed high regenerability without losing dye adsorption capacity.

Keywords

References

  1. Ahmad, A., Mohd-setapar, S.H., Chuong, S. and Khatoon, A. (2015), "Recent advances in new generation dye removal technologies: Novel search for approaches to reprocess wastewater", RSC Adv., 5(39), 30801-30818. https://doi.org/10.1039/C4RA16959J.
  2. Ahmed, M.J., Islam, M.A., Asif, M. and Hameed, B.H. (2017), "Human hair-derived high surface area porous carbon material for the adsorption isotherm and kinetics of tetracycline antibiotics", Bioresour. Technol., 243, 778-784. https://doi.org/10.1016/j.biortech.2017.06.174.
  3. Ai, L., Zhou, Y. and Jiang, J. (2011), "Removal of methylene blue from aqueous solution by montmorillonite/CoFe2O4 composite with magnetic separation performance", Desalination, 266(1-3), 72-77. https://doi.org/10.1016/j.desal.2010.08.004.
  4. Ammam, M. (2013), "Polyoxometalates: Formation, structures, principal properties, main deposition methods and application in sensing", J. Mater. Chem., A, 1, 6291-6312. https://doi.org/10.1039/c3ta01663c.
  5. Anbia, M., Hariri, S.A. and Ashrafizadeh, S.N. (2010), "Adsorptive removal of anionic dyes by modified nanoporous silica SBA-3", Appl. Surf. Sci., 256(10), 3228-3233. https://doi.org/10.1016/j.apsusc.2009.12.010.
  6. Arami, M., Limaee N.Y., Mahmoodi N.M. and Tabrizi N.S. (2006), "Equilibrium and kinetics studies for the adsorption of direct and acid dyes from aqueous solution by soy meal hull", J. Hazard. Mater., 135, 171-179. https://doi.org/10.1016/j.jhazmat.2005.11.044.
  7. Baral, S.S., Das, N., Roy Chaudhury, G. and Das, S.N. (2009), "A preliminary study on the adsorptive removal of Cr(VI) using seaweed, Hydrilla verticillata", J. Hazard. Mater., 171, 358-369. https://doi.org/10.1016/j.jhazmat.2009.06.011.
  8. Ben-Ali, S., Jaouali, I., Souissi-Najar, S. and Ouederni, A. (2017), "Characterization and adsorption capacity of raw pomegranate peel biosorbent for copper removal", J. Clean. Prod., 142, 3809-3821. https://doi.org/10.1016/j.jclepro.2016.10.081.
  9. Du, Q., Sun, J., Li, Y., Yang, X., Wang, X., Wang, Z. and Xia, L. (2014), "Highly enhanced adsorption of congo red onto graphene oxide/chitosan fibers by wet-chemical etching off silica nanoparticles", Chem. Eng. J., 245, 99-106. https://doi.org/10.1016/j.cej.2014.02.006.
  10. Ghaedi, M., Nasab, A.G., Khodadoust, S., Rajabi, M. and Azizian, S. (2014), "Application of activated carbon as adsorbents for efficient removal of methylene blue: Kinetics and equilibrium study", J. Ind. Eng. Chem., 20(4), 2317-2324. https://doi.org/10.1016/j.jiec.2013.10.007.
  11. Guzel, F., Saylili, H., Akkaya Saylili, G. and Koyuncu, F. (2015), "New low-cost nanoporous carbonaceous adsorbent developed from carob (Ceratonia siliqua) processing industry waste for the adsorption of anionic textile dye: Characterization, equilibrium and kinetic modeling", J. Mol. Liq., 206, 244-255. https://doi.org/10.1016/j.molliq.2015.02.037.
  12. Hebbar, R.S., Isloor, A.M., Inamuddin, Abdullah, M.S., Ismail, A.F. and Asiri, A.M. (2018), "Fabrication of polyetherimide nanocomposite membrane with amine functionalised halloysite nanotubes for effective removal of cationic dye effluents", J. Taiwan Inst. Chem. Eng., 93, 42-53. https://doi.org/10.1016/j.jtice.2018.07.032.
  13. Heibati, B., Rodriguez-couto, S., Amrane, A., Rafatullah, M., Hawari, A. and Al-ghouti, M.A. (2014), "Uptake of reactive black 5 by pumice and walnut activated carbon: Chemistry and adsorption mechanisms", J. Ind. Eng. Chem., 20(5), 2939-2947. https://doi.org/10.1016/j.jiec.2013.10.063.
  14. Hosseini, M., Keshtkar, A.R. and Moosavian, M.A. (2016), "Electrospun chitosan/baker's yeast nanofibre adsorbent: Preparation, characterization and application in heavy metal adsorption", Bull. Mater. Sci., 39, 1091-1100. https://doi.org/10.1007/s12034-016-1260-5.
  15. Khan, M.A., Khan, M.I. and Zafar, S. (2017), "Removal of different anionic dyes from aqueous solution by anion exchange membrane", Membr. Water Treat., 3, 259-277. https://doi.org/10.12989/mwt.2017.8.3.259.
  16. Khan, M.I., Ansari, T.M., Zafar, S., Buzdar, A.R., Khan, M.A., Mumtaz, F., Prapamonthon, P. and Akhtar, M. (2018), "Acid green-25 removal from wastewater by anion exchange membrane: Adsorption kinetic and thermodynamic studies", Membr. Water Treat., 2, 79-85. https://doi.org/10.12989/mwt.2018.9.2.079.
  17. Kumar, D. and Landry, C.C. (2007), "Immobilization of a Mo, V-polyoxometalate on cationically modified mesoporous silica: Synthesis and characterization studies", Microporous Mesoporous Mater., 98, 309-316. https://doi.org/10.1016/j.micromeso.2006.09.023.
  18. Lafi, R., Mabrouk, W. and Hafiane, A. (2019), "Removal of Methylene blue from saline solutions by adsorption and electrodialysis", Membr. Water Treat., 2, 139-148. https://doi.org/10.12989/mwt.2019.10.2.139.
  19. Laohaprapanon, S., Matahum, J., Tayo, L. and You, S.J. (2015), "Photodegradation of reactive black 5 in a ZnO/UV slurry membrane reactor", J. Taiwan Inst. Chem. Eng., 49, 136-141. https://doi.org/10.1016/j.jtice.2014.11.017.
  20. Li, F., Chen, Y., Huang, H., Cao, W. and Li, T. (2015), "Removal of rhodamine B and Cr(VI) from aqueous solutions by a polyoxometalate adsorbent", Chem. Eng. Res. Des., 100, 192-202. https://doi.org/10.1016/j.cherd.2015.05.030.
  21. Li, Q., Li, Y., Ma, X., Du, Q., Sui, K., Wang, D., Wang, C., Li, H. and Xia, Y. (2017), "Filtration and adsorption properties of porous calcium alginate membrane for methylene blue removal from water", Chem. Eng. J., 316, 623-630. https://doi.org/10.1016/j.cej.2017.01.098.
  22. Li, C., Lou, T., Yan, X., Long, Y.Z., Cui, G. and Wang, X. (2018), "Fabrication of pure chitosan nanofibrous membranes as effective absorbent for dye removal", Int. J. Biol. Macromol., 106, 768-774. https://doi.org/10.1016/j.ijbiomac.2017.08.072.
  23. Liu, J. and Wang, X. (2013), "Novel silica-based hybrid adsorbents : Lead (II) adsorption isotherms", Sci. World J., 2013, 1-7. http://dx.doi.org/10.1155/2013/897159.
  24. Mahboub, M.N., Jafari, Z. and Khojasteh, Y. (2020), "Cost-effective polyvinylchloride- based adsorbing membrane for cationic dye removal", Membr. Water Treat., 2, 131-139. https://doi.org/10.12989/mwt.2020.11.2.131.
  25. Muller, A., Krickemeyer, E., Meyer, J., Bogge, H., Peters, F., Plass, W., Diemann, E., Dillinger, S., Nonnenbruch, F., Randerath, M. and Menke, C. (1995), "[Mo154(NO)14O420(OH)28(H2O)70](25±5): A water‐soluble big wheel with more than 700 atoms and a relative molecular mass of about 24000", Angew. Chem. Int. Ed., 34, 2122-2124. https://doi.org/10.1002/anie.199521221.
  26. Munagapati, V.S., Yarramuthi, V., Kim, Y., Lee, K.M. and Kim, D.S. (2018), "Removal of anionic dyes (reactive black 5 and congo red) from aqueous solutions using banana peel powder as an adsorbent", Ecotoxicol. Environ. Saf., 148, 601-607. https://doi.org/10.1016/j.ecoenv.2017.10.075.
  27. Nesic, A.R., Velickovic, S.J. and Antonovic, D.G. (2012), "Characterization of chitosan/montmorillonite membranes as adsorbents for Bezactiv Orange V-3R dye", J. Hazard. Mater., 209, 256-263. https://doi.org/10.1016/j.jhazmat.2012.01.020.
  28. Ozer, A. and Dursun, G. (2007), "Removal of methylene blue from aqueous solution by dehydrated wheat bran carbon", J. Hazard. Mater., 146(1-2), 262-269. https://doi.org/10.1016/j.jhazmat.2006.12.016.
  29. Patel, S. and Hota, G. (2014), "Adsorptive removal of malachite green dye by functionalized electrospun PAN nanofibers membrane", Fibers Polym., 15(11), 2272-2282. https://doi.org/10.1007/s12221-014-2272-7.
  30. Putaj, P. and Lefebvre, F. (2011), "Polyoxometalates containing late transition and noble metal atoms", Coord. Chem. Rev., 255(15-16), 1642-1685. https://doi.org/10.1016/j.ccr.2011.01.030.
  31. Rabbani, M., Seghatoleslami, Z.S. and Rahimi, R. (2017), "Selective adsorption of organic dye methylene blue by Cs4H2PMo11FeO40·6H2O in presence of methyl orange and Rhodamine-B", J. Mol. Struct., 1146, 113-118. https://doi.org/10.1016/j.molstruc.2017.05.134.
  32. Rache, M.L., Garcia, A.R., Zea, H.R., Silva, A.M.T., Madeira, L.M. and Ramirez, J.H. (2014), "Azo-dye orange II degradation by the heterogeneous Fenton-like process using a zeolite Y-Fe catalyst-Kinetics with a model based on the Fermi's equation", Appl. Catal. B., 146, 192-200. https://doi.org/10.1016/j.apcatb.2013.04.028.
  33. Rajabi, M., Mirza, B., Mahanpoor, K., Mirjalili, M., Najafi, F., Moradi, O., Sadegh, H., Shahryari-ghoshekandi, R., Asif, M., Tyagi, I., Agarwal, S. and Gupta, V.K. (2016), "Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: Determination of equilibrium and kinetics parameters", J. Ind. Eng. Chem., 34, 130-138. https://doi.org/10.1016/j.jiec.2015.11.001.
  34. Roesink, H.D.W., Beerlage, M.A.M., Potman, W., Van Den Boomgaard, T., Mulder, M.H.V. and Smolders, C.A. (1991), "Characterization of new membrane materials by means of fouling experiments Adsorption of bsa on polyetherimidepolyvinylpyrrolidone membranes", Colloids Surf., 55, 231-243. https://doi.org/10.1016/0166-6622(91)80095-6.
  35. Shao, L., Cheng, X.Q., Liu, Y., Quan, S., Ma, J., Zhao, S.Z. and Wang, K.Y. (2013), "Newly developed nanofiltration (NF) composite membranes by interfacial polymerization for Safranin O and Aniline blue removal", J. Membr. Sci., 430, 96-105. https://doi.org/10.1016/j.memsci.2012.12.005.
  36. Tangestaninejad, S., Moghadam, M., Mirkhani, V., Mohammadpoor-Baltork, I. and Salavati, H. (2010), "Vanadium-containing polyphosphomolybdate immobilized on TiO2 nanoparticles: A recoverable and efficient catalyst for photochemical, sonochemical and photosonochemical degradation of dyes under irradiation of UV light", J. Iran. Chem. Soc. 7, 161-174. https://doi.org/10.1007/bf03246195.
  37. Thirumoorthy, K. and Krishna, S.K. (2020), "Removal of cationic and anionic dyes from aqueous phase by Ball clay - Manganese dioxide nanocomposites", J. Environ. Chem. Eng., 8, 103582. https://doi.org/10.1016/j.jece.2019.103582.
  38. Tsigdinos, G.A. and Hallada, C.J. (1968), "Molybdovanadophosphoric acids and their salts. I. Investigation of methods of preparation and characterization", Inorg. Chem., 7, 437-441. https://doi.org/10.1021/ic50061a009.
  39. Vakili, M., Rafatullah, M., Salamatinia, B., Abdullah, A.Z., Ibrahim, M.H., Tan, K.B., Gholami, Z. and Amouzgar, P. (2014), "Application of chitosan and its derivatives as adsorbents for dye removal from water and wastewater: A review", Carbohydr. Polym., 113, 115-130. https://doi.org/10.1016/j.carbpol.2014.07.007.
  40. Vakili, M., Rafatullah, M., Salamatinia, B., Hakimi, M. and Zuhairi, A. (2015), "Elimination of reactive blue 4 from aqueous solutions using 3-aminopropyl triethoxysilane modified chitosan beads", Carbohydr. Polym., 132, 89-96. https://doi.org/10.1016/j.carbpol.2015.05.080.
  41. Vakili, M., Rafatullah, M., Hakimi, M., Zuhairi, A., Salamatinia, B. and Gholami, Z. (2016), "Chitosan hydrogel beads impregnated with hexadecylamine for improved reactive blue 4 adsorption", Carbohydr. Polym., 137, 139-146. http://dx.doi.org/10.1016/j.carbpol.2015.09.017.
  42. Vakili, M., Rafatullah, M., Hakimi, M., Zuhairi, A., Gholami, Z. and Salamatinia, B. (2017), "Enhancing reactive blue 4 adsorption through chemical modification of chitosan with hexadecylamine and 3-aminopropyl triethoxysilane", J. Water Process Eng., 15, 49-54. https://doi.org/10.1016/j.jwpe.2016.06.005.
  43. Wang, X., Liu, Z., Ye, X., Hu, K., Zhong, H., Yu, J., Jin, M. and Guo, Z. (2014), "A facile one-step approach to functionalized graphene oxide-based hydrogels used as effective adsorbents toward anionic dyes", Appl. Surf. Sci., 308, 82-90. https://doi.org/10.1016/j.apsusc.2014.04.103.
  44. Wang, X., Li, Y., Li, H. and Yang, C. (2016), "Chitosan membrane adsorber for low concentration copper ion removal", Carbohydr. Polym., 146, 274-281. https://doi.org/10.1016/j.carbpol.2016.03.055.
  45. Weber, W.J. and Morris, J.C. (1963), "Kinetics of adsorption on carbon from solution", Am. Soc. Civ. Eng., 89, 31-60.
  46. Wong, S., Tumari, H.H., Ngadi, N., Mohamed, N.B., Hassan, O., Mat, R. and Saidina Amin, N.A. (2019), "Adsorption of anionic dyes on spent tea leaves modified with polyethyleneimine (PEISTL)", J. Clean. Prod., 206, 394-406. https://doi.org/10.1016/j.jclepro.2018.09.201.
  47. Xin, S., Zeng, Z., Zhou, X., Luo, W., Shi, X., Wang, Q., Deng, H. and Du, Y. (2017), "Recyclable saccharomyces cerevisiae loaded nanofibrous mats with sandwich structure constructing via bio-electrospraying for heavy metal removal", J. Hazard. Mater., 324, 365-372. https://doi.org/10.1016/j.jhazmat.2016.10.070.
  48. Xiong, X., Jianguo, B., Hassan, O.S., Hui, G., Yu, Z. and Hong, W. (2016), "Study for adsorption behaviors of emulsion oil on a novel ZrO2/PVDF modified membrane", Desal. Water Treat., 57, 11736-11745. https://doi.org/10.1080/19443994.2015.1044918.
  49. Yang, Y., Wang, G., Wang, B., Li, Z., Jia, X., Zhou, Q. and Zhao, Y. (2011), "Biosorption of Acid Black 172 and Congo Red from aqueous solution by nonviable Penicillium YW 01: Kinetic study, equilibrium isotherm and artificial neural network modeling", Bioresour. Technol., 102, 828-834. https://doi.org/10.1016/j.biortech.2010.08.125.
  50. Yao, L., Zhang, L.Z., Wang, R., Loh, C.H. and Dong, Z.L. (2013), "Fabrication of catalytic membrane contactors based on polyoxometalates and polyvinylidene fluoride intended for degrading phenol in wastewater under mild conditions", Sep. Purif. Technol., 118, 162-169. https://doi.org/10.1016/j.seppur.2013.06.029.
  51. Yao, L., Lua, S.K., Zhang, L., Wang, R. and Dong, Z.L. (2014), "Dye removal by surfactant encapsulated polyoxometalates", J. Hazard. Mater., 280, 428-435. https://doi.org/10.1016/j.jhazmat.2014.08.026.
  52. Yao, L., Zhang, L., Wang, R., Chou, S. and Dong, Z.L. (2016), "A new integrated approach for dye removal from wastewater by polyoxometalates functionalized membranes", J. Hazard. Mater., 301, 462-470. https://doi.org/10.1016/j.jhazmat.2015.09.027.
  53. Yildirim, Y. and Topaloglu, A.K. (2018), "POM based catalytic membrane contactor preparing and characterizing", MSU J. Sci., 6, 539-544. https://doi.org/10.18586/msufbd.459266.
  54. Yu, S., Liu, M., Ma, M., Qi, M., Lu, Z. and Gao, C. (2010), "Impacts of membrane properties on reactive dye removal from dye/salt mixtures by asymmetric cellulose acetate and composite polyamide nanofiltration membranes", J. Membr. Sci., 350, 83-91. https://doi.org/10.1016/j.memsci.2009.12.014.
  55. Zhang, X., Chen, M., Yu, Y., Yang, T. and Wang, J. (2011), "Polyelectrolyte-modified multi-walled carbon nanotubes for the adsorption of chromium(vi)", Anal. Methods., 3(2), 457-462. https://doi.org/10.1039/c0ay00621a.
  56. Zhang, B., Yu, S., Zhu, Y., Shen, Y., Gao, X., Shi, W. and Hwa Tay, J. (2020), "Adsorption mechanisms of crude oil onto polytetrafluoroethylene membrane: Kinetics and isotherm, and strategies for adsorption fouling control", Sep. Purif. Technol., 235, 116212. https://doi.org/10.1016/j.seppur.2019.116212.
  57. Zhao, S., Wang, X. and Huo, M. (2010), "Catalytic wet air oxidation of phenol with air and micellar molybdovanadophosphoric polyoxometalates under room condition", Appl. Catal. B., 97, 127-134. https://doi.org/10.1016/j.apcatb.2010.03.032.
  58. Zheng, H., Liu, D., Zheng, Y., Liang, S. and Liu, Z. (2009), "Sorption isotherm and kinetic modeling of aniline on Cr-bentonite", J. Hazard. Mater., 167(1-3), 141-147. https://doi.org/10.1016/j.jhazmat.2008.12.093.