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Qualitative comparison of chemical and green synthesized Fe3O4 nanoparticles

  • Gokila, V. (Thermal and Bio Analysis Laboratory, Department of Chemical Engineering, AC Tech Campus, Anna University) ;
  • Perarasu, V.T. (Thermal and Bio Analysis Laboratory, Department of Chemical Engineering, AC Tech Campus, Anna University) ;
  • Rufina, R. Delma Jones (Thermal and Bio Analysis Laboratory, Department of Chemical Engineering, AC Tech Campus, Anna University)
  • 투고 : 2020.01.31
  • 심사 : 2020.11.04
  • 발행 : 2021.01.25

초록

Synthesis of nanoparticles using green technology using plants is gaining significant attention as it is an environmentally friendly substitute to conventional physical and chemical methods. The present study was focused on the chemical and green synthesis of Iron Oxide nanoparticles from ferric chloride. The green synthesis was achieved by utilizing the bio components of Hibiscus rosa-sinensis. The Fe3O4 nanoparticles with the size range of 87-400 nm were synthesized by wet chemical reduction technique which are unstable, prone to aggregation while in green synthesis the phytochemicals present in the leaf extract acts as the capping as well as the reducing agent thus the green synthesized iron (III) oxide nanoparticles were naturally stabilized, spherical shaped and are in the size range of 2-80 nm. The results of both the protocols are compared and presented briefly.

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참고문헌

  1. Al-Snafi, A.E. (2018), "Chemical constituents, pharmacological effects and therapeutic importance of Hibiscus rosa-sinensis - A review", J. Pharm., 8(7), 101-119.
  2. haki, S.H., Malek, T.J., Chaudhary, M.D., Tailor, J.P. and Deshpande, M.P. (2015), "Magnetite Fe3O4 nanoparticles synthesis by wet chemical reduction and their characterization", Adv. Nat. Sci. Nanosci. Nanotechnol., 6(3), 035009. http://dx.doi.org/10.1088/2043-6262/6/3/035009.
  3. Devi, R.S. and Gayathri, R. (2014), "Green synthesis of zinc oxide nanoparticles by using Hibiscus rosa-sinensis", Int. J. Curr. Eng. Technol., 4(4), 2444-2446.
  4. ravani, S. (2011), "Green synthesis of metal nanoparticles using plants", Green Chem., 13(10), 2638-2650. http://dx.doi.org/10.1039/C1GC15386B.
  5. Kanagasubbulakshmi, S. and Kadirvelu, K. (2017), "Green synthesis of iron oxide nanoparticles using Lagenaria siceraria and evaluation of its antimicrobial activity", Defence Life Sci. J., 2(4), 422-427. https://doi.org/10.14429/dlsj.2.12277.
  6. Kharissova, O.V., Dias, H.R., Kharisov, B.I., Perez, B.O. and Perez, V.M.J. (2013), "The greener synthesis of nanoparticles", Trends Biotechnol. 31(4), 240-248. https://doi.org/10.1016/j.tibtech.2013.01.003.
  7. Makarov, V.V., Makarova, S.S., Love, A.J., Sinitsyna, O.V., Dudnik, A.O., Yaminsky, I.V., Taliansky, M.E. and Kalinina, N.O. (2014), "Biosynthesis of stable iron oxide nanoparticles in aqueous extracts of Hordeum vulgare and Rumex acetosa plants", Langmuir, 30(20), 5982-5988. https://doi.org/10.1021/la5011924.
  8. Mohanpuria, P., Rana, N.K. and Yadav, S.K. (2008), "Biosynthesis of nanoparticles: Technological concepts and future applications", J. Nanopart. Res., 10(3), 507-517. https://doi.org/10.1007/s11051-007-9275-x.
  9. Muthukumar, H., Mohammed, S.N., Chandrasekaran, N., Sekar, A.D., Pugazhendhi, A. and Matheswaran, M. (2019), "Effect of iron doped Zinc oxide nanoparticles coating in the anode on current generation in microbial electrochemical cells", Int. J. Hydrog. Energy, 44(4), 2407-2416. https://doi.org/10.1016/j.ijhydene.2018.06.046.
  10. Nasrollahzadeh, M., Sajadi, S. M., Sajjadi, M. and Issaabadi, Z. (2019), "An introduction to nanotechnology", Interf. Sci. Technol., 28, 1-27. http://dx.doi.org/10.1016/B978-0-12-813586-0.00001-8.
  11. Njagi, E.C., Huang, H., Stafford, L., Genuino, H., Galindo, H.M., Collins, J.B., Hoag, G.E. and Suib, S.L. (2010), "Biosynthesis of iron and silver nanoparticles at room temperature using aqueous sorghum bran extracts", Langmuir, 27(1), 264-271. https://doi.org/10.1021/la103190n.
  12. Pugazhendhi, A., Kumar, S.S., Manikandan, M. and Saravanan, M. (2018), "Photocatalytic properties and antimicrobial efficacy of Fe doped CuO nanoparticles against the pathogenic bacteria and fungi", Microb. Pathog., 122, 84-89. https://doi.org/10.1016/j.micpath.2018.06.016.
  13. Reveendran, A., Varghese, S. and Viswanathan, K. (2016), "Green synthesis of silver nano particle using Hibiscus rosasinensis", IOSR J. Appl. Phys., 8, 35-38. https://doi.org/10.9790/4861-0803023538.
  14. Ruiz-Baltazar, A., Esparza, R., Rosas, G. and Perez, R. (2015), "Effect of the surfactant on the growth and oxidation of iron nanoparticles", J. Nanomater., 2015, 240948. https://doi.org/10.1155/2015/240948.
  15. Salam, H.A., Sivaraj, R. and Venckatesh, R. (2014), "Green synthesis and characterization of zinc oxide nanoparticles from Ocimum basilicum L. var. purpurascens Benth- Lamiaceae leaf extract", Mater. Lett., 131, 16-18. https://doi.org/10.1016/j.matlet.2014.05.033.
  16. Thunugunta, T. and Reddy, A.C. (2015), "Green synthesis of nanoparticles: Current prospectus", Nanotechnol. Rev., 4(4), 303-323. https://doi.org/10.1515/ntrev-2015-0023.
  17. Vasantharaj, S., Sathiyavimal, S., Senthilkumar, P., LewisOscar, F. and Pugazhendhi, A. (2019), "Biosynthesis of iron oxide nanoparticles using leaf extract of Ruellia tuberosa: Antimicrobial properties and their applications in photocatalytic degradation", J. Photochem. Photobiol. B Biol., 192, 74-82. https://doi.org/10.1016/j.jphotobiol.2018.12.025.
  18. Sarsar, V., Selwal, K.K. and Selwal, M.K. (2014), "Nanosilver: Potent antimicrobial agent and its biosynthesis", Afr. J. Biotechnol., 13(4), 546-554. https://doi.org/10.5897/AJB2013.13147
  19. Wang, Y., O'Connor, D., Shen, Z., Lo, I.M., Tsang, D.C, Pehkonen, S., Pu, S. and Hou, D. (2019), "Green synthesis of nanoparticles for the remediation of contaminated waters and soils: Constituents, synthesizing methods and influencing factors", J. Clean. Prod., 226, 540-549. https://doi.org/10.1016/j.jclepro.2019.04.128.
  20. Yardily, A. and Sunitha, N. (2019), "Green synthesis of iron nanoparticles using hibiscus leaf extract, characterization, antimicrobial activity", Int. J. Sci. Res. Rev., 8, 32-46.
  21. Zhu, X., Pathakoti, K. and Hwang, H.M. (2019), Green Synthesis, Characterization and Applications of Nanoparticles, Elsevier, Amsterdam, Netherlands. https://doi.org/10.1016/B978-0-08-102579-6.00010-1