습식법을 이용한 고무 소재의 가교밀도 분석 기법

  • Published : 2021.12.31

Abstract

Keywords

References

  1. C. E. Son and S.-S. Choi, "Analytical techniques for measurement of crosslink densities of rubber vulcanizates", Elast. Compos., 54, 209 (2019). https://doi.org/10.7473/ec.2019.54.3.209
  2. S.-S. Choi, "Bond dissociation of sulfur crosslinks in IR and BR vulcanizates using semi-empirical calculations", Kor. Polym. J., 5, 393 (1997).
  3. 박희용, 이유라, 조혜성, "가황 고무 내 황 가교 결합 길이의 분석 방법", 대한민국특허 10-2017-0124354 (2017).
  4. T. Saleesung, D. Reichert, K. Saalwachter, and C. Sirisinha, "Correlation of crosslink densities using solid state NMR and conventional techniques in peroxide-crosslinked EPDM rubber", Polymer, 56, 309 (2015). https://doi.org/10.1016/j.polymer.2014.10.057
  5. M. K. Dibbanti, "Study of polymer crosslink density by time domain NMR spectroscopy", University of Milano-Bicocca (2015).
  6. S. P. Carvalho, E. F. Lucas, G. Gonzalez, and L. S. Spinelli, "Determining Hildebrand solubility parameter by ultraviolet spectroscopy and microcalorimetry", J. Braz. Chem. Soc., 24, 1998 (2013).
  7. Y. K. Chae, W. Y. Kang, J-H. Jang, and S-S. Choi, "A simple NMR method to measure crosslink density of natural rubber composite", Polym Test., 29, 953 (2010). https://doi.org/10.1016/j.polymertesting.2010.08.003
  8. M. D. Ellul, H. Tsou, and W. Hu, "Crosslink densities and phase morphologies in thermoplastic vulcanizates", Polymer, 45, 3351 (2004). https://doi.org/10.1016/j.polymer.2004.03.029
  9. G. J. Price and I. M. Shillcock, "Inverse gas chromatographic measurement of solubility parameters in liquid crystalline systems", J. Chrom. A, 964, 199 (2002). https://doi.org/10.1016/S0021-9673(02)00651-9
  10. M. Garbarczyk, F. Grinberg, N. Nestle, and W. Kuhn, "A novel approach to the determination of the crosslink density in rubber materials with the dipolar correlation effect in low magnetic fields", J. Polym. Sci. B, Polym. Phys., 39, 2207 (2001). https://doi.org/10.1002/polb.1194
  11. V. M. Litvinov, W. Barendswaard, and M. van Duin, "The density of chemical crosslinks and chain entanglements in unfilled EPDM vulcanizates as studied with low resolution, solid state 1H NMR", Rubber Chem. Technol., 71, 105 (1998). https://doi.org/10.5254/1.3538466
  12. W. Kuhn, P. Barth, P. Denner, and R. Muller, "Characterization of elastomeric materials by NMR-microscopy", Solid State Nucl. Magn. Reson., 6, 295 (1996). https://doi.org/10.1016/0926-2040(96)01236-2
  13. W. Gronski, U. Hoffmann, G. Simon, A. Wutzler, and E. Staraube, "Structure and density of crosslink in natural-rubber vulcanizates. A combined analysis by NMR spectroscopy, mechanical mearuement, and rubber-elastic theory", Rubber Chem. Technol., 65, 63 (1992). https://doi.org/10.5254/1.3538608
  14. 최성신, "고무 배합물의 결합고무 분석 기법", 고무기술지, 22, 241-274 (2021).
  15. P. J. Flory, "Statistical mechanics of swelling of network structures", J. Chem. Phys., 18, 108 (1950). https://doi.org/10.1063/1.1747424
  16. S.-S. Choi and D.-H. Han, "Strain effect on recovery behaviors from circular deformation of natural rubber vulcanizate", J. Appl. Polym. Sci., 114, 935 (2009). https://doi.org/10.1002/app.30699
  17. S.-S. Choi and J.-C. Kim, "Lifetime prediction and thermal aging behaviors of SBR and NBR composites using crosslink density changes", J. Ind. Eng. Chem., 18, 1166 (2012). https://doi.org/10.1016/j.jiec.2012.01.011
  18. S.-S. Choi, H.-M. Kwon, Y. Kim, J. W. Bae, and J.-S. Kim, "Characterization of maleic anhydride-grafted ethylene-propylene-diene terpolymer (MAH-g-EPDM) based thermoplastic elastomers by formation of zinc ionomer J. Ind. Eng. Chem., 19, 1990 (2013). https://doi.org/10.1016/j.jiec.2013.03.011
  19. S.-S. Choi and E. Kim, "A novel system for measurement of types and densities of sulfur crosslinks of a filled rubber vulcanizate", Polym. Test., 42, 62 (2015). https://doi.org/10.1016/j.polymertesting.2014.12.007
  20. J. K. Kim and M. A. Paglicawan, "Effect of devulcanizer on the properties of natural rubber vulcanizates", Philippine J. Sci., 133, 87 (2004).
  21. Z. Hrnjak-Murgic, J. Jelencic, M. Bravar, and M. Marovic, "Influence of the network on the interaction parameter in system EPDM vulcanizate-solvent", J. Appl. Polym. Sci., 65, 991 (1997). https://doi.org/10.1002/(SICI)1097-4628(19970801)65:5<991::AID-APP17>3.0.CO;2-V
  22. W. Salgueiro, A. Somoza, I. L. Torriani, and A. J. Marzocca, "Cure temperature influence on natural rubber-a small angle X-ray scattering study", J. Polym. Sci. B Polym. Phys., 45, 2966 (2007). https://doi.org/10.1002/polb.21293
  23. R. W. Brotzman and P. J. Flory, "Elastic behavior of cis-1,4-polybutadiene", Macromolecules, 20, 351 (1987). https://doi.org/10.1021/ma00168a021
  24. R. M. Masegosa, M. G. Prolongo, and A. Horta, "The g interaction parameter of polymer-solvent systems", Macromolecules, 19, 1478 (1986). https://doi.org/10.1021/ma00159a033
  25. S. Seghar, N. Ait Hocine, V. mittal, S. Azem, A. F. Al-Zohbi, B. Schmaltz, and N. Poirot, "Devulcanization of styrene butadiene rubber by microwave energy: Effect of the presence of ionic liquid", Exp. Polym. Lett., 9, 1076 (2015). https://doi.org/10.3144/expresspolymlett.2015.97
  26. J. Kruzelak, R. Dosoudil, and I. Hudec, "Thermooxidative aging of rubber composites based on NR and NBR with incorporated strontium ferrite", J. Elast. Plast., 50, 71 (2017).
  27. J. Kruzelak, M. Matvejova, R. Dosoudil, and I. Hudec, "Barium and strontium ferrite-filled composites based on NBR and SBR", J. Elast. Plast., 1, (2018).
  28. W. L. Hergenrother, Characterization of networks from the peroxide cure of polybutadiene", J. Appl. Polym. Sci., 16, 2611 (1972). https://doi.org/10.1002/app.1972.070161014
  29. W. O. Parker, A. Ferrando, D. Ferri, and V. Canepari, "Cross-link density of a dispersed rubber measured by 129Xe chemical shift", Macromolecules, 40, 5787 (2007). https://doi.org/10.1021/ma070793a
  30. F. Guom, J. W. Andreasen, M. E. Vigild and S. Ndoni, "Influence of 1,2-PB matrix cross-linking on structure and properties of selectively etched 1,2-PB-b-PDMS block copolymers", Macromolecules, 40, 3669 (2007). https://doi.org/10.1021/ma062947c
  31. N. Z. Noriman, H. Ismail, and A. A. Rashid, "Characterization of styrene butadiene rubber/recycled acrylonitrile-butadiene rubber (SBR/NBRr) blends: The effects of epoxidized natural rubber (ENR-50) as a compatibilizer", Polym. Test., 29, 200 (2010). https://doi.org/10.1016/j.polymertesting.2009.11.002
  32. M. I. Avadanei, "Photocrosslinking of 1,2-polybutadiene and characteristics of the crosslinked system", J. Macromol. Sci. B, 51, 313 (2011). https://doi.org/10.1080/00222348.2011.596788
  33. S. Saeki, J. C. Holste, and D. C. Bonner, "Vapor-liquid equilibria for polybutadiene and polyisoprene solutions", J. Polym. Sci. Polym. Phys., 20, 793 (1982). https://doi.org/10.1002/pol.1982.180200502
  34. R. S. Jessup, "Thermodynamic properties of the systems polybutadiene-benzene and polyisobutene-benzene", J. Res. Natl. Bur. Stand., 60, 47 (1958). https://doi.org/10.6028/jres.060.006
  35. E. C. Gregg and S. E. Katrenick. "Chemical structure in cis-1,4-polybutadiene vulcanizates. Model compound approach", Rubber Chem. Technol., 43, 549 (1970). https://doi.org/10.5254/1.3547273
  36. H. Nabil, H. Ismail, and A. R. Azura, "Effects of virgin ethylene-propylene-diene-monomer and its preheating time on the properties of natural rubber/recycled ethylene-propylene-diene-monomer blends", Mater. Design, 50, 27 (2013). https://doi.org/10.1016/j.matdes.2013.02.086
  37. J. Diez, R. M. Bellas, J. Lopez, and G. Santoro, "Study of the crosslink density, dynamo-mechanical behaviour and microstructure of hot and cold SBR vulcanizates", J. Polym. Res., 17, 99 (2010) https://doi.org/10.1007/s10965-009-9295-6
  38. S. Rolere, C. Bottier, L. Vaysse, J. Sainte-Abeuve, and F. Bonfils, "Characterisation of macrogel composition from industrial natural rubber samples: Influence of proteins on the macrogel crosslink density", Exp. Polym. Lett., 10, 408 (2016). https://doi.org/10.3144/expresspolymlett.2016.38
  39. S.-S. Choi, "Influence of rubber composition on change of crosslink density of rubber vulcanizates with EV cure system by thermal aging", J. Appl. Polym. Sci., 75, 1378 (2000). https://doi.org/10.1002/(SICI)1097-4628(20000314)75:11<1378::AID-APP9>3.0.CO;2-I
  40. S.-S. Choi and J.-C. Kim, "Lifetime prediction and thermal aging behaviors of SBR and NBR composites using crosslink density changes", J. Ind. Eng. Chem., 18, 1166 (2012). https://doi.org/10.1016/j.jiec.2012.01.011
  41. S.-S. Choi, I.-S. Kim, and C.-S. Woo, "Influence of TESPT content on crosslink types and rheological behaviors of natural rubber compounds reinforced with silica",J. Appl. Polym. Sci., 106, 2753 (2007). https://doi.org/10.1002/app.25744
  42. H.-M. Kwon and S.-S. Choi, "Characterization of crosslinks of maleic anhydride-grafted EPDM/zinc oxide composite using dichloroacetic acid/toluene cosolvent and extraction temperature", Elast. Compos., 48, 288 (2013). https://doi.org/10.7473/EC.2013.48.4.288
  43. D. Y. Kim , J. W. Park, D. Y. Lee, and K. H. Seo, "Correlation between the Crosslink characteristics and mechanical properties of natural rubber compound via accelerators and reinforcement", Polymers, 12, 2020 (2020). https://doi.org/10.3390/polym12092020
  44. S.-S. Choi and Y. Y. Chung, "Simple test method for determination of contribution level of crosslink density by crystalline structure of poly(ethylene-co-vinyl acetate) compound", Polym. Test., 77, 105928 (2019). https://doi.org/10.1016/j.polymertesting.2019.105928