Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
권호 표지
DOI QR코드

DOI QR Code

Electrochemical Property of the Composite Electrode with Graphene Balls and Graphene Oxide for Supercapacitor

슈퍼커패시터용 그래핀볼 - 그래핀옥사이드 복합전극의 전기화학적 특성

  • Jeong, Woo-Jun (School of Energy, Materials & Chemical Engineering Korea University of Technology and Education) ;
  • Oh, Ye-Chan (School of Energy, Materials & Chemical Engineering Korea University of Technology and Education) ;
  • Kim, Sang-Ho (School of Energy, Materials & Chemical Engineering Korea University of Technology and Education)
  • 정우준 (한국기술교육대학교 에너지신소재화학공학과) ;
  • 오예찬 (한국기술교육대학교 에너지신소재화학공학과) ;
  • 김상호 (한국기술교육대학교 에너지신소재화학공학과)
  • Received : 2020.09.28
  • Accepted : 2020.10.27
  • Published : 2020.10.31
Download PDF
⟨ Previous Next ⟩

Abstract

Composite material of the graphene ball (GB) inserted graphene oxide (GO) sheet for a supercapacitor electrode was studied. Chemical vapor deposition (CVD) process used to make GBs on the silicon oxide nanoparticles. The GBs mixed into the GO sheets to make GOGB and reduced it to create a reduced GOGB(RGOGB) composite. The RGOGB composite electrode had a large surface area and improved electrochemical properties. Specific capacitance of the RGBGO composite electrode was higher over 20 times than a pure GO and GOGB electrode in cyclic voltammetry(CV) tests, and the Z' and Z" impedance measured by an electrochemical impedance spectrometry(EIS) also low. So, the RGBGO composite electrode would use effectively to expand a performance of supercapacitor.

Keywords

References

  1. Nguyen Bao Trung, Tran Van Tam, Hye Ryeon Kim, Seung Hyun Hur, Eui Jung Kim, Won Mook Choi, Three-dimensional hollow balls of graphene-polyaniline hybrids for supercapacitor applications, Chemical Engineering Journal. 255 (2014) 89-96. https://doi.org/10.1016/j.cej.2014.06.028
  2. Eun Hee Jo, Ji-Hyuk Choi, Su-Ryeon Park, Chong Min Lee, Hankwon Chang, Hee Dong Jang, Size and Structural Effect of Crumpled Graphene Balls on the Electrochemical Properties for Supercapacitor Application, Electrochimica Acta. 222 (2016) 58-63. https://doi.org/10.1016/j.electacta.2016.11.016
  3. Jie Tian, Sai Wu, Xianglu Yin, Wei Wu, Novel preparation of hydrophilic graphene_graphene oxide nanosheets for supercapacitor electrode, Applied Surface Science. 496 (2019) 143696. https://doi.org/10.1016/j.apsusc.2019.143696
  4. Huaping Wang, Gui Yu, Direct CVD Graphene Growth on Semiconductors and Dielectrics for Transfer-Free Device Fabrication, Advanced Materials. 28(25) (2016) 4956-4975. https://doi.org/10.1002/adma.201505123
  5. Hwee Ling Poh, Filip Sanek, Adriano Ambrosi, Guanjia Zhao, Zdenek Sofer and Martin Pumera, Graphenes prepared by Staudenmaier, Hofmann and Hummers methods with consequent thermal exfoliation exhibit very different electrochemical properties, Nanoscale 4. (2012) 3515-3522. https://doi.org/10.1039/c2nr30490b
  6. N.I. Zaabaa, K.L. Fooa,*, U. Hashima,d, S.J.Tanb,c, Wei-Wen Liua, C.H. Voona, Synthesis of Graphene Oxide using Modified Hummers Method: Solvent Influence, Procedia Engineering. 184 (2017) 469-477. https://doi.org/10.1016/j.proeng.2017.04.118
  7. In Hyuk Son, Jong Hwan Park, Seongyong Park, Kwangjin Park, Sangil Han, Jaeho Shin, Seok-Gwang Doo, Yunil Hwang, Hyuk Chang & Jang Wook Choi, Graphene balls for lithium rechargeable batteries with fast charging and high volumetric energy densities, Nat Commun 8. 1561 (2017). https://doi.org/10.1038/s41467-017-01823-7
  8. Choi, S., Ko, Y., Lee, J. et al. Rapid continuous synthesis of spherical reduced graphene ballnickel oxide composite for lithium ion batteries. Sci Rep 4 5786 (2015). https://doi.org/10.1038/srep05786
  9. Seung Ho Choi, Yun Chan Kang, Fe3O4-decorated hollow graphene balls prepared by spray pyrolysis process for ultrafast and long cycle-life lithium ion batteries, CARBON 79. (2014) 58-66. https://doi.org/10.1016/j.carbon.2014.07.042
  10. Deqiang Chen, Xiang Liu, Huali Nie, Crumpled graphene balls as rapid and efficient adsorbents for removal of copper ions, Journal of Colloid and Interface Science. 530 (2018) 46-51. https://doi.org/10.1016/j.jcis.2018.06.051
  11. Naderi M, Surface Area: Brunauer- Emmett- Teller (BET), Progress in Filtration and Separation. (2015) 585-608.
  12. Kyoung Hwan Kim, MinHo Yang, Kyeong Min Cho, Young-Si Jun, Sang Bok Lee & Hee-Tae Jung, High quality reduced graphene oxide through repairing with multi-layered graphene ball nanostructures, Scientific Reports. volume 3 Article number: 3251 (2013).
  13. Mukesh Singha, Asha Yadav b, Shailendra Kumar c, Annealing induced electrical conduction and band gap variation in thermally reduced graphene oxide films with different sp2/sp3 fraction, Applied Surface Science. 326 (2015) Pages 236-242. https://doi.org/10.1016/j.apsusc.2014.11.121
  14. V. Rajeswaria, R. Jayavelb,A. Clara Dhanemozhi, Synthesis And Characterization Of Graphene-Zinc Oxide Nanocomposite Electrode Material For Supercapacitor Applications, Materials Today: Proceedings. 4 (2017) 645-652. https://doi.org/10.1016/j.matpr.2017.01.068
  15. Guex, L. G., Sacchi, B., Peuvot, K. F., Andersson, R. L., Pourrahimi, A. M., Strom, V, R. T. Experimental review: chemical reduction of graphene oxide (GO) to reduced graphene oxide (rGO) by aqueous chemistry. Nanoscale. 9(27), (2017). 9562-9571. https://doi.org/10.1039/C7NR02943H
  16. R. Greef, Instrument methods in electrochemistry, John Wiley, first published, Ellis Horwood Limited, New York (1985), 263-268.