Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Catalytic Reduction of ortho- and meta-Nitroaniline by Nickel Oxide Nanoparticles

  • Jeon, Sugyeong (Department of Convergence Science, Graduate School, Sahmyook University) ;
  • Ko, Jeong Won (Nanomaterials Research Institute, Sahmyook University) ;
  • Ko, Weon Bae (Department of Convergence Science, Graduate School, Sahmyook University)
  • Received : 2020.07.14
  • Accepted : 2020.08.02
  • Published : 2020.09.30
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Abstract

Nickel oxide (NiO) nanoparticles were synthesized by a reaction of nickel nitrate hexahydrate (Ni(NO3)2·6H2O) and sodium hydroxide (NaOH). The synthesized NiO nanoparticles were examined with X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and ultraviolet-visible (UV-vis) spectroscopy. The NiO nanoparticles were used as the catalyst for the reduction of o- and m-nitroaniline to phenylenediamine. The reduction rate of m-nitroaniline was faster than that of o-nitroaniline. The reduction rate for both o- and m-nitroaniline increased as the reaction temperature increased. The rate of reduction for nitroaniline followed a pseudo first-order reaction rate law.

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References

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