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상업적으로 프로필렌카보네이트를 제조하기 위한 공정 조건 연구

Study on the Process Condition for Producing Propylene Carbonate in Commercial

  • 진상현 (그린케미칼주식회사 부설연구소) ;
  • 이학범 (그린케미칼주식회사 부설연구소) ;
  • 백제범 (그린케미칼주식회사 부설연구소)
  • 투고 : 2019.11.08
  • 심사 : 2020.01.15
  • 발행 : 2020.03.31

초록

연소 배기가스 중 온실가스의 원인이 되는 이산화탄소를 회수하여 활용하며 상업적으로도 가치가 큰 프로필렌카보네이트(Propylene Carbonate)를 합성하는 연구를 수행하였다. 상업적으로 프로필렌카보네이트 생산 적용이 가능한 균일계 유기 촉매와 반응 조건을 이용하여 pilot scale로 실험을 진행하였으며, 상업적으로 적용 가능한 최적의 촉매 및 농도, 반응 온도 및 압력등의 공정조건을 확립 할 수 있었다. 환경 친화적인 공법이며, 촉매 제조에 가격 경쟁력이 있고, 촉매는 재사용이 가능하며, 기존 대비 낮은 온도 및 압력의 반응 조건으로 95% 이상의 높은 전환율과 99%이상의 순도로 제조 가능하기에 상업적으로 충분히 적용 가능한 공정임을 확인 할 수 있었다.

Among the exhaust gas, Carbon dioxide which is a causative factor in greenhouse effect. We study for synthesis of propylene carbonate with carbon dioxide which is captured and utilized in commercially valuable. The Experiment was proceeded as pilot scale with using homogeneous organic catalyst which is able to produce propylene carbonate in commercial and reaction conditions. Optimization condition for concentration of catalyst and reaction temperature, pressure was studied. We confirm that this process is eco-friendly method and commercial application due to the mild condition and also catalyst has a competitive price, reusability.

키워드

참고문헌

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