Journal of Electrochemical Science and Technology

  • 제11권3호
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  • Pages.282-290
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  • 2020
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  • 2093-8551(pISSN)
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  • 2288-9221(eISSN)
한국전기화학회 (The Korean Electrochemical Society)
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High-Rate Blended Cathode with Mixed Morphology for All-Solid-State Li-ion Batteries

  • Heo, Kookjin (Korea Institute of Industrial Technology (KITECH)) ;
  • Im, Jehong (Korea Institute of Industrial Technology (KITECH)) ;
  • Lee, Jeong-Seon (Korea Institute of Industrial Technology (KITECH)) ;
  • Jo, Jeonggeon (Department of Materials Science and Engineering, Chonnam National University) ;
  • Kim, Seokhun (Department of Materials Science and Engineering, Chonnam National University) ;
  • Kim, Jaekook (Department of Materials Science and Engineering, Chonnam National University) ;
  • Lim, Jinsub (Korea Institute of Industrial Technology (KITECH))
  • 투고 : 2019.11.20
  • 심사 : 2020.03.16
  • 발행 : 2020.08.31
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초록

In this article, we report the effect of blended cathode materials on the performance of all-solid-state lithium-ion batteries (ASLBs) with oxide-based organic/inorganic hybrid electrolytes. LiFePO4 material is good candidates as cathode material in PEO-based solid electrolytes because of their low operating potential of 3.4 V; however, LiFePO4 suffers from low electric conductivity and low Li ion diffusion rate across the LiFePO4/FePO4 interface. Particularly, monoclinic Li3V2(PO4)3 (LVP) is a well-known high-power-density cathode material due to its rapid ionic diffusion properties. Therefore, the structure, cycling stability, and rate performance of the blended LiFePO4/Li3V2(PO4)3 cathode material in ASLBs with oxidebased inorganic/organic-hybrid electrolytes are investigated by using powder X-ray diffraction analysis, field-emission scanning electron microscopy, Brunauer-Emmett-Teller sorption experiments, electrochemical impedance spectroscopy, and galvanostatic measurements.

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