Membrane and Water Treatment

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Wastewater treatment using a hybrid process coupling adsorption on marl and microfiltration

  • Received : 2019.09.07
  • Accepted : 2020.04.16
  • Published : 2020.07.25
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Abstract

Hranfa's marl, a local natural mineral, is selected for the decontamination by adsorption of aqueous effluents in textile industry. Its physicochemical characterization is first performed. It is composed mainly of Calcite, Quartz, Ankerite and Muscovite. Its specific surface area is 40 ㎡ g-1. Its adsorption performance is then tested in batch conditions using an industrial organic dye, Bemacid Red E-TL, as a model pollutant. The measured adsorption capacity of Hranfa's marl is 16 mg g-1 which is comparable to that of other types of natural adsorbents. A hybrid process is tested coupling adsorption of the dye on marl in suspension and microfiltration. An adsorption reactor is inserted into the circulation loop of a microfiltration pilot using ceramic membranes. This makes possible a continuous extraction of the treated water provided that a periodic replacement of the saturated adsorbent is done. The breakthrough curve obtained by analyzing the dye concentration in the permeate is close to the ideal one considering that no dye will cross the membrane as long as the adsorbent load is not saturated. These first experimental data provide proof of concept for such a hybrid process.

Keywords

Acknowledgement

The authors warmly thank D. Cot and B. Ribière (IEM) for SEM and EDX analyses, A. El Manssouri (IEM) for specific surface area measurements, D. Granier (Réseau RX and gamma ICGM) for DRX analyses, F.B. Henni Chebra and F. Guitarni (University of Chlef) for FTIR and chemical analyses. They also thank the Algerian and the French Ministries of Higher Education and Research for their financial support.

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