DOI QR코드

DOI QR Code

Excellent toluene removal via adsorption by honeycomb adsorbents under high temperature and humidity conditions

  • 투고 : 2018.12.21
  • 심사 : 2019.03.01
  • 발행 : 2020.04.30

초록

Removal through adsorption is the most widely used and effective treatment method for volatile organic compounds (VOCs) in exhaust gases. However, at high temperatures and humidity, adsorption is competitive due to the presence of moisture and unsmooth physical adsorption thereby deteriorating adsorption performance. Therefore, water adsorption honeycomb (WAH) and VOCs adsorption honeycomb (VAH) were prepared to improve VOCs adsorption at high temperatures and humidity. Adsorbed toluene amounts on single honeycomb (SH), containing only VAH, and combined honeycomb (CH), containing WAH and VAH, were determined. Further, the toluene adsorption rates of honeycomb adsorbents mounted on rotary systems, VAH-single rotor (SR) and WAH/VAH-dual rotor (DR) were determined. Toluene adsorption by WAH/VAH-CH (inlet temperature: 40-50℃; absolute humidity: 28-83 gH2O/kg-dry air) was 1.6 times that by VAH-SH, and the water adsorption efficiency of WAH/VAH-CH was 1.7 times that of VAH-SH. The adsorption/removal efficiency of the WAH/VAH-DR (inlet temperature: 45℃; absolute humidity: 37.5 gH2O/kg-dry air) was 3% higher than that of VAH-SR. This indicates that the WAH at the rotor inlet selectively removed water, thereby improving the adsorption efficiency of the VAH at the outlet.

키워드

참고문헌

  1. Noordally E, Richmond JR, Drumm KJ. Catalytic oxidation processes for odour and VOC control. Stud. Environ. Sci. 1994;61;459-467. https://doi.org/10.1016/S0166-1116(08)72076-4
  2. Volkamer R, Jimenez JL, San Martini F, et al. Secondary organic aerosol formation from anthropogenic air pollution: Rapid and higher than expected. Geophys. Res. Lett. 2006;33:L17811. https://doi.org/10.1029/2006GL026899
  3. Zou L, Luo Y, Hooper M, Hu E. Removal of VOCs by photocatalysis process using adsorption enhanced $TiO_2-SiO_2$ catalyst. Chem. Eng. Process. 2006;45:959-964. https://doi.org/10.1016/j.cep.2006.01.014
  4. Li WB, Wang JX, Gong H. Catalytic combustion of VOCs on non-noble metal catalysts. Catal. Today 2009;148:81-87. https://doi.org/10.1016/j.cattod.2009.03.007
  5. Mitsuma Y, Ota Y, Hirose T. Performance of thermal swing honeycomb VOC concentrators. J. Chem. Eng. Jpn. 1998;31;482-484. https://doi.org/10.1252/jcej.31.482
  6. Mitsuma Y, Yamauchi H, Hirose T. Analysis of VOC reversing adsorption and desorption characteristics for actual efficiency prediction for ceramic honeycomb adsorbent. J. Chem. Eng. Jpn. 1998;31:253-257. https://doi.org/10.1252/jcej.31.253
  7. Ichiura H, Okamura N, Kitaoka T, Tanaka H. Preparation of zeolite sheet using a papermaking technique. Part II. The strength of zeolite sheet and its hygroscopic characteristics. J. Mater. Sci. 2001;36:4921-4926. https://doi.org/10.1023/A:1011840405043
  8. Yoo YJ, Kim HS. Adsorption and desorption dynamics of toluene on high silica zeolite honeycomb adsorbent. In: Korean. Soc. Energy Proceedings on Spring Symposium; 2000. p. 307-312.
  9. Motsuma Y, Ota Y, Hirose T. Performance of thermal swing honeycomb VOC Concentrators. J. Chem. Eng. Jpn. 1998;31:482-484. https://doi.org/10.1252/jcej.31.482
  10. Chang FT, Lin YC, Bai H, Pei BS. Adsorption and desorption characteristics of semiconductor volatile organic compounds on the thermal swing honeycomb zeolite concentrator. J. Air Waste Manage. Assoc. 2003;53:1384-1390. https://doi.org/10.1080/10473289.2003.10466301
  11. Yang J, Chen Y, Cao L, Guo Y, Jia J. Development and field-scale optimization of a honeycomb zeolite rotor concentrator/recuperative oxidizer for the abatement of volatile organic carbons from semiconductor industry. Environ. Sci. Technol. 2012:46:441-446. https://doi.org/10.1021/es203174y
  12. Zhao XS, Ma Q, Lu GQ. VOC Removal: Comparison of MCM-41 with hydrophobic zeolites and activated carbon. Energ. Fuel. 1998;12:1051-1054. https://doi.org/10.1021/ef980113s
  13. Diaz E, Ordonez S, Vega A, Coca J. Adsorption characterization of different volatile organic compounds over alumina, zeolites and activated carbon using inverse gas chromatography. J. Chromatogr. A 2004;1049:139-146. https://doi.org/10.1016/j.chroma.2004.07.061
  14. Takeuchi Y, Iwamoto H, Miyata N, Asano S, Harada M. Adsorption of 1-butanol and p-xylene vapor and their mixtures with high silica zeolites. Sep. Technol. 1995;5:23-34. https://doi.org/10.1016/0956-9618(94)00101-W
  15. Lee SW, Kam SK, Lee MG. Comparison of breakthrough characteristics for binary vapors composed of acetone and toluene based on adsorption intensity in activated carbon fixed-bed reactor. J. Ind. Eng. Chem. 2007;13:911-916.
  16. Monneyron P, Manero MH, Foussard JN. Measurement and modeling of single- and multi-component adsorption equilibria of VOC on high-silica zeolites. Environ. Sci. Technol. 2003;37:2410-2414. https://doi.org/10.1021/es026206c
  17. Chuang CL, Chiang PC, Chang EE. Modeling VOCs adsorption onto activated carbon. Chemosphere 2003;53:17-27. https://doi.org/10.1016/S0045-6535(03)00357-6
  18. Bouhamra WA, Elkilani AS, Baker CGJ. Testing adsorbents capacities for indoor volatile organic compounds at optimum operating conditions. WIT Trans. Ecol. Environ. 2006;86:411-420.
  19. Yang RT. Gas separation by adsorption processes. Boston:Butterworth; 1987. p. 1-48.
  20. Brunaure S, Emmett PH. The use of low temperature van def waals adsorption isotherms in determining the surface areas of various adsorbents. J. Am. Chem. Soc. 1937;59:2682-2689. https://doi.org/10.1021/ja01291a060
  21. Cho MW, An D, Yim B, et al. Toluene adsorption characteristics of zeolite depending on temperature and relative humidity. Odor Indoor Environ. 2016;15:368-374. https://doi.org/10.15250/joie.2016.15.4.368