Journal of Korean Society of Water and Wastewater (상하수도학회지)

The Korean Society of Water and Wastewater (대한상하수도학회)
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Degradation characteristics and intermediate study of tetracycline in aqueous system by liquid ferrate(VI)

Liquid ferrate(VI)에 의한 다양한 수중 환경에서의 tetracycline 분해특성 및 중간생성물 연구

  • Park, Kyeong-Deok (Interdisciplinary Program of Marine Convergence Design, Pukyong National University) ;
  • Kang, Dong-Hwan (Institute of Environmental Research, Pukyong National University) ;
  • So, Yoon-Hwan (Institute of Environmental Research, Pukyong National University) ;
  • Cho, Joung-Hyung (Interdisciplinary Program of Marine Convergence Design, Pukyong National University) ;
  • Kim, Il-Kyu (Department of Environmental Engineering, Pukyong National University)
  • 박경덕 (부경대학교 마린융합디자인협동과정) ;
  • 강동환 (부경대학교 환경연구소) ;
  • 소윤환 (부경대학교 환경연구소) ;
  • 조정형 (부경대학교 마린융합디자인협동과정) ;
  • 김일규 (부경대학교 환경공학과)
  • Received : 2019.12.08
  • Accepted : 2020.02.10
  • Published : 2020.02.15
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Abstract

Tetracycline is one of the most commonly used antibiotics in domestic and foreign livestock industries to suppress the growth of pathogens. Tetracycline has been reported as a non-biodegradable compound. Therefore it has been not completely removed in the sewage treatment process. In this study, tetracycline was degraded using liquid ferrate (VI). Based on these experiments, the optimal water condition (pH and water temperature) were selected, appropriate liquid ferrate (VI) dosage was calculated, and finally the degradation pathway was estimated with the intermediate products detected by LC/MS/MS. All degradation experiments were completed within 30 seconds and the optimal condition was obtained in basic condition (pH 10) at room temperature (20℃). And the appropriate molar ratio between tetracycline and liquid ferrate (VI) was 12.5:1. Finally, 12 intermediate products were detected with LC/MS/MS and the degradation pathways and the degradation pathways and proposed the degradation pathways.

Keywords

References

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