한국건설순환자원학회논문집 (Journal of the Korean Recycled Construction Resources Institute)

한국건설순환자원학회 (Korean Recycled Construction Resources Institute)
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무기질계 팽창재가 포함된 시멘트 모르타르의 자기치유성능에 관한 연구

Investigation on the Self-Healing Performance of Cement Mortar Incorporating Inorganic Expansive Additives

  • 신진욱 (한양대학교 건축공학과) ;
  • 허성원 (한양대학교 건축공학과) ;
  • 배성철 (한양대학교 건축공학과)
  • Shin, Jin-Wook (Department of Acrhitectural Engineering, Hanyang University) ;
  • Her, Sung-Wun (Department of Acrhitectural Engineering, Hanyang University) ;
  • Bae, Sung-Chul (Department of Acrhitectural Engineering, Hanyang University)
  • 투고 : 2020.09.18
  • 심사 : 2020.10.12
  • 발행 : 2020.12.30
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초록

본 연구는 무기질 재료인 Calcium sulfoaluminate(CSA), Crystalline admixture(CA) 그리고 Magnesium oxide(MgO)가 포함된 시멘트 모르타르의 물성 및 자기치유성능을 조사하였다. 자기치유성능을 분석하기 위해 모르타르 강도시험, 물투과성 실험을 실시하였으며, 다양한 균열폭 변화는 디지털 광학현미경을 사용하여 측정하였다. 자기치유를 통해 생성된 수화물에 대해서는 X-ray powder diffraction, Thermogravimetry를 통한 성분분석을 실시하였다. 분석결과 CA치환량이 증가 할수록 압축 및 휨 강도는 증가하였다. 하지만 MgO치환 시에는 오히려 CA치환량이 증가 할수록 압축 및 휨 강도는 감소하였다. 회복된 균열부에 생성된 치유물질은 Ca(OH)2, MgCO3, CaCO3으로 확인되었다. CaCO3은 균열부에 생성된 주요 치유 성분으로 나타났으며, Ca(OH)2, MgCO3보다 높은비율을 차지하고 있는 것으로 확인 되었다. 또한, 물 투과성과 균열폭 결과를 통한 최적의 배합은 CSA 8% + CA 1% + MgO 2.5%으로 나타났다.

Herein, the properties and self-healing performance of cement mortar incorporating calcium sulfoaluminate(CSA), crystalline admixture(CA), and magnesium oxide(MgO) were investigated. Mortar strength test and water permeability experiments were conducted to analyze self-healing performance of the mortar. Also, variation in crack width were measured via digital optical microscope observation. The hydration products formed in the crack via self-healing were analyzed using x-ray diffraction(XRD), thermogravimetry(TG), and digital optical microscope. The analysis revealed that compressive strength and tensile strength increased as CA substitutional ratio increased. However, in the case of MgO replacement, the compressive strength and tensile strength decreased as the CA substitution ratio increased. The products in the recovered cracks are found to be mostly Ca(OH)2, MgCO3, and CaCO3. CaCO3 was shown to be the main healing product and had a higher portion than Ca(OH)2 and MgCO3 in the recovery products. Moreover, the optimal mix derived via water permeability and crack width results was 8% CSA + 1% CA + 2.5% MgO.

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참고문헌

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