과제정보
This study is based upon work supported by the Department of Energy Technology Research & Development Program under award number DE-AC07-05ID14517. The authors would like to thank Dr. James King from Idaho National Laboratory for suggestions and discussions on uranium morphology. The authors would also like to thank Meredith B. Eaheart for her contributions to the experiments discussed in this report.
참고문헌
- C.H. Lee, T.J. Kim, S. Park, S.J. Lee, S.W. Paek, D.H. Ahn, and S. K. Cho, "Effect of Cathode Material on the Electrorefining of U in LiCl-KCl Molten Salts", J. Nucl. Mater., 488, 210-214 (2017). https://doi.org/10.1016/j.jnucmat.2017.03.023
- S.L. Marshall, L. Redey, G.F. Vandegrift, and D.R. Vissers, Electroformation of Uranium Hemispherical Shells, Argonne National Laboratory Report, ANL-89/26 (1990).
- K.C. Marsden, B.R. Westphal, M.N. Patterson, and B. Pesic, "Purity of Uranium Product from Electrochemical Recycling of Used Metallic Fuel", IPRC, Fontana, Wisconsin (2012).
- K.C. Marsden, "Measurement and Analysis of Uranium and Cerium Depositions from LiCl-KCl Eutectic" Diss., University of Idaho (2015).
- H. Tang and B. Pesic, "Electrochemistry and the Mechanisms of Nucleation and Growth of Neodymium during Electroreduction from LiCl-KCl Eutectic Salts on Mo Substrate", J. Nucl. Mater., 458, 37-44 (2015). https://doi.org/10.1016/j.jnucmat.2014.11.084
- K. Serrano, P. Taxil, O. Dugne, S. Bouvet, and E. Puech, "Preparation of Uranium by Electrolysis in Chloride Melt", J. Nucl. Mater., 282(2-3), 137-145 (2000). https://doi.org/10.1016/S0022-3115(00)00423-2
- C.S. Wang, Y. Liu, H. He, F.X. Gao, L.S. Liu, S.W. Chang, J.H. Guo, L. Chang, R.X. Li, and Y.G. Ouyang, "Electrochemical Separation of Uranium and Cerium in Molten LiCl-KCl", J. Radioanal. Nucl. Chem., 298(1), 581-586 (2013). https://doi.org/10.1007/s10967-013-2506-y
- T.C. Totemeier and R.D. Mariani, "Morphologies of Uranium and Uranium-Zirconium Electrodeposits" J. Nucl. Mater., 250(2-3), 131-146 (1997). https://doi.org/10.1016/S0022-3115(97)00288-2
- H. Tang and B. Pesic, "Electrochemical behavior of LaCl3 and morphology of la deposit on molybdenum substrate in molten LiCl-KCl eutectic salt", Electrochim. Acta, 119, 120-130 (2014). https://doi.org/10.1016/j.electacta.2013.11.148
- H. Tang and B. Pesic, "Electrochemistry of ErCl3 and morphology of erbium electrodeposits produced on Mo Substrate in Early Stages of Electrocrystallization from LiCl-KCl Molten Salts", Electrochim. Acta, 133, 224-232 (2014). https://doi.org/10.1016/j.electacta.2014.04.014
- T. Mioduski, C. Guminski, and D. Zeng, "IUPAC-NIST solubility data series. 87. Rare earth metal chlorides in water and aqueous systems. Part 2. Light Lanthanides (Ce-Eu)", J. Phys. Chem. Ref. Data, 38(2), 441-62 (2009). https://doi.org/10.1063/1.3112775
- T. Mioduski, C. Guminski, and D. Zeng, "IUPACNIST solubility data series. 87. rare earth metal chlorides in water and aqueous systems. Part 3. heavy lanthanides (Gd-Lu)", J. Phys. Chem. Ref. Data, 38(2), 925-1011 (2009). https://doi.org/10.1063/1.3212962
- D. Lide, "Aqueous Solubility of Inorganic Compounds at Various Temperatures", in: CRC Handb. Chem. Phys. 85th ed., CRC Press, New York (1968).
- S.P. Pinho and E.A. Macedo, Solubility of NaCl, NaBr, and KCl in water, methanol, ethanol, and their mixed solvents, J. Chem. Eng. Data, 50(1), 29-32 (2005). https://doi.org/10.1021/je049922y
- M. Li, D. Constantinescu, L. Wang, A. Mohs, and J. Gmehling, "Solubilities of NaCl, KCl, LiCl, and LiBr in methanol, ethanol, acetone, and mixed solvents and correlation using the liquac model", Ind. Eng. Chem. Res., 49(10), 4981-4988 (2010). https://doi.org/10.1021/ie100027c
- J.P. Hsu and B.T. Liu, "Dissolution of solid particles in liquids: A reaction-diffusion model", Colloids Surf., 69(4), 229-238 (1993). https://doi.org/10.1016/0166-6622(93)80004-Y
- M. Shaltry and S. Phongikaroon, "Experimental study of salt bead dissolutions in aqueous solvents", Ind. Eng. Chem. Res., 53(34), 13550-13556 (2014). https://doi.org/10.1021/ie502608v
- C.H. Lee, T.J. Kim, S. Park, S.J. Lee, S.W. Paek, D.H. Ahn, and S.K. Cho, "Effect of cathode material on the electrorefining of U in LiCl-KCl molten salts", J. Nucl. Mater., 488, 210-214 (2017). https://doi.org/10.1016/j.jnucmat.2017.03.023
피인용 문헌
- Investigation of the effects of cerium concentration and overpotential on the morphology and purity of uranium dendrites vol.330, pp.3, 2020, https://doi.org/10.1007/s10967-021-08006-1