Resources Recycling (자원리싸이클링)

The Korean Institute of Resources Recycling (한국자원리싸이클링학회)
권호 표지
DOI QR코드

DOI QR Code

Research Trends in Flotation of Waste-plastics and Its Use as Functional Materials

폐플라스틱의 부유선별 및 기능성 소재로의 활용 연구동향

  • Han, Yosep (Resource Recovery Research Center, Mineral Resources Division, Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Kim, Rina (Resource Recovery Research Center, Mineral Resources Division, Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Hong, Hye-Jin (Resource Utilization Research Center, Mineral Resources Division, Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Park, In-Su (Resource Utilization Research Center, Mineral Resources Division, Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Kim, Dong-Gyun (Advanced Functional Polymers Research Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Kim, Yun Ho (Advanced Functional Polymers Research Center, Korea Research Institute of Chemical Technology (KRICT)) ;
  • Jeon, Ho-Seok (Resource Recovery Research Center, Mineral Resources Division, Korea Institute of Geoscience and Mineral Resources (KIGAM)) ;
  • Chang, Hankwon (Resource Utilization Research Center, Mineral Resources Division, Korea Institute of Geoscience and Mineral Resources (KIGAM))
  • 한요셉 (한국지질자원연구원 광물자원연구본부 자원회수연구센터) ;
  • 김리나 (한국지질자원연구원 광물자원연구본부 자원회수연구센터) ;
  • 홍혜진 (한국지질자원연구원 광물자원연구본부 자원활용연구센터) ;
  • 박인수 (한국지질자원연구원 광물자원연구본부 자원활용연구센터) ;
  • 김동균 (한국화학연구원 고기능 고분자 연구센터) ;
  • 김윤호 (한국화학연구원 고기능 고분자 연구센터) ;
  • 전호석 (한국지질자원연구원 광물자원연구본부 자원회수연구센터) ;
  • 장한권 (한국지질자원연구원 광물자원연구본부 자원활용연구센터)
  • Received : 2020.11.24
  • Accepted : 2020.12.18
  • Published : 2020.12.30
Download PDF
⟨ Previous Next ⟩

Abstract

In recent years, there is an increasing interest in environmental friendly treatment of waste-plastics in terms of the generation of microplastics. Accordingly, the recycling of waste-plastics is very important because it provides advantages of volume reduction, mitigation of carbon dioxide emission, and reproduction of value-added products. In particular, in order to recycle the eco-friendly waste-plastics, it is necessary to use a physical separation methods, and among them, flotation separation, which can separate material (i.e., polymer component) in waste-plastics is well known as a very effective separation method in terms of material recycle. Therefore, in this review, the research trend of flotation separation for effective separation of mixture waste-plastics was investigated. In addition, through the reported research results, approaches to use as new functional materials from polymers, which are raw materials for waste-plastics, are summarized.

최근 미세플라스틱의 발생 측면에서 폐플라스틱의 친환경적 처리에 대한 관심이 증대하고 있다. 이에, 폐플라스틱의 재활용이 폐기물 간소화, 이산화탄소 배출 감소 및 부가가치 제품 재생산의 이점을 제공하기 때문에 매우 중요하다고 할 수 있다. 특히, 친환경적인 폐플라스틱의 재활용을 위해서는 물리적 선별방법을 통해야 하며, 그 중에서도 폐플라스틱내의 재질별 분리가 가능한 부유선별이 물질재활용 측면에서 매우 효과적인 분리방법으로 잘 알려져 있다. 따라서, 본 총설에서는 혼합 폐플라스틱의 효과적인 재질 분리를 하기 위한 부유 선별의 연구 동향을 조사하였다. 추가적으로 보고된 연구결과들을 통하여 플라스틱의 원재료인 폴리머로부터 기능성 신소재로서의 활용에 대한 접근방법을 요약 정리하였다.

Keywords

References

  1. Wang, C., Wang, H., Fu, J., et al., 2015 : Flotation separation of waste plastics for recycling-A review, Waste Management, 41, pp.28-38. https://doi.org/10.1016/j.wasman.2015.03.027
  2. Geyer, R., Jambeck, J.R. and Law, K.L., 2017 : Production, use, and fate of all plastics ever made, Science Advances, 3(7), pp.1-5.
  3. Irfan, T., Khalid, S., Taneez, M., et al., 2020 : Plastic driven pollution in Pakistan: the first evidence of environ mental exposure to microplastic in sediments and water of Rawal Lake, Environmental Science and Pollution Research, 27, pp.15083-15092. https://doi.org/10.1007/s11356-020-07833-1
  4. Wang, H., Zhang, Y. and Wang, C., 2019 : Surface modification and selective flotation of waste plastics for effective recycling - a review, Separation and Purification Technology, 226(1), pp.75-94. https://doi.org/10.1016/j.seppur.2019.05.052
  5. Al-Salem, S.M., Lettieri, P. and Baeyens, J., 2009 : Recycling and recovery routes of plastic solid waste (PSW): a review. Waste Management, 29, pp.2625-2643. https://doi.org/10.1016/j.wasman.2009.06.004
  6. Zhang, D.Q., Tan, S.K. and Gersberg, R.M., 2010 : Municipal solid waste management in China: status, problems and challenges, Journal of Environmental Management, 91, pp.1623-1633. https://doi.org/10.1016/j.jenvman.2010.03.012
  7. Achilias, D.S., Roupakias, C., Megalokonomos, P., et al., 2007 : Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP), Journal of Hazardous Materials, 149, pp.536-542. https://doi.org/10.1016/j.jhazmat.2007.06.076
  8. Cho, Y. and Cho, B.G., 2020: Status and future prospects for plastics recycling, Journal of Korean Institute of Resources Recycling, 29(4), pp.31-44. https://doi.org/10.7844/KIRR.2020.29.4.31
  9. Kim, S., Baek, S., Han, Y., et al., 2020 : Current research trends for treatment of microplastics, Journal of Korean Institute of Resources Recycling, 29(5), pp.15-27. https://doi.org/10.7844/KIRR.2020.29.5.15
  10. Hopewell, J., Dvorak, R., Kosior, E., 2009. Plastics recycling: challenges and opportunities. Philosophical Transactions of the Royal Society B: Biological Sciences, 364, pp.2115-2126. https://doi.org/10.1098/rstb.2008.0311
  11. Miller, M.E., Kroon, F.J. and Motti, C.A., 2017 : Recovering microplastics from marine samples: A review of current practices, Marine Pollution Bulletin, 123(1-2), pp.6-18. https://doi.org/10.1016/j.marpolbul.2017.08.058
  12. Ruggero, F., Gori, R. and Lubello, C., 2020 : Methodologies for microplastics recovery and identification in heterogeneous solid matrices: A Review, Journal of Polymers and the Environment, 28, pp.739-748. https://doi.org/10.1007/s10924-019-01644-3
  13. Nguyen, B., Claveau-Mallet, D., Hernandez, L.M., et al., 2019 : Separation and analysisi of microplastics and nanoplastics in complex environmental samples, Accounts of chemical research, 52(4), pp.858-866. https://doi.org/10.1021/acs.accounts.8b00602
  14. Singh, N., Hui, D., Singh, R., et al., 2007 : Recycling of plastic solid waste: A state of art review and future applications, Composites Part B, 115, pp.409-422. https://doi.org/10.1016/j.compositesb.2016.09.013
  15. Buchan, R. and Yarar, B., 1995 : Recovering plastics for recycling by mineral processing techniques. The Journal of The Minerals, Metals & Materials Society, 47, pp.52-55. https://doi.org/10.1007/BF03221410
  16. Erbil, H.Y., Demirel, A.L., Avci, Y., et al., 2003 : Transformation of a simple plastic into a superhydrophobic surface. Science, 299, pp.1377-1380. https://doi.org/10.1126/science.1078365
  17. Wang, C., Wang, H., Fu, J., et al., 2014 : Effects of additives on PVC plastics surface and the natural flotability, Colloids Surface A, 441, pp.544-548. https://doi.org/10.1016/j.colsurfa.2013.10.010
  18. Shen, H., Forssberg, E. and Pugh, R., 2001 : Selective flotation separation of plastics by particle control, Resources, Conservation & Recycling, 33, pp.37-50. https://doi.org/10.1016/S0921-3449(01)00056-8
  19. Fraunholcz, N., 1997. Plastics flotation. Ph.D. thesis, Delft University of Technology, Eburon P&L, Delft, The Netherlands.
  20. Marques, G.A. and Tenorio, J.A.S., 2000 : Use of froth flotation to separate PVC/PET mixtures, Waste Management, 20, pp.265-269. https://doi.org/10.1016/S0956-053X(99)00333-5
  21. Stuckrad, B., Lohr, K. and Vogt, V., 1997. Sorting of waste plastic mixtures by flotation. In: Proceedings of the XX International Mineral Processing Congress.
  22. Olah, A., Hillborg, H. and Vancso, G.J., 2005 : Hydrophobic recovery of UV/ozone treated poly (dimethylsiloxane): adhesion studies by contact mechanics and mechanism of surface modification, Applied Surface Science, 239, pp. 410-423. https://doi.org/10.1016/j.apsusc.2004.06.005
  23. Martin, N., Skvarla, J., Sisol, M., 2011. A Possibility of using the flotation process to separate plastics, Annals of Faculty Engineering Hunedoara, pp.275-278.
  24. Alter, H., 1978 : Application of the critical surface tension concept to items in our everyday life, The Journal of Adhesion, 9, pp.135-140. https://doi.org/10.1080/00218467808075108
  25. Marques, G.A. and Tenorio, J.A.S., 2000 : Use of froth flotation to separate PVC/PET mixtures, Waste Management, 20, pp.265-259. https://doi.org/10.1016/S0956-053X(99)00333-5
  26. Takoungsakdakun, T. and Pongstabodee S., 2007 : Separation of mixed post-consumer PET-POM-PVC plastic waste using selective flotation, Separation and Purification Technology, 54, pp.248-252. https://doi.org/10.1016/j.seppur.2006.09.011
  27. Drelich, J., Payne, T., Kim, J.H. and Miller, J.D., 1998 : Selective froth flotation of PVC from PVC/PET mixtures for the plastics recycling industry, Polymer Engineering Science, 38, pp.1378-1386. https://doi.org/10.1002/pen.10308
  28. Alter, H., 2005 : The recovery of plastics from waste with reference to froth flotation, Resources, Conservation & Recycling, 43, pp.119-132. https://doi.org/10.1016/j.resconrec.2004.05.003
  29. Shent, H. and Pugh, RJ., 1999 : Forssberg E. A review of plastics waste recycling and the flotation of plastics, Resources, Conservation & Recycling, 25, pp.85-109. https://doi.org/10.1016/S0921-3449(98)00017-2
  30. Barlaz, MA. and Haynie, FH., 1993 : Overcash MF. Framework for assessment of recycle potential applied to plastics. Journal of Environmental Engineering, 119, pp.798-810. https://doi.org/10.1061/(ASCE)0733-9372(1993)119:5(798)
  31. Carvalho, T., Durao, F. and Ferreira, C., 2010 : Separation of packaging plastics by froth flotation in a continuous pilot plant. Waste Management, 30, pp.2209-15. https://doi.org/10.1016/j.wasman.2010.05.023
  32. Wang, H., Wang, C.Q., Fu, J.G., et al., 2014 : Flotability and flotation separation of polymer materials modulated by wetting agents, Waste Management, 34, pp.309-315. https://doi.org/10.1016/j.wasman.2013.11.007
  33. Saisinchai, S., 2013 : Separation of PVC from PET/PVC mixtures using flotation by calcium lignosulfonate depressant, Engineering Journal, 18, pp.45-54. https://doi.org/10.4186/ej.2014.18.1.45
  34. Pongstabodee, S., Kunachitpimol, N. and Damronglerd, S., 2008 : Combination of threestage sink-float method and selective flotation technique for separation of mixed post-consumer plastic waste, Waste Management, 28, pp. 475-483. https://doi.org/10.1016/j.wasman.2007.03.005
  35. Deiringer, G., Edelmann, G. and Rauxloh, B., 1993 : Process for the separation of plastics by flotation. US Patent 5248041.
  36. Singh, B.P., 1998 : Wetting mechanism in the flotation separation of plastics, Filtration & Separation, 35, pp.525-527. https://doi.org/10.1016/S0015-1882(98)80027-X
  37. Valdez, E.G. and Wilson, W.J., 1979 : Separation of plastics by flotation. US Patent 4167477.
  38. Kangal, M.O., 2010 : Selective flotation technique for separation of PET and HDPE used in drinking water bottles, Mineral Processing & Extractive Metallurgy Review, 31, pp.214-223. https://doi.org/10.1080/08827508.2010.483362
  39. Abbasi, M., Salarirad, M.M. and Ghasemi, I., 2010 : Selective separation of PVC from PET/PVC mixture using floatation by tannic acid depressant, Iranian Polymer Journal, 19, pp.483-489.
  40. Burat, F., Guney, A. and Olgac Kangal, M., 2009 : Selective separation of virgin and postconsumer polymers (PET and PVC) by flotation method, Waste Management, 29, pp. 1807-1813. https://doi.org/10.1016/j.wasman.2008.12.018
  41. Shibata, J., Matsumoto, S., Yamamoto, H., et al., 1996 : Flotation separation of plastics using selective depressants, International Journal of Mineral Processing, 48, pp.127-134. https://doi.org/10.1016/S0301-7516(96)00021-X
  42. Izumi, S. and Saitoh, K., 1979 : Method for separating mixture of plastics, US Patent 4132633.
  43. Yoon, R.H. and Ravishankar, S.A., 1994 : Application of Extended DLVO Theory. 3. Effect of Octanol on the Long-Range Hydrophobic Forces between DodecylamineCoated Mica Surfaces, Journal of Colloid Interface Science, 166, pp.215-224. https://doi.org/10.1006/jcis.1994.1287
  44. Han, Y., Han, S., Kim, B., et al., 2019 : Flotation separation of quartz from apatite and surface forces in bubble-particle interactions: Role of pH and cationic amine collector contents, Journal of Industrial and Engineering Chemistry, 70, pp.107-115. https://doi.org/10.1016/j.jiec.2018.09.036
  45. Fraunholcz, N., 2004 : Separation of waste plastics by froth flotation-A review, part I. Minerals Engineering, 17, pp.261-268. https://doi.org/10.1016/j.mineng.2003.10.028
  46. Saleem, J., Riaz, M.A. and McKay, G., 2018 : Oil sorbents from plastic wastes and polymers: A review, Journal of Hazardous Materials, 341, pp.424-437. https://doi.org/10.1016/j.jhazmat.2017.07.072
  47. James C. Fletcher, and Harold E. Marsh, Jr., 1977 : Oil and fat absorbing polymers, U.S. Patent No. 4039489.
  48. Wu, J., Wang, N., Wang, L., et al., 2012 : Electrospun porous structure fibrous film with high oil adsorption capacity, ACS Applied Materials Interfaces, 4, pp.3207-3212. https://doi.org/10.1021/am300544d
  49. Han, Y., Rheem, Y., Lee, K.H., et al., 2018 : Synthesis and characterization of orthorhombic-MoO3 nanofibers with controlled morphology and diameter, Journal of Industrial and Engineering Chemistry, 62, pp.231-238. https://doi.org/10.1016/j.jiec.2017.12.063
  50. Li, D. and Xia, Y., 2003 : Fabrication of titania nanofibers by electrospinning, Nano Letters 2003, 3, pp.555-560.
  51. Li, D. and Xia, Y., 2004 : Electrospinning of nanofibers: reinventing the wheel? Advanced Materials, 16, pp.1151-1170. https://doi.org/10.1002/adma.200400719
  52. Lin, J., Ding, B., Yang, J., et al., 2012 : Subtle regulation of the micro- and nanostructures of electrospun polystyrene fibers and their application in oil absorption, Nanoscale, 4, pp.176-182. https://doi.org/10.1039/c1nr10895f
  53. Wang, G. and Uyama, H., 2016 : Facile synthesis of flexible macroporous polypropylene sponges for separation of oil and water, Scientific Reports, 6, pp.21265-21271. https://doi.org/10.1038/srep21265