DOI QR코드

DOI QR Code

Removal of safranin from aqueous solution through liquid emulsion membrane

  • Lohiya, Roshni (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Goyal, Arihant (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Dohare, Rajeev Kumar (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Agarwal, Madhu (Department of Chemical Engineering, Malaviya National Institute of Technology) ;
  • Upadhyaya, Sushant (Department of Chemical Engineering, Malaviya National Institute of Technology)
  • 투고 : 2017.06.05
  • 심사 : 2019.04.27
  • 발행 : 2019.09.25

초록

One of the real issues of the recent years is water contamination because of harmful synthetic dyes. Liquid Membranes (LM) resemble a promising alternative to the current separation processes, demonstrating various points of interest as far as effectiveness, selectivity, and operational expenses. The improvement of various Liquid Membranes designs has been a matter of examination by few researchers, particularly for the expulsion of dyes from aqueous solutions. The choice of organic surfactants plays an essential role in the efficiency of the dye removal. In LM design, the most significant step towards productivity is the decision of the surfactant type and its concentration. Liquid emulsion membrane (LEM) was used to remove safranin from aqueous solutions in which the emulsion was made with the help of D2EHPA as carrier, kerosene was used as a diluent and Span 80 (Sorbiton monooleate) was used as an emulsifying agent or surfactant. Various sorts of internal stages were utilized, to be specific sulphuric acid and sodium hydroxide. The impact of parameters influencing extraction efficiency such as pH of feed solution, concentrations of surfactant and emulsifying agent in membrane phase, volume ratio of internal phase to membrane phase, internal phase concentration, agitation speed and time of extraction were analyzed.

키워드

참고문헌

  1. Alamddine, I. and El Jamal, M.M. (2009), "Effect of supporting electrolyte and substituents on the electrochemical treatment of monoazo benzene dyes", J. University Chem. Technol. Metallurgy, 44, 127-132.
  2. Sumalatha, B., Venkata, A. Narayana, K., Kiran Kumar, D., Babu, J. and Venkateswarulu, T.C. (2016), "Phenol Removal from Industrial Effluent Using Emulsion Liquid Memebranes", J. Pharmaceutical Sci. Res., 8, 307-312.
  3. Bahloul, L., Bendebane, F., Djenouhat, M., Meradi, H. and Ismail, F. (2016), "Effects and optimization of operating parameters of anionic dye extraction from an aqueous solution using an emulsified liquid membrane: application of designs of experiments", J. Taiwan Institute Chem. Eng., 59, 26-32. https://doi.org/10.1016/j.jtice.2015.07.013.
  4. Bhatt, P. and Rani, A. (2013), "Textile dyeing and printing industry: An environmental hazard". Asian Dyer, 10, 51-54.
  5. Boyadzhiev, L. (1990), "Liquid pertraction or liquid membranes - State of the art", Separation Sci. Technol., 25, 187-205. https://doi.org/10.1080/01496399008050329.
  6. Daas, A. and Hamdaoui, O. (2010), "Extraction of anionic dye from aqueous solutions by emulsion liquid membrane", J. Hazardous Mater., .178, 973-981. https://doi.org/10.1016/j.jhazmat.2010.02.033
  7. Das, C., Rungta, M., Arya, G., Dasgupta, S. and De, S. (2008), "Removal of dyes and their mixtures from aqueous solution using liquid emulsion membrane", J. Hazardous Mater., 159, 365-371. https://doi.org/10.1016/j.jhazmat.2008.02.027.
  8. Djenouhat, M., Hamdaoui, O., Chiha, M. and Samar, M. H. (2008), "Ultrasonication-assisted preparation of water-in-oil emulsions and application to the removal of cationic dyes from water by emulsion liquid membrane: Part 1: Membrane stability", Separation Purification Technol., 62, 636-641. https://doi.org/10.1016/j.seppur.2008.03.018.
  9. Hajarabeevi, N., Bilal, I. M., Easwaramoorthy, D. and Palanivelu, K. (2009), "Facilitated transport of cationic dyes through a supported liquid membrane with D2EHPA as carrier", Desalination, 245, 19-27. https://doi.org/10.1016/j.desal.2008.06.009.
  10. Juang, R.S. and Lin, K.H. (2004), "Ultrasound-assisted production of W/O emulsions in liquid surfactant membrane processes", Colloids and Surfaces A: Physicochemical and Engineering Aspects, 238, 43-49. https://doi.org/10.1016/j.colsurfa.2004.02.028.
  11. Mondal, D.N., Sarangi, K., Pettersson, F., Sen, P.K., Saxen, H. and Chakraborti, N. (2011), "Cu-Zn separation by supported liquid membrane analyzed through Multi-objective Genetic Algorithms", Hydrometallurgy, 107, 112-123. https://doi.org/10.1016/j.hydromet.2011.02.008.
  12. Muthuraman, G. and Palanivelu, K. (2006), "Transport of textile dye in vegetable oils based supported liquid membrane", Dyes Pigments, 70, 99-104. https://doi.org/10.1016/j.dyepig.2005.05.002.
  13. Muthuraman, G. and Teng, T.T. (2009), "Extraction and recovery of rhodamine B, methyl violet and methylene blue from industrial wastewater using D2EHPA as an extractant", J. Industrial Eng. Chem., 15, 841-846. https://doi.org/10.1016/j.jiec.2009.09.010.
  14. Othman, N., Yi, O.Z., Zailani, S.N., Zulkifli, E.Z. and Subramaniam, S. (2013), "Extraction of Rhodamine 6G dye from liquid waste solution: Study on emulsion liquid membrane stability performance and recover", Separation Sci. Technol. 48, 1177-1183. https://doi.org/10.1080/01496395.2012.731123.
  15. Othman, N., Zailani, S.N. and Mili, N. (2011), "Recovery of synthetic dye from simulated wastewater using emulsion liquid membrane process containing tri-dodecyl amine as a mobile carrier", J. Hazardous Mater., 198, 103-112. https://doi.org/10.1016/j.jhazmat.2011.10.014.
  16. Patnaik, P.R. (1995), "Liquid emulsion membranes: principles, problems and applications in fermentation processes", Biotechnol. Adv., 13, 175-208. https://doi.org/10.1016/0734-9750(95)00001-7.
  17. Ren, Z., Meng, H., Zhang, W., Liu, J. and Cui, C. (2009), "The transport of copper (II) through hollow fiber renewal liquid membrane and hollow fiber supported liquid membrane", Separation Sci. Technol., 44, 1181-1197. https://doi.org/10.1080/01496390902728975.
  18. Robinson, T., Mcmullan, G., Marchant, R. and Nigam, P. (2001), "Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative", Bioresource Technol., 77, 247-255. https://doi.org/10.1016/S0960-8524(00)00080-8.
  19. Singh, S.K., Misra, S.K., Tripathi, S.C. and Singh, D.K. (2010), "Studies on permeation of uranium (VI) from phosphoric acid medium through supported liquid membrane comprising a binary mixture of PC88A and Cyanex 923 in n-dodecane as carrier", Desalination, 250, 19-25. https://doi.org/10.1016/j.desal.2009.06.067.
  20. Srivastava, A., Bhagat, A., Sharma, U., Dohare, R.K., Singh, K. and Upadhyaya, S. (2017), "Comparative study of arsenic (V) removal from aqueous solution using Aliquat-336 and 2-ethyl hexanol through emulsion liquid membrane", J. Water Process Eng., 16, 64-68. https://doi.org/10.1016/j.jwpe.2016.12.007.
  21. Sumalatha B., Narayana, A.V., Kumar, K.K., Babu, D.J. and Venkateswarulu, T.C. (2016) Phenol Removal from Industrial Effluent Using Emulsion Liquid Memebranes Journal of Pharmaceutical Science and Research, 8, 307-312.
  22. Vu, K.B., Kaminski, M.D. and Nunez, L. (2003), Review of Arsenic Removal Technologies for Contaminated Groundwaters, Argonne National Lab., IL, USA. https://doi.org/10.2172/815660.