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Investigation of Residual Organochlorine Pesticides in Apple and Pear Orchard Soil and Fruit

사과 및 배 과수원의 토양 및 과실 중 잔류성유기염소계 농약류 잔류량 조사

  • Lim, Sung-Jin (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Park, Jeong-Hwon (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Ro, Jin-Ho (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Lee, Min-Ho (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Yoon, Hyo-In (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Choi, Geun-Hyoung (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Ryu, Song-Hee (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Yu, Hye-Jin (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Park, Byung-Jun (Chemical Safety Division, National Institute of Agricultural Sciences, Rural Development Administration)
  • 임성진 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 박정훤 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 노진호 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 이민호 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 윤효인 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 최근형 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 류송희 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 유혜진 (농촌진흥청 국립농업과학원 화학물질안전과) ;
  • 박병준 (농촌진흥청 국립농업과학원 화학물질안전과)
  • Received : 2019.01.03
  • Accepted : 2019.06.24
  • Published : 2019.06.30

Abstract

BACKGROUND: Residual organochlorine pesticides (OCPs) are designated as persistent organic pollutants (POPs) by Stockholm Convention because they bioaccumulate through the food web, and pose a risk of causing adverse effect to human health and the environment. Apple and pear is economic crop in agriculture, and its cultivation area and yield has been increased. Therefore, we tried to investigate the OCPs residue in apple and pear orchard soils and fruits. METHODS AND RESULTS: Extraction and clean-up method were developed using the modified QuEChERS method for residual organochlorine pesticides (ROCPs) in apple and pear orchard soil and fruits. Recovery and limit of quantitation (LOQ) of ROCPs in soil and fruits were 75.4-101.4 and 76.9-93.4%, 0.03-0.21 and $0.6-1.2{\mu}g/kg$, respectively. Detected ROCPs in apple and pear orchard soil was 2,4-DDT, 4,4-DDD, 4,4-DDE, 4,4-DDT, and endosulfan sulfate, the residues were 2.2, 1.9-48.0, 1.3-84.1, 90.6-863.1, and $11.3-239.0{\mu}g/kg$, respectively. But five pesticides in all fruit samples were not detected. CONCLUSION: These results showed that ROCPs residues in apple and pear orchard soil had no effect on safety of agricultural products.

Keywords

References

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